What is the role of the sp-band in bandstructures and density-of-states?

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In summary, the conversation discusses the concept of bandstructures and density-of-states in solid state physics. It is explained that when matter forms the condensed state, it forms bonds and the valence electrons become delocalized in collective orbitals. These orbitals give rise to the band structure, with certain bands being associated to the sp hybrid orbitals. The speaker suggests looking into the tight binding model for more information on this topic.
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markmick
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I understand what the s-band, p-band and d-bands are. And I understand the sp hybrid orbital. But I'm unclear what the sp-band is, in conjunction with bandstructures and density-of-states.

For example: Molybdenum is [Kr] 5s1 4d5. What gives rise to sp-band for Mo?

Mark
 
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Are you familiar with the tight binding model? when matter forms the condensed state, it forms bonds. A solid can be thought as a macromolecule. The valence electrons no longer "belong" to specific atoms, they are delocalized in collective orbitals. Those orbitals give rise to the band structure. In particular, bands associated to the sp hybrid orbitals are 'sp' bands. You should look for the tight binding model in a solid state physics textbook.

This might help a bit: https://en.wikipedia.org/wiki/Tight_binding

And this: https://www2.le.ac.uk/departments/physics/people/mervynroy/lectures/pa4311/tight-binding.pdf (just google 'tight binding').
 
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FAQ: What is the role of the sp-band in bandstructures and density-of-states?

What is the sp-band?

The sp-band refers to the electronic energy band in a solid material that is formed from the combination of s and p atomic orbitals. It is a type of hybridization that occurs in materials with covalent bonding, such as semiconductors and insulators.

How is the sp-band different from other energy bands?

The main difference is that the sp-band is formed from hybridized atomic orbitals, while other energy bands are typically formed from pure atomic orbitals. The sp-band is also usually located at a higher energy level compared to other bands, making it important for the electronic properties of a material.

What is the significance of the sp-band in materials?

The sp-band plays a crucial role in determining the electronic and optical properties of materials. It affects the conductivity, bandgap, and other properties that are important for various applications, such as in electronics and energy devices.

How is the sp-band related to the band structure of a material?

The sp-band is one of several energy bands that make up the band structure of a material. It is typically located near the top of the valence band and can overlap with other bands, depending on the material. The overall band structure determines the electronic properties of a material.

Can the sp-band be manipulated or controlled?

Yes, the sp-band can be manipulated or controlled through various methods such as doping, strain engineering, and surface modifications. This can alter the band structure and therefore the electronic properties of a material, making it useful for tailoring the properties of materials for specific applications.

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