- #36
bahamagreen
- 1,014
- 52
My old book says...
The Hamiltonian for the atom will have operators that only operate on the coordinates of the particular particles, but it also includes motion of the atom as a whole (the center of mass).
So the Schrodinger equation may be separated, and the eigenfunctions connected only through a common separation constant, which includes the kinetic energy of the center of mass of the atom.
So unless the atom is "in a box", the KE can assume any value, so the eigenfunctions are independent* of each other, and the internal state of the atom is independent of the motion of its center of mass.
*In the event that the separation constant, itself, is quantized; the factors of the eigenfunctions may be only conditionally independent.
The Hamiltonian for the atom will have operators that only operate on the coordinates of the particular particles, but it also includes motion of the atom as a whole (the center of mass).
So the Schrodinger equation may be separated, and the eigenfunctions connected only through a common separation constant, which includes the kinetic energy of the center of mass of the atom.
So unless the atom is "in a box", the KE can assume any value, so the eigenfunctions are independent* of each other, and the internal state of the atom is independent of the motion of its center of mass.
*In the event that the separation constant, itself, is quantized; the factors of the eigenfunctions may be only conditionally independent.