What Volumes of HNO2 and KNO2 Create a pH 3 Buffer?

  • Thread starter Hemolymph
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In summary, to make a 1 liter buffered solution with a pH of 3.000 using 0.200 M HNO2 and 0.200 M KNO2, you will need 286 mL of HNO2 and 714 mL of KNO2 (option B). This is determined by using the Henderson-Hasselbalch equation and the volume-concentration equation.
  • #1
Hemolymph
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Homework Statement



. You have solutions of 0.200 M HNO2 and 0.200 M KNO2 (Ka for HNO2 = 4.00 × 10–4). A buffer of pH 3.000 is needed. What volumes of HNO2 and KNO2 are required to make 1 liter of buffered solution?
A) 500 mL of each
B) 286 mL HNO2; 714 mL KNO2
C) 413 mL HNO2; 587 mL KNO2
D) 714 mL HNO2; 286 mL KNO2
E) 587 mL HNO2; 413 mL KNO2


Homework Equations



pH=pKa+log([A]-/[HA])

The Attempt at a Solution



3=3.4+log([A-]/[HA])
-.4=log([A-]/[HA])
10^-.4
.398=[A-]/[HA]
I get confused conceptually of what to do after this. I know I need .398M of conj base for every 1M of acid
 
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  • #2
Hemolymph said:
.398=[A-]/[HA]

This is one equation. The other is

[tex]V_{A^-} + V_{HA} = 1L[/tex]

You need to combine volume with concentration - and you will have two equations in two unknowns. Just solve.
 

Related to What Volumes of HNO2 and KNO2 Create a pH 3 Buffer?

What is the Henderson Hasselback Equation?

The Henderson Hasselback Equation is an equation used in biochemistry to calculate the pH of a buffer solution. It relates the concentration of a weak acid and its conjugate base to the pH of the solution.

Why is the Henderson Hasselback Equation important?

The Henderson Hasselback Equation is important because it allows scientists to predict the pH of a buffer solution, which is crucial in many biological and chemical processes. It also helps in the design and preparation of buffer solutions for experiments and procedures.

How is the Henderson Hasselback Equation derived?

The Henderson Hasselback Equation is derived from the equilibrium constant expression for a weak acid and its conjugate base. It takes into account the dissociation constant of the weak acid and the concentrations of the acid and its conjugate base in the solution.

What are the limitations of the Henderson Hasselback Equation?

The Henderson Hasselback Equation is only applicable to buffer solutions containing a weak acid and its conjugate base. It does not work for buffer solutions containing strong acids or bases. Additionally, it assumes that the acid and its conjugate base are in equal concentrations, which may not always be the case.

How accurate is the Henderson Hasselback Equation?

The Henderson Hasselback Equation is accurate for buffer solutions with a pH close to the pKa of the weak acid. However, as the pH deviates from the pKa, the accuracy decreases. Additionally, experimental errors in measuring concentrations and pH can also affect the accuracy of the equation.

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