Why do Oxygenated fuels contain less energy than hydrocarbons?

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In summary, the conversation discusses the question of why oxygenated fuels contain less energy than hydrocarbons. The student's science teacher asked this question and the student used a calorimeter to test the energy content of ethanol and octane, with octane showing a higher amount of energy. The student then asks for help in answering the question and later suggests that the difference may be due to the strength of bonds in each fuel. The question is noted as a good one for testing understanding of combustion reactions, and prompts consideration of the products and reactants, oxidation and reduction, and factors affecting energy release in redox reactions.
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Homework Statement



Why do Oxygenated fuels contain less energy than hydrocarbons?
So my science teacher asked us this question and i have no clue what the answer is. We used a calorimeter to test the amount of energy in ethanol and octane, and the octane had more energy. Could anyone answer the question above? I would appreciate all the help i can get, thanks :)

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The Attempt at a Solution


Okay after doing some more research, I am guessing it has to do with the bonds in each fuel. Since hydrocarbons contain mostly carbon-carbon bonds, which are one of the strongest, they are very durable and hard to break. Unlike oxygenated fuels which are mixed with oxygen and have weaker bonds. Thus, the hydrocarbons are stronger due to the stronger bonds. Is that right? and does it make sense?
 
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This question is a very good question to ask students because it tests whether they understand combustion reactions. Here are a few things to think about as you answer:

1) In the combustion of hydrocarbons (oxygenated or not), what are the products and reactants?

2) A combustion reaction is a redox reaction. Which chemical species are being oxidized and which species are being reduced?

3) In redox reactions, what factors determine how much energy gets released by the reaction?
 

Related to Why do Oxygenated fuels contain less energy than hydrocarbons?

1. Why do oxygenated fuels contain less energy than hydrocarbons?

Oxygenated fuels, such as ethanol and methanol, contain less energy than hydrocarbons because they have a lower heat of combustion. This means that when they are burned, they release less energy in the form of heat compared to hydrocarbons.

2. How does the presence of oxygen affect the energy content of fuels?

The presence of oxygen in fuels decreases their energy content because oxygen is an oxidizing agent. This means that it reacts with the fuel during combustion, resulting in a lower energy release.

3. Can the lower energy content of oxygenated fuels be compensated for?

Yes, the lower energy content of oxygenated fuels can be compensated for by using a larger volume of fuel. This is why in most cases, oxygenated fuels need to be used in higher concentrations than hydrocarbons to achieve the same energy output.

4. Are there any benefits to using oxygenated fuels despite their lower energy content?

Yes, there are several benefits to using oxygenated fuels. They have a higher octane rating, which can improve engine performance and reduce emissions. They also have a higher oxygen content, which can help to reduce carbon monoxide emissions.

5. What is the main reason for the use of oxygenated fuels?

The main reason for the use of oxygenated fuels is to reduce air pollution. They have a lower carbon content and produce fewer harmful emissions compared to hydrocarbons, making them a more environmentally friendly option.

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