Entropy is a scientific concept, as well as a measurable physical property that is most commonly associated with a state of disorder, randomness, or uncertainty. The term and the concept are used in diverse fields, from classical thermodynamics, where it was first recognized, to the microscopic description of nature in statistical physics, and to the principles of information theory. It has found far-ranging applications in chemistry and physics, in biological systems and their relation to life, in cosmology, economics, sociology, weather science, climate change, and information systems including the transmission of information in telecommunication.The thermodynamic concept was referred to by Scottish scientist and engineer Macquorn Rankine in 1850 with the names thermodynamic function and heat-potential. In 1865, German physicist Rudolph Clausius, one of the leading founders of the field of thermodynamics, defined it as the quotient of an infinitesimal amount of heat to the instantaneous temperature. He initially described it as transformation-content, in German Verwandlungsinhalt, and later coined the term entropy from a Greek word for transformation. Referring to microscopic constitution and structure, in 1862, Clausius interpreted the concept as meaning disgregation.A consequence of entropy is that certain processes are irreversible or impossible, aside from the requirement of not violating the conservation of energy, the latter being expressed in the first law of thermodynamics. Entropy is central to the second law of thermodynamics, which states that the entropy of isolated systems left to spontaneous evolution cannot decrease with time, as they always arrive at a state of thermodynamic equilibrium, where the entropy is highest.
Austrian physicist Ludwig Boltzmann explained entropy as the measure of the number of possible microscopic arrangements or states of individual atoms and molecules of a system that comply with the macroscopic condition of the system. He thereby introduced the concept of statistical disorder and probability distributions into a new field of thermodynamics, called statistical mechanics, and found the link between the microscopic interactions, which fluctuate about an average configuration, to the macroscopically observable behavior, in form of a simple logarithmic law, with a proportionality constant, the Boltzmann constant, that has become one of the defining universal constants for the modern International System of Units (SI).
In 1948, Bell Labs scientist Claude Shannon developed similar statistical concepts of measuring microscopic uncertainty and multiplicity to the problem of random losses of information in telecommunication signals. Upon John von Neumann's suggestion, Shannon named this entity of missing information in analogous manner to its use in statistical mechanics as entropy, and gave birth to the field of information theory. This description has been proposed as a universal definition of the concept of entropy.
Hi,
I am quite confused about followed question,
I think scientist think the last scattering surface was dense plasma at the temperature of 3000K. If the today's universe much cooler and less dense then "the last scattering surface" how can anyone says entropy increased by time? Isn't universe...
Homework Statement
Homework EquationsThe Attempt at a Solution
## dS = \frac { dQ_{rev} } { T } ##
Assuming that isothermal process is a reversible processes,
## dU = dQ – pdV##
For isothermal process, dU = 0.
## dQ = pdV ##
## pV = nRT##, where n is number of moles.
For one mole,
##...
Homework Statement
I am Pretty Lost with this problem...[/B]
A 2.45-kg aluminum pan at 155∘C is plunged into 3.58 kg of water. If the entropy change of the system is 162 J/K, what was the initial temperature of the water? NOTE:We did not receive a Tf for the system.
Homework Equations...
Thermodynamics is stated in different ways. E.g.
In isolated systems entropy never decreases
Heat never spontaneously pass from colder to warmer body
Total energy quality decreases in all processes.
Energy disperses
But what is it exactly? What is the correct description of the 2nd law of...
Homework Statement
A system having ##N## non-degenerate energy eigenstates populated by##N## identical spin-zero particles and ##2N## identical spin-half particles. There are no interaction between any of these particles. If ##N=1000## what is the entropy of the system?
Homework Equations...
Homework Statement
I came across this equation ##L / T = \Delta S## and am not too sure about its derivation.
From what I know, ##L = Q/m## and ##Q = TdS ##.
Substitution gives me ##\Delta S = mL / T## which isn't correct.
Could someone assist me in understanding the derivation?
Thanks...
I read this discussion but I am interested in how the entropy is obtained as a function of pressure. Namely, how can you determine a following integral for an ideal gas:
$$S(p) = -\int_{0}^{p} \frac{nR}{p}dp $$
when you need to start from 0 pressure?
As I understand it, horizons, such as black hole or cosmological event horizons is a place where time seems to stop. So if nothing changes at the horizon, then can there be entropy there? Does entropy require things to change with time? If not energy dissipates because nothing moves, then what...
Homework Statement
A container of 1.5 Kg of gas is at a temperature and pressure of 293 K and 1 bar respectively. The gas is adiabatically compressed until its temperature and pressure are 450 K, 4.49 bars. Adiabatic processes are processes with no heat transfer. The properties of this...
Homework Statement
Calculate q, w, ∆E, and ∆H for the process in which 93.0 g of nitrous oxide gas (N2O) is cooled from 179°C to 55°C at a constant pressure of 4.00 atm.
Cp(N2O) = 38.70 J K-1 mol-1
Homework Equations
q= mCΔT
ΔH=n(Cp)=n(qv)ΔT
ΔE=q+w
w= -pΔV
*Probably something else too but I'm...
I have a question regarding the process of getting towards equilibrium in our universe. If we imagine a causal patch with our planet at the centre, every planet will redshift away from us an after a while the planet itself will disintegrate, let's call this process the decay of Earth. Eventually...
Homework Statement [/B]
Phospine exist in three forms. known as the \alpha, \beta and \gamma forms. The \alpha and \beta forms are in equilibrium with each other at 49.43 \, K, and the \alpha and \gamma forms are in equilibrium at 30.29 \, K. Obtain the molar heat of transformation for the...
Homework Statement
Two vessels A and B each contain N molecules of the same perfect monatomic gas. Initially, the two vessels are thermally isolated from each other, with the two gases at the same pressure P and at temperatures T_A and T_B. The two vessels are now brought into thermal contact...
Homework Statement
Two systems that have the same heat capacity Cv but different initial temperatures T1 and T2 (with T2 > T1) are placed in thermal contact with each other for a brief time, so that some heat flows but the temperature of neither system changes appreciably. Show that there is a...
Homework Statement
Show that \Gamma_T is maximum at E_a = \frac{N_aE}{N_a+N_b}
Homework Equations
The expression for \Gamma(E) when N\gg 1
\Gamma_T = C_aC_b exp \left( -\frac{E_a^2}{2N_a\mu_B^2h^2} \right) exp \left[ - \frac{(E-E_a)^2}{2N_b\mu_B^2H^2} \right]
where C_a and C_b are...
Homework Statement
Formulate a proof that the energy minimum principle implies the entropy maximum principle. That is, show that if the entropy were not maximum at constant energy then the enrgy could not be minimum at constant entropy. HINT: First show that the permissible increase in entropy...
Homework Statement
Homework EquationsThe Attempt at a Solution
I didn't understand the last part.
At eqbm. ##\Delta S = 0##. This means that the RHS of the eqnn. 14.25 is 0.
This doesn't mean that the following eqns. must hold true.
##(\frac 1 T_1 - \frac 1 T_2) =0,.............(1)
\\...
So while practicing statistical mechanics problems I was faced with the following problem : calculate the entropy as function of energy for an ensemble of harmonic oscillators ( the Hamiltonian is ##\sum_{i=1}^N \frac {p_i^2} {2m} + \frac {m\cdot\omega\cdot q_i^2} 2##) ).
Now the official...
I'm interested in classical and quantum entropy. Is there a section on PF devoted exclusively to this topic? I searched a few forum discussions but couldn't find anything.
I'm new here. Thank you.
Homework Statement
The question is:
What happened with the entropy in a free expansion? The system is isolated and the state equation is:
$$p=AT/V+B/V^2$$
Homework Equations
$$dU=TdS-pdV$$
The Attempt at a Solution
My attempt is:
Because the system is isolated and corresponding to an free...
1. Robert Dehoff 4.12
A system is designed that permits continuous programmed control of the pressure and volume of the gas that it contains. The system is filled with 1 g atom of helium and brought to an initial condition of one atmosphere and 18 liters. It is then reversibly compressed to 12...
Is it ok to assume that the entropy ##S## of an arbritary system can be written as a power series as a function of the system's internal energy ##U##? Like
$$S(U) = \sum_{i=1}^{\infty}a_iU^i = a_1 U + a_2 U^2 + \ ...$$ with ##a_i \in \mathbb{R}##.
What results could be obtained from such...
There is a fascinating demo on YouTube of "32 metronomes synchronizing". They are all started at different times but in barely more than 2 minutes they are all synchronized and working as one unit. If you have not seen this then go to Google and type in "metronomes synchronizing".
Could somebody...
Can we always express the entropy of a given system as ##\partial U / \partial T##, i.e. as the variation of the internal energy of the system w.r.t. its temperature?
By always I really mean, in every discussion we are eventually engaged in. Like, when I want to talk about the evolution of the...
Our universe is considered a closed system. Law says that the entropy of a closed system is bound to increase.
Then how could living beings evolve when they are an extremely ordered system?
From what I have heard, entropy is the amount of energy that is unavailable to do work. What exactly does it mean by "unavailable energy", and can someone give some examples of energy being unavailable to do work in real life?
Homework Statement
The fundamental equation of a system of \tidle{N} atoms each of which can exist an atomic state with energy e_u or in atomic state e_d (and in no other state) is
F= - \tilde{N} k_B T \log ( e^{-\beta e_u} + e^{-\beta e_d} )
Here k_B is Boltzmann's constant \beta = 1/k_BT...
Homework Statement
Water vapor at 6 MPa, 600C enters a turbine operating at steady state and expands to 10 kPa. The mass flow rate is 2 kg/s, and the power developed is 2626 kW. Stray heat transfer and kinetic and potential energy effects are negligible. Determine (a) the isentropic turbine...
In classical mechanics, if a system consisting of one particle suddenly became two particles, the entropy of the system would increase because the number of spatial degrees of freedom would double. But, in QM, I believe, when one particle decays into two particles, the two new particles would be...
it seems it is not reasonable
Sorry
it said that delta S>=0
in an isolated system. i know why they put " = " sign, but i don't know why it is still possible that dS>0 in an isolated systembecause in an isolated system,it is said that dQ=0 (because no heat transfer between the system and the...
Homework Statement
This is a state ecuation of a gas:
PV=AT+B/V, where A and B there are constants.
First: Demonstrate that ##c_V## depends only of T
Second: Find U(T,V) and S(T,V)
Homework Equations
##\left(\frac{\partial U}{\partial S}\right)_V=T\text{ (1)}##
##\left(\frac{\partial...
Why do they introduce the partition function. I have seen it in the derivation of the Boltzmann distribution. But I don't know the physical significance of it here? And how do they get to (L.11) after that? I get everything until L.7. Including L.7.
The rest of the proof is here just in case...
I know that early oscillating models of the universe fail due to the second law of thermodynamics. One thing that I am unclear about is since as far as i know the laws of physics break down in a singularity can the second law of thermodynamics break down also?
When I see comments to the...
Dear community,
I stumbled upon this ecology article (https://www.witpress.com/elibrary/dne/4/2/402, page 4) and have some confusion about a statement in there:
"Before further unpacking the formal defnition of entropy, one would be justifed in asking why not simply choose (1 – p) instead of...
Hi everyone!
1. Homework Statement
Given is a function for the internal energy: ##U(T,V)=Vu(T)##
Asked is to derive the entropy balance equation. In order to do so i need to find the "isothermal and adiabatic compressibility": $$\kappa_{T}=-\frac{1}{V}\left(\frac{\partial V}{\partial...
In order to better explain my question let me give a precise situation and then state my question
Say I have a well insulated rigid container containing some mass m of a saturated liquid-vapor mixture of water at some pressure P1. Initially it's at some quality x1. An electric resistance heater...
Homework Statement
A 5.0-kg piece of lead at a temperature of is 600 Celsius placed in a lake whose temperature is 15 Celsius. Determine the entropy change of (a) the lead piece, (b) the lake, and (c) the universe.
mass of lead=5 kg
initial temperature of lead=873.15 K
final temperature of...
Entropy is often represented as a representation of disorder in a system or the amount of energy deposited as unusable in a system. What are the other perspectives about entropy?
Something I've always wondered: why do we measure the amount of disorder (entropy) rather than the amount of order?
We don't measure brightness by the amount of "dark". Surely order is the thing of interest, so why don't we measure that rather than measuring the absence of it?
And in...
Hello, I am a curious layman, so I might have some misconceptions. I have been pondering some questions, and I was hoping someone might be able to either confirm, or explain this. What I am wondering, if I am understanding this correctly, is why atoms do not experience entropy? If this is true...
Hi.
I found following exercise in a high school textbook:
"Compute the entropy change in following process:"
The solution is
"The number of particles decreases from ##N_1## to ##N_2=N_1/2##. Hence the entropy decreases by
$$\Delta S=-k\cdot N_1\cdot \ln{2}\enspace ."$$
I can't quite follow...
Hi. This is the problem 5.1-1 from the second edition of Callen's Thermodynamics. It says
Formulate a proof that the energy minimum principle implies the entropy maximum principle. That is, show that if the entropy were not maximum at constant energy then the enrgy could not be minimum at...
The Theory. Newton's Third Law of 1)Motion states: 'To every action there is an equal and opposite reaction'. ... The force exerted by the second body on the first body is called reaction. The action and reaction are equal and opposite.
2)Second Law of Thermodynamics : In any cyclic process the...
Why is it so much easier to increase the temperature of something than it is to decrease the temperature?
Why are refrigerators more complex than stoves?
I began reading Mehran Kardar's Statistical Physics of Particles and about halfway through the first chapter, there was a discussion on the second law of thermodynamics. He makes no mention of the old tenet that 'the total entropy in the universe must always increase' (I'll refer to this as the...
Is there something like ##\frac {dS\dt}=...## Like in the general system,
I know its always positive but I want to know is there any constant quantity of the universe like universe entropy increases amount of 45J/C or something like that.Or it depends only the knows closed systems which we ca...