Gases Definition and 501 Threads

Gas is one of the four fundamental states of matter (the others being solid, liquid, and plasma). A pure gas may be made up of individual atoms (e.g. a noble gas like neon), elemental molecules made from one type of atom (e.g. oxygen), or compound molecules made from a variety of atoms (e.g. carbon dioxide). A gas mixture, such as air, contains a variety of pure gases. What distinguishes a gas from liquids and solids is the vast separation of the individual gas particles. This separation usually makes a colorless gas invisible to the human observer. The interaction of gas particles in the presence of electric and gravitational fields are considered negligible, as indicated by the constant velocity vectors in the image.
The gaseous state of matter occurs between the liquid and plasma states, the latter of which provides the upper temperature boundary for gases. Bounding the lower end of the temperature scale lie degenerative quantum gases which are gaining increasing attention.
High-density atomic gases super-cooled to very low temperatures are classified by their statistical behavior as either Bose gases or Fermi gases. For a comprehensive listing of these exotic states of matter see list of states of matter.

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  1. fluidistic

    Thermodynamics, finding the fundamental equation of ideal gases

    Homework Statement An ideal monoatomic gas is characterized by the two equations PV=NRT and U=\frac{3NRT}{2} in which R is a constant. Find the fundamental equation corresponding to a monoatomic ideal gas. Homework Equations S=\left ( \frac{1}{T} \right ) U+\left ( \frac{P}{T} \right )...
  2. K

    Velocity distribution of particles in an arbitrary-arrangement of rotating gases

    If we have a "quasi-rigid" rotating convective cell where the gas overall rotates at the same angular velocity, we could establish a non-inertial frame of reference co-rotating with this convective cell such that the particles of the gas (seen from that frame of reference) may follow a...
  3. C

    Why are gases more viscous at higher temps?

    I'd expect that since they carry more kinetic energy, they are more fluid. Thanks!
  4. fluidistic

    What Formula Should Be Used for Thermodynamics of Two Gases?

    Homework Statement Two particular systems separated by a diathermic wall have the following equations of state: \frac{1}{T^{(1)}}=\frac{3}{2}R \frac{N^{(1)}}{U^{(1)}} \frac{1}{T^{(2)}}=\frac{5}{2}R \frac{N^{(1)}}{U^{(2)}} where R=1.986 cal/mol K, N^{(1)}=2 and N^{(1)}=3. Homework...
  5. A

    How Do You Calculate Kc and Kp for a Reversible Gas Reaction?

    Homework Statement When 1.000 mol PCl5 is intorduced into a 5.000L container @500K, 78.50% of PCl5 dissociates to give equilibrium mixture PCl5, PCl3, Cl2 : PCl5--->PCl3+Cl2 (this eq. is reversible) (a) calculate Kc and Kp (b) if the initial concentrations are [PCl5]=.500M...
  6. C

    Ionization Energies Of Noble Gases

    Homework Statement I was going through my past question and answer, I then came across this: "The noble gases have the highest ionization energies in each period". I then wondered why and how the above statement is a reality. How can the above statement be true when the noble gases have...
  7. P

    How Does Resonance Affect Greenhouse Gas Absorption?

    Hi, I am now learning about climate change and have come across resonance. When I previously studied SHM however, I learned about resonance, and I believe I have a good understand of what it means. If the frequency of a driving force matches the natural frequency of the system, this leads to...
  8. J

    Does Internal Energy of an Ideal Gas Change with Heat Transfer?

    Homework Statement Hey guys, I am having trouble understanding how the ideal gases behave and I got these 3 questions in homework: If an ideal gas is transferred, at constant temperature, 10 Joules of heat, does the internal energy change? If an ideal gas is transferred, at constant...
  9. T

    Why Does Balloon Volume Decrease with Liquid Nitrogen?

    50 minutes into this video the professor puts a balloon into liquid nitrogen that's about 1/4 of the room temperature, but its volume decreases to much less than 1/4 of its original volume. Why? Right after the balloon demo, he talks about tennis balls. Why if you open up a can of tennis...
  10. Rapier

    How does pressure affect work done in ideal gases?

    Homework Statement I want to start by saying that my instructor is a particle physics guy. He loves to talk about particles seems to want to rush through fluids and thermo so he can get to particles and the 'real modern physics.' He is skipping, skimming and not really covering a lot of this...
  11. stevmg

    Name of intermolecular forces of gases

    For a non-ideal gas expanding in a vacuum, the kinetic energy of each of the molecules does NOT remain consant as the gravitational effect of the other molecules would "slow down" these velocities by deceleration. What are those forces referred to? Are they "Newton" forces or what? I can't...
  12. X

    Ideal gases thermodynamic enthelpy and internal energy change

    Homework Statement See attachment ecxample001. Homework Equations See attachment D11. The Attempt at a Solution In the first equation (Cp/R = a+bT+cT^2...etc.), Cp/R is the constant pressure specific heat. The general formula for enthalpy change is h2-h1 = integral[Cp]dT, so does...
  13. M

    Why Some Materials Are Sensitive to Gases & How Doping Affects Them

    hi.. please tell me that 1) why some materials like ZnO, SnO, Pt, etc r sensitive to gases and others like Si, Ge, InP, GaAs, etc r not sensitive to gases. 2) how doping increase the sensitivity of a certain material to certain gases.
  14. M

    Questions on the kinetic molecular theory of gases

    Hello,world 1-"the intermolecular attractive forces between gas particles are very weak due to the large intermolecular distances separating them" Is that true? this is wriiten in my textbook and it is confusing me because I've always thought of it in a different way ,I thought the...
  15. D

    Is there a Conceptual problem here? (Pressure in the Kinetic theory of gases)

    I have reviewed recently the demonstration of the formula for the pressure of a gas by using the kinetic theory and it seems that there is a terrible flaw in it, which I will describe below. Can anyone comment on it, please? In all textbooks, the pressure of a gas is proven to be proportional...
  16. B

    Interacting gases - Thermodynamics question

    Homework Statement 2.0g of helium at an initial temperature of 300K interacts thermally with 8.0g of oxygen at an initial temperature of 600K . What is the initial thermal energy of each gas? What is the final thermal energy of each gas? How much heat energy is transferred, and in...
  17. P

    How Do We Calculate the Kinetic Energy of Gases in Stars?

    Hi, I have a conceptual and mathematical question about gases in stars. The information we have from stars is due to the motion of particles in one dimension: along our line of sight. We assume that this motion is isotropic and that regardless of where on the star we look, we'll get the...
  18. P

    Kinetic energy of gases in stars

    Hi, I have a conceptual and mathematical question about gases in stars. The information we have from stars is due to the motion of particles in one dimension: along our line of sight. We assume that this motion is isotropic and that regardless of where on the star we look, we'll get the...
  19. DaveC426913

    Medical Which Liquid Gases Do Hospitals Use and Why Are They Warmed?

    On the way into work, I pass through "Hospital Alley". I saw a collection of Praxair tanks with radiating fins that were covered in ice. If you put fins on something that's cold, it will warm up faster. I was trying to figure out why they would have a system that was designed to warm up the...
  20. E

    Thermodynamics question - Ideal gases

    A rigid tank with a volume of 0.75 m3 initially contains air at 70 kPa and 25 degrees C. A small hole develops in the tank. The surrounding air at 100 kPa and 25 degrees C slowly leaks into the tank due to the hole. Heat transfer between the surroundings and the tank maintains a constant air...
  21. B

    Kinetic Molecular Theory of Gases

    Hello, So, I am reading this theory, and I come across this sentence explaining to me that gas particles of different mass have the same average kinetic energy at a particular temperature. Is this somehow due to momentum? Each particle is given a certain energy which will cause them to move...
  22. J

    Gases and thermodynamics in confinement.

    Hi. Consider a plenum with a small restricting outlet. Highly heated gas constantly flows through the plenum, and a build-up, or congestion of high-pressure gas exists in the plenum due to the restricting outlet pipe. The intake flow of gas does not change. 1. A hotter plenum should...
  23. B

    Why Does One Mole of Any Gas Occupy Same Volume?

    Okay, I have searched the internet for why one mole of any gas occupies the same volume, and found the internet devoid of any explanation that will suffice in my understanding. Can someone please help me Thank you
  24. O

    Boltzmann distribution of two different gases

    hi everyone, consider two different masses of ideal gases with different molar masses, we're putting them in a uniform gravitational field and wait until they come to their equilibrium states. how would the density distribution change with height in this case? ( i came out with this question...
  25. N

    Mean Free Path of Gases with Bulk Velocities

    Hello all, I'm modeling a situation in which a gas moves through a pressure gradient established by a quartz frit with 40-100 μm sized pores. What I'm interested in finding out is how the mean free path of the gas changes after it exits the frit region, if at all. I think that the mean...
  26. F

    Calculating Energy Lost Due to Flue Gases

    Hi! I'm working on problem, where I have to estimate energy, lost due to flue gases, i.e. some amount of natural gases burned in some time period, say [t0;t1]. Burning is used for some material heating. I need to find energy, lost by gases (gases, after combustion), which goes out from flue...
  27. L

    Reversible vs. Irreversible change (gases)

    Homework Statement I know how to do the problem so I don't need help actually solving it, I just don't understand the concepts. A sample of 4.5g of methane occupies 12.7L at 310k. a) Calculate the work done when the gas expands isothermally against a constant external pressure of 7.7 kPa...
  28. R

    Problem about adiabatic expansion of gases

    Hello everyone. I would like to know if I did this correctly. Homework Statement Calculate the heat, internal energy and work of 1 mol of hydrogen, which undergoes a reversible adiabatic expansion from a volume of 5.25 m^3 at 300 K to a volume of 25.5 m^3 The Attempt at a Solution...
  29. J

    Thermodynamics specific volume, heat, & ideal gases

    Homework Statement I attached the problems. The first one is D) at the top of the page parts a) and b). The second one is E) at the top of the second attachment. 1) The rigid tanks shown below have volumes of .4m^3 and .004^3 respectively and each contains a water liquid-vapor mixture of...
  30. T

    What's a good book for 'Thermodynamics and kinetic theory of gases'?

    The main book we'll be using will be Serway's, but I want a different book that's more focused on the mathematics formulation of thermodynamics and kinetic theory of gases, and not so simple as Serway's. The other 3 books in the discipline's bibliography are: • M.W. Zemansky and R. H...
  31. T

    Calculate a values given equation of state for gases

    Calculate "a" values given equation of state for gases Homework Statement For my equation of state: Vm = (RT/P) - (a/T) what kind of sign for the constant a (positive or negative) do you think the following gases will have and why: a. H2 b. He c. CH4 d. CO2 Hint: There is almost no...
  32. D

    Entropy of Mixing for Two Ideal Gases at Different Temperatures

    Homework Statement Two monatomic ideal gases are separated in a container by an impermeable wall, with volumes V_{1} and V_{2}, temperatures T_{1} and T_{2}, number of atoms N_{1} and N_{2}, and both are at the same, constant pressure P. The wall is then removed, and the pressure is continued...
  33. I

    Combustion and expansion of gases?

    I think most of us have probably seen the little trick in which somone will place a burning candle in a bottle and get something like an egg to be pushed inside the bottle. How does this happen? I understand that a vacuum is created inside the bottle, and the normal outside air...
  34. M

    Exploring Crookes Dark Space in Low-Pressure Gases

    Homework Statement From the book: "When electrodes are placed in a gas at normal atmospheric pressure no current passes and the gas act as an insulator until the electric field is increased to above 3 or 4 MV/m when sparking takes place. In crontast, at lower pressures, a steady current can be...
  35. M

    Can the heat equation apply to gases?

    I've never known this but the equation only seems to contain a conduction term so I assume it can only apply to solids. Is there a similar equation for the time-evolution of temperature fields in gases, where convection is also considered? (how about radiation? although that sounds like it will...
  36. G

    Is there a correlation between compressibility factor and temperature in gases?

    Hi I would like to ask is there any relation between compressibility factor of gases and temperature? My textbook says that it always increases with increase in temperature but doesn't explains how? I know that on increases the temperature it is harder for molecules to show attractive...
  37. J

    Design of a mixing box of different gases

    Hi guys, I am designing a mixing box for different gases. Here is my plan: I will use Acrylic panels with the dimension of 30cm x 30cm x30cm. Two 3/4 inch pipes feed inflows at flow rate of 1300 LPM in total. The outlet is an rectangular opening of 8cm x 8cm. How can I define the pressure inside...
  38. M

    Kinetic theory of gases - Maximum speed

    If the aleatory speed of a gas rises with pressure and temperature and there is not an apparent limit for these two, what prevents the particles to reach the speed of light? thank you
  39. E

    Atmospheric Gases - absorption, reflection, and emission of radiation

    I'm going to be very careful to avoid the word "greenhouse" because of the indefinite ban on discussions about climate change - I want to be clear, this isn't a topic about that. Part 1 - some gasses in the atmosphere absorb and emit radiation in the thermal infrared range. Gases like water...
  40. B

    Question about gases and kinetic theory

    i have a question that I cannot solve; Show that the rms velocity of a sodium atom moving in a vacuum chamber at 300 kelvin is about 570 metres per second pV=nRT and 3pV=Nm<c^2>
  41. J

    Work and Ideal Gases: Calculate Initial Volume

    Homework Statement One mole of an ideal gas does 1975 J of work on the surroundings as it expands isothermally to a final pressure of 1.2 atm and a volume of 24 L. find the initial volume. The universal gas constant is 8.31451 J/K mol The Attempt at a Solution Something he...
  42. O

    Which Formula Should I Use to Calculate the Kinetic Energy of Gases?

    in the picture you can see Three different tanks contain Three different gases. the temperature are equal to 25 Degrees Celsius in all the Three tanks, and it not changing. i asked to calculate the kinetic energy of the Three different gases. so i thought to use this formula:3/2*RT but i...
  43. O

    Final pressure when two gases at different pressure

    final pressure when two gases at different pressure are mixed. The valve between a 5-L tank containing a gas (Methane) at 3 atm and a 1-L tank containing a gas ( Ethane) at 0.55 atm (both are in 50 Degrees Celsius) is opened. What is the final pressure in the tanks? (assume that there is no...
  44. E

    Maxwell-Boltzman Distribution for Ideal Gases (Thermodynamics)

    I just have a question of this subject, it is a pretty straight forward concept, however there are things that i just can;t figure out, like in any given gas which is the minimum volume required to have a maxwell boltzman distribution, @ 1 atm 273.15 K ? I honestly just can't figure it out...
  45. C

    Material Balance Problem Involving Ideal Gases- Any ?

    Homework Statement A furnace is fired with 1000 feet cubed per hour at 60 degrees F and 1 atm of a natural gas containing the following volumetric analysis: CH4: 80%, C2H6: 16%, O2: 2%, CO2: 1%, and N2: 1%. The exit flue gas temperature is 800 degrees F and the pressure is 760 mm Hg absolute...
  46. E

    Transition of Mechanical Waves (Solids to Gases and vice versa)

    As a hobby, I have been researching the different aspects of modeling the sounds produced by musical instruments. Particularly, I want to create as accurate a model as possible, and not something very simple (to which many may ask "why?" if complexity will reduce the likeliness of real time...
  47. B

    Quick question about pressure in gases.

    Two gases are in a vessel and separated by a partition. They start at different pressures P1 and P2. When the partition is removed and equilibrium restored am I right in thinking the new pressure is the average of the starting pressure i.e. P_{f} = \frac{P1+P2}{2} Thanks.
  48. R

    Slater orbitals for alkali earth metals and noble gases

    Hello Forum, Does anyone know where I can find the slater bases for the alkali metal 'np' orbitals and the noble gas '(n+1)p' orbitals, either altogether or individually? I'm a physicist and wanted to know what the standard (or even non-standard) reference is? I know that the...
  49. O

    Properties of Gases: Volume Change with Cooling & Pressure Increase

    Homework Statement A volume of 2.40x10^-3 m^3 of hydrogen gas is enclosed in a cylinder with a movable piston at 300 K under a pressure of 203 kPa (2.00 atm). The density of hydrogen under these conditions is 0.180 kg m^3. 1. The gas is cooled down to 150 K, and the pressure is increased to...
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