Hydrogen is the chemical element with the symbol H and atomic number 1. With a standard atomic weight of 1.008, hydrogen is the lightest element in the periodic table. Hydrogen is the most abundant chemical substance in the universe, constituting roughly 75% of all baryonic mass. Non-remnant stars are mainly composed of hydrogen in the plasma state. The most common isotope of hydrogen, termed protium (name rarely used, symbol 1H), has one proton and no neutrons.
The universal emergence of atomic hydrogen first occurred during the recombination epoch (Big Bang). At standard temperature and pressure, hydrogen is a colorless, odorless, tasteless, non-toxic, nonmetallic, highly combustible diatomic gas with the molecular formula H2. Since hydrogen readily forms covalent compounds with most nonmetallic elements, most of the hydrogen on Earth exists in molecular forms such as water or organic compounds. Hydrogen plays a particularly important role in acid–base reactions because most acid-base reactions involve the exchange of protons between soluble molecules. In ionic compounds, hydrogen can take the form of a negative charge (i.e., anion) when it is known as a hydride, or as a positively charged (i.e., cation) species denoted by the symbol H+. The hydrogen cation is written as though composed of a bare proton, but in reality, hydrogen cations in ionic compounds are always more complex. As the only neutral atom for which the Schrödinger equation can be solved analytically, study of the energetics and bonding of the hydrogen atom has played a key role in the development of quantum mechanics.
Hydrogen gas was first artificially produced in the early 16th century by the reaction of acids on metals. In 1766–81, Henry Cavendish was the first to recognize that hydrogen gas was a discrete substance, and that it produces water when burned, the property for which it was later named: in Greek, hydrogen means "water-former".
Industrial production is mainly from steam reforming natural gas, and less often from more energy-intensive methods such as the electrolysis of water. Most hydrogen is used near the site of its production, the two largest uses being fossil fuel processing (e.g., hydrocracking) and ammonia production, mostly for the fertilizer market. Hydrogen is problematic in metallurgy because it can embrittle many metals, complicating the design of pipelines and storage tanks.
If you draw lewis structure, central atom (N) will have 1 lone pair and 4 single bonds with Hydrogen.
Why can't hydrogen in this ion molecule be able to form hydrogen bonding with other molecules alike?
Is it because there's only 1 electron on the central atom?See for yourself: 5N + 4H -1 = 9...
Homework Statement
I am wondering, is it possible to predict the vibrational frequency of D2 from H2, supposing vibrational frequency of H2 is 4400cm-1?
Homework Equations
...
The Attempt at a Solution
From what I know, H2 has two H's, meaning 2 protons and 2 electrons, whereas D2 has 2...
Today I was studying Atkins physical chemistry basics and I saw a bit of incoherence.
ΔrG°=ΔrH°-TΔrS°
ΔrG°=ΔfG°(products) - ΔfG°(substrates)
ΔrG°=nFE°
Data: ... ΔfH° ... ΔfG°...ΔS°(J*K*mol-1)
H2(g)...0......0......130,684
H+......0.....0.....0
2H+(aq) 2e- => H2(g)
Using second and third...
if you take a hydrogen atom and strip off the electron so that you are left with a proton. does the proton have energy levels around it? can a solitary proton still be regarded as an atom (H+)
I've been wondering what is up with hydrogen. It shares little more than basic commonality with any other atom, this strikes me as strange as all atoms share some properties with those around them on the periodic table whether be it nuclear, physical, or chemical. I asked a reputable source and...
Homework Statement
I know this question has been asked before, but I am looking for a different kind of answer than the other poster. Bear with me here.
Problem: For a hydrogen atom in the ground state, what is the probability to find the electron between the Bohr radius a0 and (1.01)a0...
If the hydrogen gas is supposed to emit photons when the electrons undergo excitation, then why did the gas absorb energy earlier and got the electrons excited?
Hi there.
The energy used for hydrogen production can be recovered using the buoyancy force of the gas created at sufficient depth of water.
Suppose we use electricity to split ocean water to produce hydrogen. Then the produced gas is captured into containers which are attached to a conveyer...
Hi,
I wanted to ask, what does the density of a hydrogen cloud in space depend upon?
That might be a silly question given the definition of density, but here's the context;
Considering a particle at rest within a molecular cloud at radius r from the centre, I have shown that the acceleration...
From the ground state wave equation the most probable outcome of anyone measurement will be in the center of the atom, at the nucleus. The expectation value is found to be the Bohr radius.
So does this mean that if you measure the position of an electron in a hydrogen atom in the ground state...
Homework Statement
(a) What is the minimum kinetic energy in electron volts that an electron must have to be able to ionize a hydrogen atom (that is, remove the electron from being bound to the proton)? Answer: 13.6 eV
(b) If electrons of energy 12.8 eV are incident on a gas of hydrogen...
Homework Statement
When displaced from equilibrium by a small amount, the two hydrogen atoms in an H2molecule are acted on by a restoring force Fx=−k1x with k1 = 500N/m.
Calculate the oscillation frequency f of the H2 molecule. Use meff=m/2 as the "effective mass" of the system, where m is the...
Homework Statement
During fusion of hydrogen to helium, 4 billion kg of matter are converted
to energy each second. What fraction of the Sun’s total mass is lost each
year to this process?
Homework Equations
None.
The Attempt at a Solution
First:
Convert how many seconds are there in a year
1...
If a symmetric distribution of charge has no electric dipole moment, where does the \mu term we write in the part of the hamiltonian representing interaction with light come from? We suppose it is induced by the electric field of the light?
Homework Statement
The distance between the both nucleons in the H2 molecule is 0.0741 nm
The energy for the 3 lowest radiation levels of the molecule are:
##E_{0}=0 \\
E_{1}=0.0151 eV \\
E_{2}=0.0453 eV##
How many revolutions per second does the molecule rotate with in the different states...
After reading this article, Water Vapor Found on Neptune-size Alien Planet - http://www.space.com/27251-water-found-neptune-size-exoplanet.html, I was wondering what other reactions would occur within the atmosphere of the planet as a result of the combination of oxygen at 25% to the 90% volume...
Homework Statement
Hello! I am trying to derive the ground state enegry of a hydrogen atom, and have come to
U=\frac{-mk_{0}^{2}Ze^{4}}{n^{2}\hbar^{2}}
Problem is, I know there should e another factor of 2 in the denomenator because I get the ground state energy of hydrogen as being 27.145eV...
Hi all,
I was always of the belief that hydrogen did not belong to any group in the periodic table. After discussions, some say that a group 1 or 7 place might be more suitable. Any opinions would be welcomed hopefully from a physics point-of-view on this topic.Thanks in advance
Does electron excitation for atoms above hydrogen happen at the valence before the core electrons first?
I know that for a gamma ray it is due to the excitation within the nucleus, but what about for normal emission spectra.
Do we just shine a bunch of different energy onto the atom and...
In our electrolysis of brine, Cl2 & H2 are produced as gaseous products along with aqueous NaOH. In this scenario I require what amount of maximum moisture can Cl2 or H2 hold up at specific temperature & pressure (precisely 85celsius & 1.2bar absolute). Two coolers (shell/tube exchanger with...
Homework Statement
why acyl chloride can't form hydrogen bond?
there's C=O , which O atom can form hydrogen bond . am i right?Homework Equations
The Attempt at a Solution
Would one expect the emission and absorption spectral lines for Hydrogen to be at slightly different frequencies ? So if electrons are excited to higher energy levels on absorption of photons and then fall back down again emitting photons, would there be any difference in frequency. Assuming...
Homework Statement
What is the magnitude of the electric force a hydrogen nucleus exerts on its only orbiting electron in the Bohr model?
The Attempt at a Solution
Fe = kQq/r^2
Since there is one proton and one electron. Q and q are equal to each other: 1.6 x 10^-19.
k = 9 x...
Hi,
I was wondering why there is no liquid hydrogen in space? Space is very cold, more cold then the temperature that is required to convert gas hydrogen to liquid here on earth? Therefore, why is hydrogen in space in gas form and not liquid?
Thanks
So I'm trying to use the excitation law of Boltzmann and the ionisation law of Saha to calculate stuff about what percentage of a quantity of hydrogen in ionised and in what energy state. I have the temperature and energy levels values, so i still need the:
-statistical weight (degeneracy)...
Hi
I have a new formula (or at least I think it's new) for predicting the wavelengths/frequencies of hydrogen's spectral lines. Please take a look and tell me if it is new. I am quite confident that it works because Bohr's original formula 'falls out' if one approximates cos(x) as 1 + x^2/2...
I was looking through a physics book that has the answers in the back.
this is not homework. It asks about a neutral beam of hydrogen atoms going into a strong non-constant B field. It asks how many ways will the beam split. It says the answer is 2.
Why is the answer not 3. spin 1, spin 0...
I can tell this is simple, but I'm just not seeing it: (pages 146-147)
Radial equation = d^{2}u/dp^{2} = [1 - p_{0}/p + l(l+1)/p^{2}]u
Later... (having stripped off the asymptotic p^{l}e^{-p} parts)
d^{2}u/dp^{2} = p^{l}e^{-p}{[-2l-2+p+l(l+1)/p]v + 2(l+1-p)dv/dp + p*d^{2}v/dp^{2}}
And he...
Hi,
I'm curious about J.J thomsons Catode ray, and i have a few questions:
In J.J. Thomsons Catode ray setup he has hydrogen gas in a chamber through which the catode ray is beamed. What is the role of hydrogen gas? What could he use the hydrogen gas for?
And how could he make up...
I need help with something that i seemed to remember was fairly easy, but just can't seem to find the simple formula for:
I have an amount of hydrogen atoms at a temperature of 10000 Kelvin. What percentage of them are ionised and what percentage of them are in the n=2 excited state...
hello,
i need the values for the absorption cross sections of positive hydrogen ions for a specific set of wavelengths, Halpha to start with. At first i thought finding this on the web was easy, but turns out to not be trivial at all. If you can help me, i also need the (reliable) source...
It is given in my book that " If the spectral lines are expresses in terms of Wavenumber, then the visible lines of the Hydrogen spectrum obey the following formula:
Wavenumber = 109,677(1/22 - 1/n2)
Here, I cannot understand that how can the visible lines be expressed in terms of...
In his lectures on quantum mechanics, Feynman treats the hydrogen molecule as a two-state system to give a general understanding of the covalent bond. He starts with base state |1> as electron a in ground state of left proton and electron b in ground state of right proton and base state |2> as...
I am working on the Hydrogen atom and I was trying to calculate \frac{d<r>}{dt} using \frac{d<r>}{dt} = \frac{i}{\hbar} <[\hat{H} , \hat{r}]>. Here r = \sqrt(x^2 + y^2 + z^2) and H = \frac{p^2}{2m} + V where p^2 = -\hbar^2 \nabla^2 . Now according to Ehrenfest's theorem <r> should behave...
Hi,
Does anyone know what is the energy loss of splitting water to hydrogen and then convert it back to energy?
hpw much energy do you need for making 1 KWh?
thank you,
Sami
Hey!
I did an quantum mechanical analysis of a Hydrogen Atom in a homogeneous magnetic vector potential (I know that it might be impossible to create this kind of field) out of curiousity. I showed it to some professors of mine, but they all said that they don't have time. So I decided to post...
Hi everyone, I've been reading articles and looking at many websites for methods to measure hydrogen peroxide residue concentration in lake water, waste water and ocean water as well as in cell extract in situ . But I'm not satisfied. sometimes they seem too complicated and may require a lot of...
The eigenstates of a hydrogen atom are stationary states with definite values of energy. Now, as I understand it, the quantum mechanical state of the electron in the hydrogen atom is really a linear superposition of all these energy eigenstates. So this should mean that there is a finite...
I'm in the first of 3 courses in quantum mechanics, and we just started chapter 4 of Griffiths. He goes into great detail in most of the solution of the radial equation, except for one part: translating the recursion relation into a form that matches the definition of the Laguerre polynomials...
Homework Statement
Part (a): What's the origin of that expression?
Part(b): Estimate magnetic field, give quantum numbers to specify 2p and general nl-configuration
Part (c): What is the Zeeman effect on states 1s and 2s?
Homework Equations
The Attempt at a Solution
Part (b)
H =...
Homework Statement
Does adding a proton change the atom's orbital angular momentum? Find the probability that the energy is unchanged.
Homework Equations
The Attempt at a Solution
The orbital angular momentum is unchanged, since ##<L^2> = l(l+1)\hbar^2## is independent of Z...
Hello, I have been studying the early universe where everything was a bunch of hydrogen atoms and helium atoms. Apparently they calculated the %composition of the universe at the time. How did they do that? What sort of equations can be used to calculate these quantities?
Homework Statement
What quantum numbers are used to define state of hydrogen? The wavefunction has no angular dependence. Find the values of all the angular momentum quantum numbers for the electron.
Homework Equations
The Attempt at a Solution
The numbers are n, l and m.
n: Energy level...
Homework Statement
I solved the Schrödinger equation, obtaining a wave function in terms of Radial and the spherical harmonics as follows:
$$Ψ(r,0)= AR_{10} Y_{00} + \sqrt{\frac23} R_{21} Y_{10} + \sqrt{\frac23} R_{21} Y_{11} - \sqrt{\frac23} R_{21} Y_{1,-1}$$
Homework Equations...
Homework Statement
A hydrogen atom is in the n=3 state. Given that a magnetic field is present, how many photons of different energy can we observe when the atom de-excites to the ground state?
Homework Equations
quantum number, angular momentum quantum number, orbital magnetic quantum...
From the calculations of total energy on an energy level we end up with rhe equation which consists of constants only, except of the principal quantum number.
Since equation does not include any unique variables, such as number of protons or electrons in an atom, what makes then different atoms...
Homework Statement
Part (a): Explain origin of each term in Hamiltonian. What does n, l, m mean?
Part (b): Identify which matrix elements are non-zero
Part (c): Applying small perturbation, find non-zero matrix elements
Part (d): Find combinations of n=2 states and calculate change in...