Molecule Definition and 462 Threads

A molecule is an electrically neutral group of two or more atoms held together by chemical bonds. Molecules are distinguished from ions by their lack of electrical charge.
In quantum physics, organic chemistry, and biochemistry, the distinction from ions is dropped and molecule is often used when referring to polyatomic ions.
In the kinetic theory of gases, the term molecule is often used for any gaseous particle regardless of its composition. This violates the definition that a molecule contain two or more atoms, since the noble gases are individual atoms.A molecule may be homonuclear, that is, it consists of atoms of one chemical element, as with two atoms in the oxygen molecule (O2); or it may be heteronuclear, a chemical compound composed of more than one element, as with water (two hydrogen atoms and one oxygen atom; H2O).
Atoms and complexes connected by non-covalent interactions, such as hydrogen bonds or ionic bonds, are typically not considered single molecules.Molecules as components of matter are common. They also make up most of the oceans and atmosphere. Most organic substances are molecules. The substances of life are molecules, e.g. proteins, the amino acids they are made of, the nucleic acids (DNA & RNA), sugars, carbohydrates, fats, and vitamins. The nutrient minerals ordinarily are not molecules, e.g. iron sulfate.
However, the majority of familiar solid substances on Earth are not made of molecules. These include all of the minerals that make up the substance of the Earth, soil, dirt, sand, clay, pebbles, rocks, boulders, bedrock, the molten interior, and the core of the Earth. All of these contain many chemical bonds, but are not made of identifiable molecules.
No typical molecule can be defined for salts nor for covalent crystals, although these are often composed of repeating unit cells that extend either in a plane, e.g. graphene; or three-dimensionally e.g. diamond, quartz, sodium chloride. The theme of repeated unit-cellular-structure also holds for most metals which are condensed phases with metallic bonding. Thus solid metals are not made of molecules.
In glasses, which are solids that exist in a vitreous disordered state, the atoms are held together by chemical bonds with no presence of any definable molecule, nor any of the regularity of repeating unit-cellular-structure that characterizes salts, covalent crystals, and metals.

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  1. J

    A How to obtain the spectrum for a given atom or simple molecule?

    The Bohr atom gave the answer to the spectrum of the hydrogen atom. But the spectra of stars contains many absorption (and sometimes emission) lines, corresponding to most atoms (up to iron, I believe). And atmospheric absorption is also due to absorption of some molecules, such as water...
  2. Fabrizio Vassallo

    B What is the volume occupied by a molecule?

    Hello, I'm trying to calculate what is the effective volume of a molecule of N2 in the most precise way possible (I'm a high school student so "in the most precise way possible" is probably not that precise considering my lack of advanced mathematical knowledge). What I want to know is, if I had...
  3. L

    Density matrix of an ammonia molecule

    In ##t = 0##, we have ##\rho (0) = | + \rangle \langle + |##. The time evolution of the density matrix is given by ##\rho(t) = e^{-i\hat{H}t} \rho (0) e^{i\hat{H}t}## (I am considering ##\hbar = 1##). I can write the state ##| + \rangle ## as a linear combination of the eigenstates of the...
  4. L

    I Can the Energy of Ammonia Molecule Be Defined in a Non-Eigenstate State?

    We can consider the ammonia molecule ##NH_{3}## a two level quantum system, because the ##N## atom can be either above or below the plane formed by the three ##H## atoms. We call these states ##|+ \rangle## and ##|- \rangle##, respectively. The hamiltonian in the basis ##(|+ \rangle, |-...
  5. Igor 77

    A Radioisotope-induced radioactivity in a protein molecule

    Dear Forum Members, I am a molecular biologist. One of my projects is focused on the identification of a protein that interacts with a known organic molecule. Namely, I try to chase a transmembrane protein that is known to transport one organic acid. If possible, I would like to get an idea on...
  6. navneet9431

    Does the Potential Energy increase during Chemical Bonding?

    Hi All, The Potential Energy for two chemically bonding atoms is defined by ,U=1/2(k*q1*q2)/r So it means that when the atoms approach each other then, their Potential Energy will increase. Where am I doing wrong? I will be thankful for help!
  7. Ryan Walsh

    Question about metallic ions and a molecule

    Cobalt(II) Copper(II) Copper(II) tetrachloro complex Chromate Vanadyl(V) (pervanadyl) Dichromate Can these metallic ions make up a certain molecule?
  8. MathematicalPhysicist

    How to simplify the diatomic molecule Hamiltonian using an expansion?

    Homework Statement I have the diatomic molecule hamiltonian given by: $$-\hbar^2/(2\mu)d^2/dr^2+\hbar^2\ell(\ell+1)/(2\mu r^2)+(1/4)K(r-d_0)^2$$ Now it's written in my solutions that if we put: $$K\equiv 2\mu \omega_0^2, \hbar^2\ell(\ell+1)/(2\mu d_0^4)\equiv \gamma_{\ell} K, r-d_0\equiv...
  9. M

    What is quantum physics and how can I learn more about it?

    So I love Quantum but unfortunately I don't have much idea of what its about. I would love to grasp the concept better. Can anyone discuss it with me?
  10. R

    Moment of Inertia of an Ammonium Molecule

    Homework Statement The ammonium ion NH4+ has the shape of a regular tetrahedron. The Nitrogen atom (blue sphere) is at the center of the tetrahedron and the 4 Hydrogen atoms are located at the vertices at equal distances L from the center (about 1 Å). Denote the mass of the hydrogen atoms by Mh...
  11. Y

    Angular frequency of an ammonia molecule

    Hello 1. Homework Statement The dipole moment of an ammonia molecule is ##d_0=5*10^{-30} C.m##.If we apply a static electric field of ##\mathcal { E }=1*10^{6 }V*m^{-1}## to an ammonia molecule initially in the state ## |ψG⟩## where the nitrogen molecule is considered to be on the left,we make...
  12. HCverma

    Is Carbon a Mono-Atomic Molecule?

    Is C a mono-atomic molecule? As I know molecules made of two or more than two atoms such as O2, N2, HCl etc but what's about carbon? like below C + O2 = CO2 Could you please explain the matter so that I can understand the concept well?
  13. HCverma

    Chemistry How to calculate the maximum charge of an atom or a molecule

    Homework Statement How to calculate the maximum charge of an atom or a molecule? As we know the equivalent weight = atomic weight / maximum charge Al, Ca and O2The Attempt at a Solution Al, E = 27/3 = 9 Ca, E = 40/2 = 20 O2, E = 16/2 = 8 I see on the books that the charges of Al, Ca and O2 are...
  14. HCverma

    Difference between 1 mole of CH4 and 1 molecule of CH4?

    Is there any difference between 1 mole of CH4 and 1 molecule of CH4? or they mean the same thing?
  15. C

    Pressure on Piston: Conservation of Energy Explained

    Homework Statement Suppose there is a tank filled with water and a piston of area S exerts a force F on the water. Suppose I divide the water boundary touching the piston to - N small equal " square " molecules. Then , the force on the upper face of each molecule is F/N . Also, the area of...
  16. R

    Quick question - orientation of a hydrophobic / hydrophilic molecule

    Hi, I am looking at how molecules with hydrophobic and hydrophillic properties move and orientate themselves in water. If I have say a PFOS molecule... The hydrophobic part (the perfluoroalkyl group - the carbon chain) will move to the liquid surface but the hydrophillic part (the sulfonate...
  17. A

    Term symbol of a molecule in an excited state

    Homework Statement Considering the molecule of ##C_2^+## in an excited state with valence configuration ##2\sigma_g^2## ##2\sigma_u^2## ##1\pi_u^2## ##3\sigma_g^1##. Finding all the possible term symbol. Homework Equations Term symbol ##^{2S+1}\Lambda## ##L=0 \rightarrow \Sigma## ##L=1...
  18. Jordan M

    Theoretical ξr of a molecule from the absolute configuration

    I am wondering if anybody knows how to calculate the theoretical relative permittivity of a molecule (1) using the theoretical configuration and values that are easily accessible (2). I am also wondering what the technique would be. In my pharmaceutical reaction class and also O-chem 2 we have...
  19. I

    'A single molecule of H2O' vs 'a single atom of H2O'

    Which one is correct below 1. a single molecule of H2O 2. a single atom of H2O (if this one is correct then what does it mean?)
  20. I

    The difference between 1 mole of C and 1 molecule of C?

    As we know, in the case of an atom, 1 mole of C = 6.023 X 10^23 C atoms and in the case of a molecule, 1 mole of C molecule = 6.023 X 10^23 molecules. as we know, atoms are used to make molecules, So can I say 1 mole of C atoms make 1 molecule of C because what we get If we break 1 molecule of C...
  21. T

    I Explaining the size of a water molecule

    I am a longtime producer and host of a children's radio show on our local public radio station. It's springtime and the rivers are running and I'm working up a little bit of shtick about water for the show. Water molecules are among the smallest, and one goal of the piece is to relate the size...
  22. I

    Chemistry How to find moles of O in CO molecule?

    Homework Statement If CO = 10 moles, then how to find moles of O in CO molecule? Homework Equations If CO = 10 moles, then how to find moles of O in CO molecule? The Attempt at a Solution I don't know how to proceed
  23. Pushoam

    Degrees of freedom of a diatomic molecule

    Homework Statement Homework EquationsThe Attempt at a Solution Considering the molecule as collection of two spherical atoms whose centers are joined such that they touch each other, Then, as a rigid body the system has 6 degrees of freedom and around the axis joining the two centers, the...
  24. F

    Set up the Lagrangian for a CO2 molecule

    Homework Statement The carbon dioxide molecule can be considered a linear molecule with a central carbon atom, bound to two oxygen atoms with a pair of identical springs in opposing directions. Study the longitudinal motion of the molecule. If three coordinates are used, one of the normal...
  25. Ben Geoffrey

    I Free Vibrations of a linear triatomic molecule

    This question is regarding equation 6.59 in Classical Mechanics Goldstein 3rd edition. I don't understand how he reaches that step. He says he does by inverting 6.41. Is he taking the transpose matrix composed of the eigen vectors by meaning inversion ? I thought I could upload the screenshot...
  26. Delta2

    Caffeine Isomers and Their Effects on the Nervous System

    I noticed that different brands of espresso coffee have different effect on my nervous system. Some are really good in the sense that they wake me up and make me feel fresh and dynamic, while others do nothing, and others make me really jumpy and nervous and stressed. Why is that? I am not good...
  27. alphaj

    Chemistry ORGO: What does it mean when a molecule is 'quenched?'

    Homework Statement n/a Homework Equations n/a The Attempt at a Solution n/a Just a question. I keep seeing that in SN2 reactions, sometimes a molecule is quenched by H2O or H3O. I've seen it turn an O- into an OH and also a heteroatom into an H. What exactly is going on here?
  28. I

    Is the O3 Molecule Polar Due to Fractional Charges and Nonlinear Geometry?

    Is O3 molecule polar or non-polar? I am confused. If it is molar, could you explain why? Thinking you.
  29. A

    How Does Dipole-Dipole Interaction Affect H₂ Molecule's Ground State Energy?

    Homework Statement Consider an ##H_2## molecule where the protons are separated by a wide distance R and both are located on the z-axis. Ignoring the spin degrees of freedom and treating the dipole-dipole interaction as a perturbation, use perturbation theory to estimate an upper limit for the...
  30. Greg Bernhardt

    Life’s First Molecule Was Protein, Not RNA

    https://www.quantamagazine.org/lifes-first-molecule-was-protein-not-rna-new-model-suggests-20171102/
  31. S

    Chemistry Determining the positive and negative poles of a molecule

    Homework Statement For the molecule CHCl3, a) Draw the electron dot diagram and structural formula b) predict the shape c) predict whether it is polar or non-polar, and justify your prediction. Indicate the positive and negative poles. Homework Equations none The Attempt at a Solution [/B]...
  32. J

    A Interference in electron conductance through e.g. molecule?

    Imagine attaching electrodes to a complex sample, e.g. a semi-conductor or a single chemical molecule, leading to some electric current. Can we decompose this electron flow into local flows? - like locally attaching amperometer and counting what fraction of electrons flow directly between given...
  33. fisher garry

    A Deriving total energy in a Hydrogen molecule

    I am looking for litterature that derives mathematically the total energy in a ##H_2## molecule by using quantum physics. Anyone knows a book they can recommend. I have seen derivations for helium atom for example: http://farside.ph.utexas.edu/teaching/qmech/Quantum/node128.html I need...
  34. Victoire

    Calculating the velocity of a molecule

    Hi, I'm stuck on a problem. I have this function that represents the velocity: f(v)=v2e(-mv2)/(2kT) T is the temperature and equals 293.15K m = 4.65 .10-26 kg k = 1.38 .10-23 J/K The problem wants us to find the derivative of the function. I found: df/dv= (2v)...
  35. S

    I Fusion half-life of diprotium molecule

    A diprotium molecule might undergo tunnelling to fuse by two reactions: p+p→d+e++νe p+p+e→d+νe What is the half-life for the fusion of an isolated diprotium molecule in its ground state (vibrational and rotational)? Naturally big, but also naturally finite. And might be computed. An estimate...
  36. Sveral

    I Can resonance be used to split a molecule of CO2?

    Hello, interested, if the posibility of splitting atoms by using resonance is possible, if so, wheather or not I can use it for something else, thanks in advance.
  37. AdrianMachin

    The direction of electric dipole moment of water molecule

    I was watching a video explaining how microwave ovens work when I found that there is a difference between my physics textbook and online images of the electric dipole moment of the water molecule, as well as the one shown in the video. Why do they differ?
  38. H

    A Single molecule fluorescence microscopy and limits

    I want to ask the limits on the molecule side for single molecule fluorescence microscopy. I am writing a proposal but I lack experimental knowledge since no one in my lab have ever used one. At least how much of an absorption coefficient, with at least how much of a radiative rate is necessary...
  39. A

    Chemistry How to calculate new IHD after finding a molecule in IR spec

    Homework Statement Lets say i have C5H10O.. The IHD is (5x2+2-10)/2 = 1 IHD So now i use my IR chart and i determine i have ketone Now i want to find the new IHD and also figure out what other atoms i have left. So i need to subtract C5H10O by ketone and figure out the new IHD. Homework...
  40. P

    Thermal motion of an ionised gas molecule in an electric field

    What I want to discuss here is what happens to the thermal velocity when an ionised gas molecule has been put into an electric field. Due to the charge (e) and potential difference (V), how much velocity has been gained by the ion can be calculated easily.eV = ½mv2 Where e is the charge of the...
  41. snoopies622

    Blackbody and gas molecule speed graphs look similar. Why?

    The graphs of intensity versus wavelength of blackbody radiation and of number of molecules versus speed in a gas look very similar to me. Is this just a coincidence? They seem like quite different phenomena.
  42. J

    Chemistry Simple elementary question chiral molecule

    Homework Statement Find if a molecule is chiral or not. It is 2-chloropentane Homework Equations IF the mirror image is superimposable to the molecule it is not chiral. The Attempt at a Solution Well I wrote the structural formula in 2D and I thought it was not chiral.(bottom ) But the book...
  43. D

    Volume occupied a single molecule of water.

    Homework Statement My problem includes answers from previous problems that are to be used as data in this problem so I will state the previous problems and the answers but not their solutions because I have solved them and they are pretty clear to me. So, I will be only posting the solution to...
  44. B

    [PoM] Most intense line of HCl molecule

    Hi guys, I've another exercise... 1. Homework Statement Determine the equilibrium internuclear distance ##R_M## of HCl molecule, knowing That some contiguous lines of the rotational spectrum of 2H35Cl are observed at the wavelengths: 234.1, 186.8, 156.4, 134.1, 117, 5 ##\mu m##. If the...
  45. B

    B Is this a printing error? (book example problem -- radius of a molecule)

    Question :- The critical volume of a gas is 0.072 L mol-1. What will be the radius of the molecule in cm ? Answer in the book :- ##V_c = 3b \implies b = 0.024 L mol## ##\therefore## for every molecule ##b = {24 \text{cm}^3\over 6 \times 10^{23}} = 4 \times 10^{-23}\text{cm}^3## per...
  46. H

    I The Shrödinger Equation & Hydrogen Molecule Bonding

    In the hydrogen molecule ion, one electron is responsible for the covalent bond between the atoms. But is it possible for one single elctron to create two bonds or more? What happens if we solve the Shrödinger equation for 3 protons and 1 electron?
  47. HelloCthulhu

    How do I measure the binding energy of a molecule?

    I read a paper on how a magnetic field of 4 T was used to break the van der Waals forces of an HeO molecule with a binding energy of 11.2 cm-1. I'll put the link to my original post below. Can someone tell me how this energy was measured? Your assistance is greatly appreciated...
  48. alexandria

    Chemistry Cellular Respiration - Final electron receptor molecule

    Homework Statement Homework Equations none The Attempt at a Solution Here is my attempted answer, can someone please tell me if I did this correctly, thank you :) 22. Final electron receptor molecule involved in aerobic respiration: * the electron transport chain relies on oxygen to keep...
  49. B

    Polarized Molecule Between Charged plates

    If a polarised molecule, e.g NH3 or H20 (Vapour molecule) or Butane is between two plates, of opposite charge, would the charges serve to trap the molecule between the plates?
  50. L

    Which molecule most likely to deviate from ideal values?

    Hi, Hoping I could get some help on this one. How would I know what causes bond angles to deviate from the ideal values? I greatly appreciate any help and advice on this. Thanks
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