Organic Definition and 449 Threads

Organic chemistry is a branch of chemistry that studies the structure, properties and reactions of organic compounds, which contain carbon in covalent bonding. Study of structure determines their chemical composition and formula. Study of properties includes physical and chemical properties, and evaluation of chemical reactivity to understand their behavior. The study of organic reactions includes the chemical synthesis of natural products, drugs, and polymers, and study of individual organic molecules in the laboratory and via theoretical (in silico) study.
The range of chemicals studied in organic chemistry includes hydrocarbons (compounds containing only carbon and hydrogen) as well as compounds based on carbon, but also containing other elements, especially oxygen, nitrogen, sulfur, phosphorus (included in many biochemicals) and the halogens. Organometallic chemistry is the study of compounds containing carbon–metal bonds.
In addition, contemporary research focuses on organic chemistry involving other organometallics including the lanthanides, but especially the transition metals zinc, copper, palladium, nickel, cobalt, titanium and chromium.

Organic compounds form the basis of all earthly life and constitute the majority of known chemicals. The bonding patterns of carbon, with its valence of four—formal single, double, and triple bonds, plus structures with delocalized electrons—make the array of organic compounds structurally diverse, and their range of applications enormous. They form the basis of, or are constituents of, many commercial products including pharmaceuticals; petrochemicals and agrichemicals, and products made from them including lubricants, solvents; plastics; fuels and explosives. The study of organic chemistry overlaps organometallic chemistry and biochemistry, but also with medicinal chemistry, polymer chemistry, and materials science.

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  1. Q

    Does Organic Chemistry Have Strong Roots in Computational Chemistry?

    So I'm an undergraduate student in Chemistry in my junior year and I recently transferred schools for a better science program. The one I was at was very, well, easy. Like toddler easy. I never went to class and I aced everything. Here, they're far ahead and it's much more rigorous. I was...
  2. D

    IUPAC Naming of Organic Compounds: Cis and Trans Isomers with Substituent Groups

    Homework Statement Give an acceptable IUPAC name for these compounds. http://i.imgur.com/tHUpwYK.pngThe Attempt at a Solution So the question is really on the 2nd problem in the picture but I need to reference the first one for my question. So my original guess on the 2nd problem was...
  3. micromass

    Organic Chemistry by Clayden, Greeves and Warren

    Author: Jonathan Clayden, Nick Greeves, Stuart Warren Title: Organic Chemistry Amazon Link: https://www.amazon.com/dp/0199270295/?tag=pfamazon01-20 Level: Undergrad
  4. Greg Bernhardt

    Organic Chemistry by Robert T. Morrison and Robert N. Boyd

    Author: Robert T. Morrison, Robert N. Boyd Title: Organic Chemistry Amazon Link: https://www.amazon.com/dp/0136436692/?tag=pfamazon01-20 Prerequisities: No prerequisites Contents: User comments: https://www.physicsforums.com/member.php?u=331656: I can't really say much about...
  5. Greg Bernhardt

    March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure

    Author: Jerry March, Michael B. Smith Title: March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure Amazon Link: https://www.amazon.com/dp/0471720917/?tag=pfamazon01-20 Prerequisities: High-School Chemistry Contents: User comments...
  6. R

    Question about organic spectroscopy (IR)

    Homework Statement Hi. I'm starting to read about IR spectroscopy and I have a question. I know that there are 2 kinds of vibrational modes in molecules: bending and stretching, so in a molecule like water for example, how can I tell which one of the vibrational does it have? What I mean...
  7. W

    Reactions, Organic and Medical Substances

    Hello again, sorry I had been idle for months. At that time I was relatively active in the Physics section. Thank God now I'm at the Fac. of Medicine, University of Sriwijaya. In the beginning of my college we had a Chemistry Lab Practice and are assigned to make the report, in which the...
  8. L

    Help with my unknown in the second organic chemistry

    1. Homework Statement Okay, I just started working on my unknown in Lab and I got stuck with a liquid. First I determined the boiling point, my professor told me to let this step go for 30 minutes and it plateaued at around 147°C. I did this twice the first time I didn't do it as long and got...
  9. S

    Organic Chemistry - Nomenclature Question

    Homework Statement (see uploaded attachment for picture). I basically have to name this molecule. The Attempt at a Solution I don't know where to start counting for the longest carbon chain and I'm not sure if it's a nonane or octane. If you guys can help it'd be much appreciated
  10. M

    Why Is Organic Chemistry So Challenging for Some Students?

    I am having difficulties studying for organic chemistry. The concepts don't seem especially difficult, but I am not performing where I want to be at in this class (1st semester organic chemistry). I do fine in math and physics, and even did well in general chemistry, but it seems the skills...
  11. R

    Difference between the acid strength of inorganic and organic acids

    Homework Statement Hi. I'm pretty much a beginner in organic chemistry and I'm just wondering something. For example, I know that HCl is a stronger acid than HF. But... then why the following happens if a have an organic acid (e.g a carboxylic acid)? According to what I see, a...
  12. Saitama

    How do you study Organic Chemistry?

    I suppose this is the right place to post this. I have been studying organic chemistry from more than three-four months and i can't even remember the basic reactions. There seems to be so many reactions which i need to memorize. Whenever i sit to do questions on the reactions, i always need to...
  13. Z

    Organic Chemistry - 1H and 13C NMR Problem. HELP

    Homework Statement Determine the structure of the compound given the information belowHomework Equations Molecular Formula: C8H6O4 1H NMR: 1.57 (d, J=8.66 Hz, 1 H) 1.77 (d, J=8.66 Hz, 1 H) 3.51 (d, J=3.00 Hz, 1 H) 3.51 (d, J=3.00 Hz, 1 H) 3.60 (sc,J=7.56, 3.00 Hz, 1 H) 3.60 (sc, J=7.56, 3.00...
  14. C

    Identifying the Electrophile in But-2-ene and Bromine Reaction

    Homework Statement But-2-ene reacts with bromine in the presence of concentrated aqueous sodium nitrate to give the following compound CH3-C(H)(ONO2)-C(H)(Br)-CH3 Which of the following statement is correct. a.the electrophile is NO2+ b.Only 2,3-dibromobutane is formed. c.Resultant...
  15. M

    Organic compounds with a charge

    Why is it that when you have an organic compound with a charge on the C, that charge takes the place of one hydrogen bonded to that C?
  16. Y

    Organic Semiconductor: Why Does Removing 2 Electrons Require More Energy?

    Hi, I just read a paper about charge transport in organic semiconductor. There, it was mention that from electrochemical experiments, it is well known that after the removal of one electron from an individual molecule, more energy is required to remove a second electron. I'm still confuse...
  17. J

    Organic chem:fractional distillation

    Hi, During fractional distillation,crude oil is heated to a certain temperature,then it is pumped into the fractional tower. As you know,petroleum is a mixture of alkanes.When it is heated in the furnace(to about 400°C),it does not burn.But lower alkanes(e.g.CH4) are extremely flammable,why it...
  18. J

    Organic chemistry:substitution reaction

    In substitution reaction between bromine and hexane, why the bromine should be in organic solvent? Bromine is already a liquid!
  19. X

    Finding the least molar mass of organic compound having molar mass > 100

    Homework Statement In an organic compound of molar mass > 100 containing only C, H , N, the percentage of C is 6 times the percentage of H while the sum of the percentages of C and H is 1.5 times the percentage of N. What is the least molar mass? Homework Equations C% + N% + H%= 100%...
  20. A

    Functional groups of organic compounds

    Homework Statement find the functional groups in the following compound: Homework Equations C8H16O4The Attempt at a Solution I know there is an ether but there is also something else. What is it? I have tried to find a group that is in the compound, but I have had no luck. It seems to be only...
  21. H

    Organic Chemistry Hantzch Synthesis

    Homework Statement http://img51.imageshack.us/img51/9563/chem3.png Homework Equations The Attempt at a Solution I know the answer has to be a or c because you need the ammonia to make this reaction happen but I don't know whether you would want to use 3-oxobutanenitrile or...
  22. N

    Understanding Nucleophilic and Electrophilic Attacks in Organic Chemistry

    How to see if there is a nucleophilic or electrophilic attack? Nucleophilic or electrophilic attack? What type of attack performs a) the water molecule in the attack with one of its free electron pairs? b) bromine molecule when in an attack with a double bond? Motivate! I think...
  23. W

    IUPAC dilemma on naming a toxin, any pro organic chemists out there?

    So I came across a cool toxin, and saw that people have not assigned an IUPAC name to it, so I took on the challenge. The compound of interest is Batrachotoxinin A unc. edu/depts/mtcgroup/litmeetings/batrachotoxinin.pdf In the second slide Batrachotoxinin A has an R which is an H...
  24. K

    Is this the same organic side chain?

    Attached is the image of the desired structure, my question is based on what is pictured as (CH3)2HC- I represented this group as C3H7 which does seem like the logical equivalent, but just being safe here. Am I right? Thank you!
  25. T

    Chem major who hates Organic Chemistry?

    I am chem major currently taking organic chemistry. I am ashamed of admitting I hate organic chemistry. This is not even science. It seems to me though, it is a branch of engineering. You have stuff, you make new stuff. You increase your yield and figure out steps to synthesize something. I...
  26. B

    Difficulties in Organic Chem. Lab

    Hi, this is my first post. I'm generally more of a blog/message board reader than a contributor, but there's really been something that has been eating away at me, making it difficult for me sleep at night. (Note: long post coming up) Last semester in Organic Chemistry I, I made a huge...
  27. B

    Social and (Maybe) Technical Issues in Organic Chemistry Lab

    Hi, this is my first post. I'm generally more of a blog/message board reader than a contributor, but there's really been something that has been eating away at me, making it difficult for me sleep at night. (Note: long post coming up) Last semester in Organic Chemistry I, I made a huge error...
  28. C

    How can BINAP be named without chiral centres using the R S nomenclature?

    Can someone tell me how to name BINAP R or S? IT has NO chiral centres and I haven't got a clue of how to name it!
  29. J

    How Do I Name the Cyclic Isomer of C2H4O?

    Hey, How would I name (IUPAC) the isomer of C2H4O that is a triangular ring with C at two vertices and O at the third? Also, I'm trying to name the 11 isomers of C3H6O. So far I have 10 and I can't seem to get the last one. The ones I have are: propanal propan-2-one prop-2-en-1-ol...
  30. N

    What Is Fuming in Organic Chemistry?

    Organic chemistry reaction Help . !URGENT! Homework Statement I can't type the O-Compounds so here's the Question http://dl.dropbox.com/u/41389643/Photo%2001-03-12%204%2047%2021%20PM%20%281%29.jpg Homework Equations The Attempt at a Solution This is the first time I came...
  31. D

    Which Is the Best Leaving Group: Cl-, Enolate, or NR3?

    which is the best leaving group? Cl- enolate NR3 I couldn't figure out how to draw the enolate here, but it is a basic 3 carbon one. I believe the answer is Cl because resonance on the enolate will disperse the neg. charge. Am I on the right track or is there a factor I am missing?
  32. T

    Find the final product. Organic Chemistry.

    Homework Statement Find the product of this http://www.webassign.net/ksorgchem2/14-P-019e1.jpg The Attempt at a Solution I tried this but it is wrong. http://www.webassign.net/marvinimages/e/d/b3dfb33e165ce17f7b0a8bab7b9d9d.png Not really sure what to do now.
  33. B

    Dienophile and diene help? organic chemistry

    dienophile and diene help?? organic chemistry We never really covered how to do diels alder reactions and I am having trouble how to do these. Here is a photo of the lab page with the questions. I just need help with 2a-e and 3b-3d. Thanks.
  34. B

    Does Solvent Affect Chirality in Fluoro-Chloro-Bromo Propanone Reactions?

    There is a compound 1-fluoro,1-chloro,1-bromo, propanone (a substituted ketone). If we react it with an alkali, we know alkali will attack carbonyl carbon and chloro-fluoro-bromo- methyl carbanion will be the leaving group, finally acetic acid and chloro-fluoro-bromo- methane will be formed...
  35. D

    Organic Chemistry - Carbanion Question hybridization/valence/geometry

    Homework Statement A carbanion is a species that contains a negatively charged, trivalent carbon. (a) What is the electronic relationship between a carbanion and a trivalent nitrogen compound such as NH3? (b) How many valence electrons does the negatively charged carbon atom have? (c) What...
  36. N

    Salting out and organic solvents

    Hello! I am confused about the protein interactions that occur when either salt concentration is increased or an organic solvent is introduced. When salting out, wiki says: "Addition of a neutral salt, such as ammonium sulfate, compresses the solvation layer and increases protein-protein...
  37. T

    Is it 4-isopropyl-2,5-octene or 4-isopropyl-2,5-octadiene?

    Homework Statement 4-isopropyl-2,5-octene or 4-isopropyl-2,5-dioctene? 2. The attempt at a solution 4-isopropyl-2,5-octene
  38. Y

    Organic Chemistry Synthesis/Mechanism

    Homework Statement Problems: http://imgur.com/qN7Iq Homework Equations n/a The Attempt at a Solution For the synthesis, I tried opening the epoxide with HBr and then adding OMe- in HOMe to substitute the Br with the OMe group in the product. However, I am unsure how to substitute the...
  39. AGNuke

    Practical Organic Chemistry - Confirm positive test

    I don't know where to ask this question, but anyways, since it was asked in an exam, so finding out the correct answer afterwards is a moral responsibility as a homework. So here I am. My question is whether the compound 2-Hydroxy-5-nitrobenzaldehyde (Did I named correctly?) gives positive...
  40. H

    Which textbook is the best for learning organic chemistry?

    As the title states, what is the best book? The book I'm using now is Vollhardt and Schore. I don't like it very much. The book is very spammy, if you know what I mean. I'd like a book that builds on previous facts. My current book just presents facts with little relation to previous topics...
  41. N

    Nomenclature of Organic Compounds: Significance of -#-yl and E/Z Isomerism

    Hi all, I have a question regarding the nomenclature of organic compounds. What is the significance of -5-yl in bicyclo[2,1,0]pent-5-ylbicyclo[3,3,0]octane ? In general, what is the significance of the # in -#-yl in compounds? Additionally, in (E)-1,2-diiodo-1methylcyclohexane, does the E...
  42. T

    Chemistry Organic Chemistry: Is there any research on any psychedelics anymore?

    I'm really interested in how psychedelics and their alkaloids do what they do. I'd really like to get a graduate degree in organic chemistry with a focus on alkaloids or a subdivision thereof. But, I'm worried about how I'd make a living by studying things or things similar to things that are...
  43. B

    ORGANIC Chemistry: Nucleophilic Substitution

    Homework Statement 8) How might you prepare each of the following molecules using a nucleophilic substitution at some step? a) (CH3)3-O-CH3 b)CH3CH2CH2CH2CN Homework Equations none The Attempt at a Solution I'm really not sure what's being asked. I'm going to assume that I...
  44. M

    How is this correct? (Organic; Stereochemistry)

    Draw Newman projections depicting the (R)-enantiomer of each of the following: a) 1-bromo-1-chloroethane b) 1-bromo-1-methoxypropane Now, I am SURE that I am mistaken, but isn't that an (S)-enantiomer for each? Assigning priorities: For a) Br > Cl > CH3 > H...right? So, wouldn't the...
  45. W

    Organic: lanosterol Biosynthetic Cyclization

    This is a tough one! Shown is the biosynthetic cyclization of oxidosqualene catalyzed by oxidosqualene cyclase (OSC) leading to lanosterol as the final product. The reaction starts with a protononation step as shown. Indicate the flow of electrons after the initial protonation step...
  46. W

    How can we convert 1-hexene to cis-3-octene using alkynes as intermediates?

    Organic: Alkene to Alkyne I am trying to do a synthesis of 2-Octyne from 1-heptene. Conversion of the triple bond to a double bond is pretty easy, but i also have to add an alkyl group, and the double bond must remain on the original triple bond location. Thus, so far thoughts: 1. remove...
  47. I

    Organic Chemistry Williamson Synthesis of an Ether

    " Write an alternate reaction that can be used to prepare the same product that we got in our lab ( changing the metal in the alkoxide or halide leaving group is not sufficient.) Explain the reaction you used, is it expected to be cheaper cost wise, and or produce a higher yield, based on the...
  48. C

    Organic Chemistry-Empirical formula problems

    Homework Statement 1)After analyzing an organic substance ,it came to this: 29,752% Carbon;5,785%Hydrogen:26,446% Sulpur and 11,57% Sodium.It is also that known that between the Oxygen mass and Sodium mass ,in a mole of substance analyzed,it's a difference of 18 grams.Determinate the molecular...
  49. S

    Can I still redeem myself in Organic Chemistry?

    I'm taking orgo 1 this semester, and we just had our first test. I know that's supposed to be the "easiest" test, but let's just say I was pretty lost. I haven't put in much effort so far in chem, and I know I have to get on track now. Is it too late for me to redeem myself? Like do I still...
  50. R

    A Few Organic Chem Questions (Stereochemistry)

    I am currently learning about stereochemistry in my O-chem class. I just have a few questions that I were running through my head. I know there are a lot of questions here, but they're not HW-related at all; my prof. just taught the lecture and I have had these questions on my mind. 1. How...
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