I have a 0.2M solution of Sodium Acetate, (which surprisingly seems to be at pH7.8, (we calculated it should be around pH9)). We then add Cadmium Sulfate, and adjust the pH using acetic acid to pH5. However, when I add the Cadmium Sulfate the pH drops.
Surely this can't happen?
I have 0.2M solution of Sodium Acetate, (100ml with 1.6g NaAc)
I want to work out the pH it should be. THERE IS NO ACETIC ACID ADDED.
This is causing me nightmares! I am measuring ph 6.5 but apparently that is wrong. Why would that be so?
Cheers!
Homework Statement
2.00M chlorus acid and 2.00M formic acid are mixed. What is the pH?
Homework Equations
Ka of chlorus acid is 1.1×10-2
Ka of formic acid is 1.78×10-4
The Attempt at a Solution
For chlorus acid with quadratic equation to find x:
x²+0.011x-0.022...
Homework Statement
50ml of 0.10M Na_3PO_4 + 50ml of 0.10M NaH_2PO_4
For H_2CO_3:
Ka_1 = 7.5 * 10^{ - 3}
Ka_2 = 6.2 * 10^{ - 8}
Ka_3 = 1.0 * 10^{ - 12}
Homework Equations
The Attempt at a Solution
Since K_h of Na_3PO_4 > > Ka_2 , I considered only hydrolysis of Na_3PO_4...
Homework Statement
Consider 1L of a solution that is 0.100 M in acetic acid and 0.100 M in sodium acetate. What will the pH be, when 0.0900 mol of sodium acetate are added?
Ignore changes in volume.
acetic acid pka = 1.75 E-5
Homework Equations
HA --> H+ + A-
pH=pka +log A-/HA...
Chemistry pH problem help please NaOH and HCl
Calculate the pH after the following total volumes of .32M HCl have been added to 25 mL of 0.16M NaOH
a. 0 mL c. 12.4 mL e. 12.6 mL
b. 1 mL d. 12.5 mL f. 15.0 mL
A. i have answered correctly but i...
Hi all,
Long time lurker, very seldom poster.
I have a need for an aqueous soluble compound that will thermally decompose or oxidize to form acidic products in the temperature range 100-300 C.
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Homework Statement
We have two solutions: One solution that has 0.300 L of 0.100 M acetic acid, and the other with 0.100 L of 0.200 M CN^-.
We mix the two solutions. At equilibrium, what is the pH of the resulting solution?
Homework Equations
For acetic acid, K_a=1.8*10^{-5}
For CN^-...
Homework Statement
The pH of pure water is temperature dependent, for example it is 6.55 at 50 C. Determine ΔG° for the ionization of water at 50C
Homework Equations
ΔG=ΔG°+RTln(Q)
at eqm ΔG=0
q=Keq
pure water:
pH 7.00 at 25C
The Attempt at a Solution
Not sure if the process...
Homework Statement
To 25.000 mL of distilled water in a 50 mL beaker, you add exactly 19 drops of 0.100 M HCl and swirl to mix. If exactly 20 drops of HCl are required to make 1.000 mL
Homework Equations
Calculate molarity of the diluted HCl and pH of the diluted HCl
The Attempt...
Homework Statement
Calculate the pH of concentrated hydrochloric acid if this solution is 24.8 % HCl by weight and has a density of 1.16 g/mL.
Homework Equations
The Attempt at a Solution
\the percentage is throwing me of, can someone explain what it is?
Homework Statement
How would you prepare 5.00 L if an aqueous solution having a pH = 10.70, if you had a supply of 0.250 M NaOH?
Homework Equations
I don't even know anymore...
The Attempt at a Solution
I've tried a million different ways but I never come up with the answer...
Homework Statement
Calculate the pH after 0.030 mol NaOH is added to 1.00 L 0.100 M HC3H5O2 and 0.100 M NaC3H5O2
Homework Equations
Ka=[H+][A-]/[HA]
pH=-log([H+]) or 14-pOH=ph
The Attempt at a Solution
HC3H5O2 <-> H+ + C3H5O2-
NaC3H5O2 <-> Na+ + C3H5O2-
I know that Na+ has no...
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Homework Statement
The pH of a 1.00x10-8 M solution of HClO4 is
Homework Equations
-log(H3O+)
The Attempt at a Solution
I thought I could just do -log(1.00x10^8) = 8, but the answer is actually 6.98. Why?
Does it have anything to do with it being a strong acid?
Homework Statement
This question is for a lab write up. We prepared a 0.1 M citrate buffer with pH 4.0, we then diluted our buffer with deionized water 20 fold and then 50 fold. The subsequent changes in pH are as follows,
20 fold pH = 4.10
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A Compound (not specified) has 2 ionizable groups. One is at pKa 4.2 and the other pKa is between 7 and 10. If you have 10.0 mL of a 1.0M solution at a pH of 8.17 and you add 10.0mL of 1.0M HCl which changes the pH to 4.2 what is the second pKa?
I tried working this problem out a few...
Homework Statement
Solid Na2HPO4 is dissolved in water. What is the resulting pH of the solution? Relative pka's of phosphate derivaties are ~2, ~7, and ~12.
Homework Equations
No equation needed, just look at the species which phosphate would develop.
The Attempt at a Solution...
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For an weak acid/strong base titration, the pH at equivalence can be estimated by pH = pKa + pHtitrant/2. Can someone explain where that equation comes from?
Thanks.
Homework Statement
What is the pH of a solution prepared by mixing 50.0 mL of 0.300 M HCL with 450.0 mL of 0.400 M HIO3? HIO3 Ka = 1.6 x 10^-1
Homework Equations
ICE
The Attempt at a Solution
I first converted each concentration to its new molarity by figuring out the number of...
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what i did was first write the...
What is the pH of .15 M methylammonium bromide, CH3NH3Br (Kb of CH3NH2 = 4.4x10^-4)
I actually asked this to someone else and got this:
It just doesn't seem right. To use the information given for CH3NH2 we need to first have CH3NH3 or CH3NH2 in the solution but we start with CH3NH3Br. Where...
[SOLVED] pH of buffer solution
Homework Statement
Calculate the pH of a solution made by mixing 750 mL 1.00 M NH4+Cl and 250 mL 1.00 M NaOH
The Attempt at a Solution
NH4+ will react with H2O to form NH3 and H2O+. If my calculations are correct, [H+] after the reaction will be 2.07E-5...
Homework Statement
Glycine which has a pKa of 9.6 can exist in protonated form (-NH3+) or as the free base (-NH2) because of the reversible equalibrium R-NH3+ <------> R-NH2 + H+.
How much 5 M KOH must be added to 1.0 L of 0.1 M glycine at pH 9 to bring the pH to exactly 10?
Homework...
Homework Statement
Concentration of acetylcholine (ACh) determined from pH change after hydrolysis. Sample incubated with acetylcholinesterase is quatitatively converted to choline + acetic acid which then dissociates to acetate + H+. A 15mL solution has unknown amount of ACh with pH 7.65, and...
[SOLVED] pH question...
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Calculate the pH of a 0.200M Sodium Cyanide solution.
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I assumed "5% acidity" to mean 5 percent of the soln was acetic acid, by volume (though, doing the calculations for "By mass", I got roughly the same pH). Also, I couldn't find the density of acetic acid in my textbook, so I assumed it was close enough...
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Homework Statement
If you mix 200mL of a 1.8M HCl solution with 300mL of a 1.16M NaOH solution, what will be the pH of the solution?
The Attempt at a Solution
Well I am really lost with this problem. I am pretty sure you need to convert each to moles.
.2L HCl x 1.8moles HCl...
Homework Statement
The concentration of Ca2+ in hard water can be determined by titration with a reagent X which forms a complex with Ca2+ giving a change in colour. Since the colour change is sensitive to pH, the titration has to be carried out in an alkaline buffer.
Th structure of X is...
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Homework Statement
A mixture containing 500ml of .1 M HC3H5O2 (acetic acid) and 500 ml of .1 M NaC3H5O2
what is the pH?Homework Equations
can someone walk me through this? i know the answer is 4.89 but I am not sure how to get that. I am not even entirely sure how to set up the equationThe...
You want to make an acetic acid/acetate buffer, pH 5.6, with a volume of 250 mL, and a final concentration of ([AcOH] + [Aco-]). You may only use acetic acid and sodium acetate( no strong acid or base). How many mL of glacial acetic acid would be needed( d=1.05g/mL)?
Homework Statement
Titrating .1006M CH3COOH with .2012M NaOH. pKa=4.74, Ka=1.8*10^-5
What is the pH at the equivalence point of the titration?
Homework Equations
pKa = -log(Ka) pH = -log[H+]
The Attempt at a Solution
Alright, after setting up an ICE table (in order to find...
Homework Statement
I have to find the pH of a 8.57x10-10M HNO3 solution.
Homework Equations
HNO3 + H20 <--> H3O+ + NO3-
pH= -log[H3O+]
The Attempt at a Solution
my theory was that the hydronium ion concentration would be the hydronium ion concentration in water (1x10-14 M) plus the...
[SOLVED] Amount of 6M H2SO4 to lower pH of pool from 7.0 to 4.0
Homework Statement
A new swimming pool is filled with fresh, clean water with a pH of 7.0. The width is 25 ft, the length is 60 ft, and the depth linearly ranges from 3.5 to 9 ft. How much 6 M H2SO4 must be added to reduce the...
Calculate the pH of the 0.30 M NH3/0.36 M NH4Cl buffer system. What is the pH after the addition of 20.0 mL of 0.050 M NaOH to 80 mL of the buffer solution?
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0.36 0.30 0
-x +x +x
0.36-x 0.30 + x x...
[SOLVED] Anticipated pH of Buffer Solution (urgent!)
Homework Statement
Can someone verify my process here? i did a lab where i had 100 mL CH3COOH/CH3CO2- buffer solution. I have to find the pH if 100 mL of 0.0983 M HCl is added to it. In the lab i got pH of 1.72
[b]2. Homework Equations...
Homework Statement
Need a little help on a lab. I have all the data for a titration of a weak acid with NaOH which includes the pH of the acid for however many mL of NaOH added. I've plotted a pH vs V NaOH added graph. From that, I plotted a ∆pH/∆V vs V NaOH added graph. From this, I found...
Homework Statement
we are to use a logarithmic formula to give the ph of a substance.
Homework Equations
find the hydrogen content and show how to find the ph.
The Attempt at a Solution
i have checked the web to find a formula but am lost