A chemical reaction is a process that leads to the chemical transformation of one set of chemical substances to another. Classically, chemical reactions encompass changes that only involve the positions of electrons in the forming and breaking of chemical bonds between atoms, with no change to the nuclei (no change to the elements present), and can often be described by a chemical equation. Nuclear chemistry is a sub-discipline of chemistry that involves the chemical reactions of unstable and radioactive elements where both electronic and nuclear changes can occur.
The substance (or substances) initially involved in a chemical reaction are called reactants or reagents. Chemical reactions are usually characterized by a chemical change, and they yield one or more products, which usually have properties different from the reactants. Reactions often consist of a sequence of individual sub-steps, the so-called elementary reactions, and the information on the precise course of action is part of the reaction mechanism. Chemical reactions are described with chemical equations, which symbolically present the starting materials, end products, and sometimes intermediate products and reaction conditions.
Chemical reactions happen at a characteristic reaction rate at a given temperature and chemical concentration. Typically, reaction rates increase with increasing temperature because there is more thermal energy available to reach the activation energy necessary for breaking bonds between atoms.
Reactions may proceed in the forward or reverse direction until they go to completion or reach equilibrium. Reactions that proceed in the forward direction to approach equilibrium are often described as spontaneous, requiring no input of free energy to go forward. Non-spontaneous reactions require input of free energy to go forward (examples include charging a battery by applying an external electrical power source, or photosynthesis driven by absorption of electromagnetic radiation in the form of sunlight).
A reaction may be classified as redox in which oxidation and reduction occur or nonredox in which there is no oxidation and reduction occurring. Most simple redox reactions may be classified as combination, decomposition, or single displacement reactions.
Different chemical reactions are used during chemical synthesis in order to obtain a desired product. In biochemistry, a consecutive series of chemical reactions (where the product of one reaction is the reactant of the next reaction) form metabolic pathways. These reactions are often catalyzed by protein enzymes. Enzymes increase the rates of biochemical reactions, so that metabolic syntheses and decompositions impossible under ordinary conditions can occur at the temperatures and concentrations present within a cell.
The general concept of a chemical reaction has been extended to reactions between entities smaller than atoms, including nuclear reactions, radioactive decays, and reactions between elementary particles, as described by quantum field theory.
Hi,
wondering if you could help me.
I want to find a chemical reaction that would involve:
Reactant + Air (or gases present within)----Exothermic----> Harmless gas
Any help would be appreciated if you knew of a chemical that I could use to react with air to produce heat and a...
It seems that no matter how far and wide I look, I can find no concise explanation as to the roles of bosons in a nuclear reaction, fusion and/or fission.
Thus, my inquiry: What role do bosons play in nuclear reactions, fusion and fission? What is the sequence of events that result in such a...
Need help, Activation energy determination from this reaction. Is this possible??
i did an experiment, i noted the tempreture and found rate constant.
My friend did the same experiment and she found rate constant and noted the tempreture.. The tempreture differs by one degree. Can i calculate...
There is a compound 1-fluoro,1-chloro,1-bromo, propanone (a substituted ketone).
If we react it with an alkali, we know alkali will attack carbonyl carbon and chloro-fluoro-bromo- methyl carbanion will be the leaving group,
finally acetic acid and chloro-fluoro-bromo- methane will be formed...
My son brought home a fourth-grade science experiment a few days ago: He was to make some sort of property change in a steel nail. He had decided that he wanted to make it rust, so we set about creating an electrolyte solution out of salt and water and leaving it in there. There wasn't...
I have recently learned how to balance chemical equations using the ion electron method.
However, I have some doubts..
Suppose the reaction takes place in an acidic medium; now how can we say that we are allowed to add an H+ or H2O molecule?
I mean, where will these elements come from when...
Homework Statement
3,4-dibromo-2,5-dimethylhexane treated with excess k t-butoxide will form an alkyne and diene. The IR spectra shows bands at 3010,2995,2980,1610,1450,1380 and 1050 cm^-1.
What are the predicted products? Which one actually formed? Why?
Homework Equations
The Attempt at...
Creating CH4 from H2 + CO2
This was a topic raised before.
However a point that should have been made and wasn't is as follows.
The problem with electricity is that it cannot be stored.
Wind energy often has to be dumped at times of low demand (night, holiday periods, weekends). The amount and...
Hi,
I am reading about rates of reactions, and I am confused about why we multiply the rate equation of a particular product or reactant by its respective coefficient, only taking the reciprocal of it. Could someone explain to me why this is done? Is it done merely out of convenience?
If I place a glass of white vinegar on the table, and let it make contact with air,
Does anyone have any suggestions on what kind of chemical reaction has between air and vinegar?
Thanks in advance for any suggestions
Hello,
I have seen that adding dish soap to water and then dissolving Alka-Seltzer in the solution causes the reaction rate to slow. Does anybody have any idea as to why this happens?
Simple rigid body collision reaction (Newton III)
Hi everyone! I'm writing a physics engine as part of a game I'm making. Up until this point I've implemented inter object collisions in a rather quick and dirty manner. Whenever something moves into something else, it is simply teleported back...
What reaction or series of reactions can I react SO2 gas with that will strip off the O2 and leave me with elemental S?
It seems most reactions will just make a sulphates etc.
Homework Statement
say we were hydrating Cobalt chloride crystals
why would
(i) more cobalt chloride
(iii) less water
result in a GREATER temperature change of reaction>
thanks
Homework Equations
The Attempt at a Solution
for ii I have used Q = mcΔt and on re-arranging to...
reaction of alkaline Earth metals with O2
i just got in my textbook that Ba,Ca,Sr is kept in paraffin but Mg and Be are not as they form a protective coat of oxide on their surface.i don't get a clue about this .could anyone explain me this?
So, in my thermo book, it says that the gibbs free energy change of a reaction is the free energy received by the system at constant T,p and constant chemical potential when the extent of the reaction varies by one mol. The part that is confusing me is the "constant chemical...
Homework Statement
Part A:
Mass of Mg (s) = 0.31 g
Initial temperature of calorimeter contents = 24.1 C
Finial temperature of calorimeter contents = 36.8 C
Part B:
Mass of MgO (S) = 1.22 g
Initial temperature of calorimeter contents = 24.0 C
Finial temperature of calorimeter contents = 31. 9 C...
Homework Statement
C3H5(NO3)3 --> N2 + CO2 + H2O + O2
Homework Equations
non O and H oxi states as follows
C: -2/3 to +4
N: +5 to 0
The Attempt at a Solution
Oxi: C3H5(NO3)3 --> CO2 +6e- added 6 electrons to balance net carbon oxi state
Red: C3H5(NO3)3 +15e- --> N2 added 15...
Good evening, everyone :) i m mathsTKK, new member od physics forum, nice to know everyone in this forum ;)
I have a question regarding chemical software which can help me a lot. I am currently using Accelyrs 3.1 to do some research, but I meet some difficulties in fully using it as some of...
Homework Statement
At 25 C a catalyzed solution of formic acid produces 44.6 ml of carbon monoxide gas in 30s.
a) Calculate the rate of reaction with respect to CO(g) production.
Homework Equations
Rate = dC / dT
The Attempt at a Solution
dC should be expressed in mol/L but I...
Can someone please help me answer this question and explain the concepts/solution step by step:
Prof. W.H Bogus claims that he has prepared a powerful new catalyst that makes it possible to synthesize NH3 with a 70% yield in a reactor operating 500K and 2 atm pressure and having a feed...
Homework Statement
Calculate the total kinetic energy of the products of the reaction d+C-13 --> N-14 + n if the incoming deuteron (d) has 36.3 MeV.
Homework Equations
Q=(Parent Mass - Daughter Mass - Decay Particle Mass)*c^2
1u = 931.5 MeV
C-13 = 13.00335u
N-14 = 14.003241u
Neutron...
I am working on a project that needs 2 chemicals to react and change colors. The catch is they most likely need to be or come in a powder form, non toxic, and relatively inexpensive.
PLEASE HELP!
Today in class my chem teacher was insistent that 2Mg + O2 = 2MgO was a synthesis reaction. this I agree with. however, he was also adamant that this was not a combustion reaction, when it our textbook it specifically gave us this very same example as a type of combustion reaction. Question: is...
Homework Statement
2HCl + Na2S2O3 -> 2NaCl +S + SO2 + H2O
Find the order of reaction with respect to S2O32- and H+
volume of 3.0M HCl was held constant at 2ml
Homework Equations
S2O32- + 2H+ -> S + SO2 + H2O
rate = k[Na2S2O3]m[HCl]n (see number 3.)
The Attempt at a Solution
i just...
Homework Statement
When Fe(NO3)3 and KSCN reated, it immediatly turned red. my teacher says this si the stuff they use for fake blood in movies. My problem is, we must state the reaction type. Homework Equations
the products, I am assuming, are FeSCN and KNO3 (i know I did not yet balance...
Does anyone know the experiment where distinct circular patterns appear to emerge in a liquid chemical reaction? This experiment was covered in my thermodynamics class due to its relevance of order emerging from chaos. All I remember about the experiment is that it was not believed at first for...
I accidentally threw dettol (chloroxylenol) down a clogged toilet drain without knowing there was already sodium hypochlorite there. For some strange reason, after flushing down once, it became even more clogged and it's still all lying there. I closed the door in fear of inhaling toxic fumes. I...
I'm in a first year organic chemistry class with a biochem focus and I am going to do a project on ketoacidosis. While I can find the pathway online, since this is an organic chemistry class, I figure that a reaction mechanism that illustrates electron movement (arrows and such) would be...
Just as the title says, I'm having difficulty understanding why the concentration of inert gas is not included in the reaction rate. I would think adding a higher concentration of N2 (or some other inert gas) would increase the reaction rate. Perhaps, I'm confusing reaction rate with space time?
Homework Statement
For the reaction N2(g) + 3H2(g) <---> 2NH3(g)
I am supposed to determine the equilibrium constant at 298K and 1 bar. We have been given a table that states that
for NH3(g):
\Delta_{r}G^{\Theta}= -16.45 kJ/mol
I know that
\Delta_{r}G^{\Theta}= \Sigma v...
http://en.wikipedia.org/wiki/Standard_enthalpy_of_reaction" of reactants (ΔHfO).
My question is, why?
And I also know that I can find http://en.wikipedia.org/wiki/Standard_enthalpy_of_reaction" (ΔHrO) by subtracting the bond energies of the reactants from the products. The result differs...
My friend said that two horses pull the Magdeburg hemispheres with same force is as same as a horse pulls the Magdeburg hemispheres which is tell on a tree(I may forget the details about the assumption)
Why?
Another Q. about action and reaction
i don't know why the reading isn't 2Mg,but is...
The purpose of this chemistry lab was to prepare/synthesize Bis(2,4-pentanedionato) Copper (II), which is also known as Cu(C5H7O2)2
I was given the following format for a chemical equation in a lab that needs to be balanced:
Cu2+ (aq) + 2 base-n (aq) + 2 C5H8O2 (aq) → Cu(C5H7O2)2 (s) + 2...
Homework Statement
I want to find a relationship between the number of moles of O2 used and the number of CH2 units in an alkane in a complete combustion reaction.
Homework Equations
The Attempt at a Solution
Right now I have come up with a math equation, given X units of CH2...
Okay, so we did a lab in class with Na2CO3 in BaCl2 first. The reaction formed a white precipitate, and I suppose the products are BaCO3 + 2NaCl. Not sure if NaCl is dissolved or not, or if it was the white precipitate I saw, but anyways, here's my question...
We added HNO3 to that new...
The standard potential of the Cl−(aq.)|AgCl(s)|Ag(s) electrode in the vicinity of T = 298 K has been found to fit the expression
E\theta/V = -0.00558 + 2.6967x10^-3(T/K) - 8.2299x10^-6(T/K)^2 + 5.869x10^-9(T/K)^3
Find the standard Gibbs free energy, the standard enthalpy, and the standard...
Critical mass is over 50kg so let's say I have 2 halves of a sphere of the isotope U-235, each weighing 30 kg. I drop one onto the other so that they form a supercritical sphere. No doubt a chain reaction would begin, but I assume it would produce energy on the level of a nuclear reactor rather...
Homework Statement
Calculate the heat of reaction per mole of water formed in the acid-base reaction. Assume that the total mass of the solution is 150g.
75mL of 2.0M NaOH added to 75mL of 2.0M HCl in a styrofoam cup. Average initial temp = 295.65K. final temp = 308.8K
Homework...
Hi guys,
I'm facing a problem.
I've read a paper where they tried to synthesise a crystal and they give the following reaction mixture molar composition:
3.0 SiO2
1.0 Al2O3
0.1 NaCl
276 H2O
What does it means?
It can't be the molar fraction since the sum of all the fraction must give 1 as...
um, i placed my elbow on the table, and i think i mustve hit some ideal spot that actually caused a (static?) reaction up my lower arm.
what i want to know is, what exactly it is, why did it happen, and why it only happens sometimes?
PER - chemical reaction
Q: A reactor is needed to convert A to R in a liquid reaction. The stoichiomentry is simply A→R and the rate data is given in the table below (P5.21, Levenspiel 1999).
For the reactant concentration to drop from CA0 = 1.3 mol/L to CAf =0.3 mol/L, determine,
a)...
Is this nuclear reaction exothermic or endothermic??
Homework Statement
Is this nuclear reaction exothermic or endothermic??
alpha particle + beryllium -> carbon12 + neutron
Homework Equations
The Attempt at a Solution
Im not quiet sure which one it is, I don't know what...
Well this is something that has been aggravating me since I did the experiment at school and really just want to solve and not have it happen again.
My problem is while mixing varying mL of NaOH and HCl we (my group and me) were supposed to record the varying changes in temperature for the...
Homework Statement
http://www.mrev.org.uk/A-Level_Site/New%20A-Level%20Unit%204/Rates.html
(the answers are at the top - see link)
Could someone please help me with the question (about half way through) on ethyl ethanoate and sodium hydroxide.
in cii) we identified the half life doubles...
I am supposed to balance the following reaction:
CdS + HNO3 (dil) → Cd(NO3)2 + NO + S + H2O
After writing out all the oxidation numbers for each atom, I found that Cd and N are both reduced (Cd5+ → Cd 1+ and N5+ → N2+).
I am wondering how to approach this problem. Is it possible to have 2...
Homework Statement
Take for example the problem given below:
C + O2 → CO2 ΔH°f = -393.5 kJ/mol
2CO + O2 → 2CO2 ΔH°rxn = -566.0 kJ/mol
To determine the ΔH°f of CO from the reaction of C graphite and O2 given those equations, one would solve it as: -393.5 kJ/mol + 1/2(566.0)=...
tert-butyl bromide reacts with HOH to give HBr and the corresponding alcohol ,
C
C-C-C
OH
But tert-butyl alcohol reacts with HCl to give tert-butyl chloride.
HBr is a "stronger" acid than HCl. Is this part of the explanation of the different reactions?
Homework Statement
What is the equation for the reaction of a alpha particle and beryllium with production of one neutron
Homework Equations
Use an a chem equation
The Attempt at a Solution
The masses are 4 + 9 = 1 + x, so x = 12. The atomic numbers (protons) are 2 + 4 = 0 + x...