- #1
zenterix
- 715
- 84
- Homework Statement
- In the book I am reading there is a snippet that seems to indicate
- Relevant Equations
- that it is possible to have a weak acid with a weak conjugate base.
Here is the relevant section from the book
This is all fine, but then there is the followingConsider the equilibrium
$$\mathrm{HA(aq)+H_2O(l)\rightleftharpoons H_3O^+(aq)+A^-(aq)}\ \ \ \ \ K_a=\mathrm{\frac{[H_3O^+][A^-]}{[HA]}}$$
The values of ##\mathrm{[HA]}## and ##\mathrm{[A^-]}## that appear in ##K_a## are the equilibrium concentrations of acid and base in the solution, not the concentrations added initially.
However, a weak acid ##\mathrm{HA}## typically loses only a tiny fraction of its protons, and so ##\mathrm{HA}## is negligibly different from the concentration of the acid used to prepare the buffer, ##\mathrm{[HA]_{initial}}##.
I am under the impression that if an acid is weak (ie, only a small fraction of the molecules donate protons) then the conjugate base is strong (a large fraction of the molecules accept protons).Likewise, only a tiny fraction of the weakly basic anions ##\mathrm{A^-}## accept protons, so ##\mathrm{[A^-]}## is negligibly different from the concentration of the base used to prepare the buffer, ##\mathrm{[A^-]_{initial}}##.
But the snippet above seems to say that that both the acid and the conjugate base are weak.
How can this be?