Calculating Internal Energy Change in a Gas Under Constant Pressure

AI Thread Summary
A gas is compressed at a constant pressure of 0.639 atm from 5.41 L to 2.3 L, with 470 J of energy leaving the gas by heat. The work done on the gas was calculated as approximately 201.31 J, which was confirmed correct. However, the initial calculation for the change in internal energy (ΔU) was incorrect due to using the wrong heat value of 407 J instead of the correct 470 J. With the correct heat value, the change in internal energy is -268.69 J. This highlights the importance of accuracy in values when performing thermodynamic calculations.
duds1234
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Hello, this is my first post, so I apologize in advance if it's not quite up to par.

Homework Statement



A gas is compressed at a constant pressure of 0.639 atm from 5.41 L to 2.3 L. In the process, 470 J of energy leaves the gas by heat.
a) What is the work done on the gas (J)?
b) What is the change in its internal energy(J)?

Homework Equations



a) ##W=-PΔV##
b) ##ΔU=Q+W##

The Attempt at a Solution



a)
##P = 0.639atm {\frac{1Pa}{9.872*10^-6atm}} = 64728.52512Pa##
##ΔV = V_f - V_i = 2.3L - 5.41L = -3.11L {\frac{1*10^{-3}m^3}{1L}} = -0.00311m^3##
##W = -P ΔV = -6.4728.52512Pa * -0.00311m^3 = 201.3057131J##

I submitted my answer to part a and it was correct. Part b is what I need help with. I believe that I am doing it correctly, but my answer is returned as incorrect. My incorrect work and answer appears below.

b)
##ΔU = Q + W = -407J + 201.3057131J = -205.6942869J##

Any insight into why my work/answer for part b is incorrect would be greatly appreciated!
 
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If your answer to part a is correct, then I can't see what's wrong with your answer to part b (see EDIT)

Is this a multi choice question that is automatically assessed?

EDIT: Just noticed that in the question statement you say that 470J of energy leaves, but in the calculation for part b you use the figure 407J
 
Last edited:
Unfortunately, this isn't a multiple choice question. I have to submit my answers electronically and a computer grades them. I have confirmation that part a is correct and that my answer for b is incorrect.
 
Ok. Can you confirm which value of heat leaving the gas is correct: 407 J or 470 J
 
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It is 470, thus this would be my error in part b. Thank you very much for helping me find my silly mistake. The correct answer would be -268.6942869J.
 
You're welcome. It happens to everyone now and then!
 
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