To calculate the number of moles from the gram formula weight of NaCN, 0.01 gram formula weight directly translates to 0.01 moles. The confusion arises from the distinction between gram formula weight and grams; gram formula weight refers to the molecular weight of the compound. The calculation involves understanding that one mole of a substance is equal to its gram formula weight in grams. Therefore, 0.01 gram formula weight of NaCN is equivalent to 0.01 moles. This highlights the importance of correctly interpreting the terminology in stoichiometry.