CO2 and H2CO3 Concentrations in Aqueous Solution: Understanding the Relationship

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In summary, the conversation discusses the concentration of CO2 in aqueous solution and its conversion into H2CO3. The solution states that the concentration of CO2 is equal to H2CO3, which can be used to solve the problem. However, it is uncertain if CO2 completely turns into H2CO3 when dissolved in aqueous solution. The conversation also mentions that there is an equilibrium between CO2, H2O, and H2CO3, but the reaction is fast and can be assumed to be part of the H2CO3 dissociation. This assumption can be used in calculations, even if it is not entirely accurate.
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i_love_science
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Homework Statement
A chemist dissolves 0.135 mole of CO2(g) in 2.50 L of 0.105 M Na2CO3. Calculate the pH of the resulting solution.
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pH
The solution says that the concentration of CO2 is equal to the concentration of H2CO3, which can be used to solve the rest of the problem. Does CO2 turn completely into H2CO3 when dissolved in aqueous solution? Thanks.
 
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Well the solution is a aqueous - it is also alkaline. So what is there in solution (what ions?) already when the CO2 is thrown in, and what is any carbonic acid molecule going to do in that solution? (What do acids do?)
 
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i_love_science said:
The solution says that the concentration of CO2 is equal to the concentration of H2CO3, which can be used to solve the rest of the problem. Does CO2 turn completely into H2CO3 when dissolved in aqueous solution?

Actually we don't know - but it doesn't matter. There is definitely some equilibrium between CO2, H2O and H2CO3, but the reaction is so fast we can safely assume that equilibrium to be just part of the H2CO3 dissociation - it changes Ka a bit, but the value of Ka we OBSERVE already takes into account. So you can safely assume all carbon dioxide gets converted into carbonic acid and use this assumption as a starting point of the calculations, even if it is not entirely correct, the result will be OK.
 
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FAQ: CO2 and H2CO3 Concentrations in Aqueous Solution: Understanding the Relationship

What is the relationship between CO2 and H2CO3 concentrations in aqueous solution?

The concentration of H2CO3 (carbonic acid) in aqueous solution is directly proportional to the concentration of CO2 (carbon dioxide) gas dissolved in the solution. This means that as the concentration of CO2 increases, so does the concentration of H2CO3.

How does temperature affect the concentration of CO2 and H2CO3 in aqueous solution?

As temperature increases, the solubility of CO2 in water decreases, resulting in a decrease in the concentration of both CO2 and H2CO3 in the solution. This is because as the temperature rises, the molecules of CO2 become more energetic and are able to escape from the solution more easily.

What is the significance of understanding the relationship between CO2 and H2CO3 concentrations in aqueous solution?

Understanding this relationship is important in various fields such as environmental science, oceanography, and chemistry. It helps us to better understand the behavior of CO2 and its impact on the environment, as well as the role of H2CO3 in regulating the pH of aqueous solutions.

How do we measure the concentrations of CO2 and H2CO3 in aqueous solution?

The concentrations of CO2 and H2CO3 can be measured using various techniques such as titration, spectrophotometry, and gas chromatography. These methods involve the use of specific indicators or instruments to determine the amount of CO2 and H2CO3 present in the solution.

Can changes in CO2 and H2CO3 concentrations in aqueous solution affect living organisms?

Yes, changes in CO2 and H2CO3 concentrations can have significant impacts on living organisms. For example, an increase in CO2 concentration can lead to ocean acidification, which can harm marine life. Changes in H2CO3 concentration can also affect the pH of bodily fluids in organisms, which can have negative effects on their health and survival.

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