d-orbital self split or proton split d-orbitals?

In summary, "d-orbital self split or proton split d-orbitals?" discusses the differences between two types of splitting in d-orbitals within a molecular or crystal field context. The term "self split" refers to the splitting of d-orbitals due to electron-electron interactions within the same atom, while "proton split" pertains to the influence of protons in the surrounding environment, such as in a crystal lattice, on the energy levels of the d-orbitals. The analysis highlights how these interactions affect the electronic structure and bonding properties of transition metal complexes.
  • #1
adf89812
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TL;DR Summary
why don't d-orbitals split themselves, why does it take a ligand? why can't proton split d-orbital?
why don't d-orbitals split themselves because of themselves without the presence of ligands? Electrons are indistinguishable. Why wouldn't it be more correct that protons from a ligand split the d-orbitals rather than the lone-pairs cause d-orbital splitting energy?
 
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  • #2
adf89812 said:
why don't d-orbitals split themselves because of themselves without the presence of ligands? Electrons are indistinguishable. Why wouldn't it be more correct that protons from a ligand split the d-orbitals rather than the lone-pairs cause d-orbital splitting energy?
Do you have a reference for where you are getting all this from?
 

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