Determine the energies of the three lowest energy states.

AI Thread Summary
The discussion focuses on determining the energies of the three lowest energy states for a particle in a two-dimensional box with specific boundary conditions. The initial setup involves the wave function ψ(x,y) and the calculation of wave numbers k1 and k2, leading to an expression for energy. A key correction is highlighted, noting that the ground state energy was not calculated correctly, as the wave function used corresponds to the first excited state. The distinction between boundary conditions for different box configurations is emphasized, clarifying that both sine and cosine solutions must be considered. Understanding these concepts is crucial for accurately determining the energy states in quantum mechanics.
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Homework Statement


A particle is confined to a two-dimensional box defined by the following boundary conditions: U(x, y) = 0 for \frac{-L}{2} ≤ x ≤ \frac{L}{2} and
\frac{-3L}{2} ≤ y ≤ \frac{3L}{2}, and U(x, y) = ∞ outside these ranges. Determine the energies of the three lowest energy states
Just want the setup right

Homework Equations


ψ(x,y,z)=Asin(k_{1}x)sin(k_{2}y)sin(k_{3}z)

The Attempt at a Solution


So I first started off with
ψ(x,y)=0 at x=\frac{L}{2} and y=\frac{3L}{2}

\Rightarrow k_{1}=\frac{2n_{1}π}{L} and k_{2}=\frac{2n_{2}π}{3L}

So then the energy =
\frac{h^{2}}{8π^{2}m}(k^{2}_{1}+k^{2}_{2})
=\frac{h^{2}}{8π^{2}m}(\frac{4n^{2}_{1}π^{2}}{L^{2}}+\frac{4n^{2}_{2}π^{2}}{9L^{2}})

π^{2} cancels out, factor out 4 and L^{2}

\frac{h^{2}}{2mL^{2}}(n^{2}_{1}+\frac{n^{2}_{2}}{9})

I have it wrong, but I don't know why
the actual one is

\frac{h^{2}}{8mL^{2}}(n^{2}_{1}+\frac{n^{2}_{2}}{9})
 
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You are not calculating the ground state energy! Your wave function is for the first excited state!

Note that there is a difference between boxes [0,L] and [-L/2, L/2]. In the former, the solution is A sin(kx), as B cos(kx) can't satisfy the boundary conditions (0 when x=0). In the latter case however, both solutions must be considered, and in fact, the ground state is the first cosine state.
 
Oh ok I see. I just thought that Asin(kx) applied for everything. It makes sense now, thanks for your help!
 
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