Group I/II Metal oxides always basic in aqueous solution -- why?

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In summary, Group I and II metal oxides are always basic in aqueous solution because they react with water to form hydroxides, which release hydroxide ions (OH⁻) into the solution. This results in a basic environment, as the presence of hydroxide ions increases the pH of the solution. The ability of these metal oxides to readily dissociate in water and produce basic hydroxides is a key characteristic that defines their basic nature.
  • #1
adf89812
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TL;DR Summary
Make argument rigorous

Transform my handy-wavy explanation of why group I/II metals oxides in aqueous solution are basic into a rigorous argument​


I heard an explanation about something being a better proton acceptor or lone pair donor but that doesn't make sense. I couldn't explain in in terms of acid-base theory.

The hand-waving way I saw it was that group I/II metal oxides are less electronegative than non-metals, so in water, they'll donate their electron to the hydrogen, the hydrogen will break away from the oxygen because hydrogen hates oxygen hogging its electrons, and because hydrogen electronegative enough.

With non-metals, my hand-waving is that metal oxides are more electronegative, when they bond with water, they'll just form one bigger molecule because they suck on other's electrons without letting go and form one big acid molecule where the least electronegative thing in there is a hydrogen, which falls of into a proton, and it may or may not be polyprotic.
 
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  • #2
adf89812 said:
group I/II metal oxides are less electronegative than non-metals

Electronegativity is a property of an element, not of a compound.
 
  • #3
Borek said:
Electronegativity is a property of an element, not of a compound.
electronegative doesn't disappear when you form a chemical bond. Oxygen doesn't become less electronegative AFAIK when it bonds.
 
  • #4
adf89812 said:
electronegative doesn't disappear when you form a chemical bond. Oxygen doesn't become less electronegative AFAIK when it bonds.
Maybe there's something about net electronegativity effect in molecules?
 

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