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Ben Niehoff
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PAllen said:diffeomorphism to an orthonormal frame
I would be careful with the language here, as these two concepts have little to do with one another. In this context, you mean a passive diffeomorphism, or a coordinate change. But a choice of frame has, in general, nothing to do with coordinates. A frame is a collection of smooth vector fields on some open subset U such that the vector fields are linearly independent at every point in U. As I mentioned earlier, a frame need not be a coordinate frame (in fact, a frame is a coordinate frame if and only if the Lie brackets between all pairs of vector fields vanish).
Let me see if I can understand your argument on degrees of feedom as follows:
Despite the 20 algebraically independent components of a Riemann tensor satisfying the common symmetries (including, blush, those of the covariant form which imply metric compatibility), and despite the fact that diffeomorphism invariance would not normally reduce degrees of freedom so much, under these assumptions there is, in fact, always a diffeomorphism to an orthonormal frame, and in such a frame the Riemann tensor must take a special form which has only (n)(n-1)/2 degrees of freedom.
Replacing the word "diffeomorphism" with "an invertible linear transformation on each tangent space, chosen continuously on some open patch U", I would say yes.
In fact, I think it can be worded a better way: Given a metric-compatible connection, R(X,Y) at any point P is an element of the group that preserves a metric sphere in the tangent space at P (where a sphere is defined as the locus of points of distance 1 from the origin, according to the inner product given by the metric tensor). The group that preserves a unit sphere in R^n is precisely SO(n), which has dimension n(n-1)/2.