Is BH3 a Lewis Base in Reaction with NH3?

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In the reaction between BH3 and NH3, BH3 acts as a Lewis base while NH3 functions as a Lewis acid. This is determined by the electronegativity values, where nitrogen (N) is more electronegative than boron (B), indicating NH3 can accept electrons more readily. The Lewis structures reveal that NH3 has three bonding pairs and one lone pair, while BH3 has three bonding pairs with no lone pairs, supporting the classification. The presence of an empty orbital in BH3 confirms its role as a Lewis base. Understanding these concepts is essential for accurately identifying Lewis acids and bases in chemical reactions.
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Homework Statement



In the reaction with NH3, is specy BH3 a Lewis base ?

Homework Equations


Lewis acid = electron acceptor
Lewis base = electron donor

The Attempt at a Solution



H electronegativity = 2.1
B electronegativity = 2.0
N electronegativity = 3
Since N-H bond is more electronegative than B-H bond, NH3 is more electronegative than BH3 which means that NH3 is more easily to accept electron. So, NH3 is Lewis acid, BH3 is Lewis base

Is it correct??
My book says that NH3 is the base with no reason, and I doubt that.
 
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A good way to analyse the above problem would be to draw the Lewis structures.There is a reason it is named after G.N. Lewis!
 
sidt36 said:
A good way to analyse the above problem would be to draw the Lewis structures.There is a reason it is named after G.N. Lewis!

Alright,
Based on Lewis structure, NH3 have three pair of bonding electrons and one pair of free electrons while BF3 have three pair of bonding electrons.

and then? How to determine which one is base or acid ?
 
So the electron configuration is something like this
Untitled.png


So i think this might help
 
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My teacher Told me if it has an empty orbital ->Lewis acid
Otherwise its most likely ->Lewis base
 
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Thanks! I got it!
 
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