Mass Spectrometer and Electric Field Problem

In summary, the distance between the lines formed by the singly charged ions of each type on the photographic film in a mass spectrometer with an electric field of 2.48 x 10^4 V/m and magnetic fields of B=B'=0.68 T is 0.0067 m for carbon isotope 12. If the ions were doubly charged, the distance would also be 0.0067 m, as the value of q is doubled for both the electric and magnetic fields.
  • #1
jena
74
0
Hi,

My Question:

Suppose the electic field between the two electric plates in the mass spectrometer is 2.48 x 10^4 V/m and the magnetic fields B=B'=0.68 T. The source contains carbon isotopes of mass number 12,13,14 from a long dead piece of tree(To estimate atomic masses multiply by 1.67 x 10^.27 kg). How far apart are the lines formed by the singlely charged ions of each type on the photographic film? What if the ions were doubly charged?

My work:

For carbon isotope 12

m=(qBB'r)/E

12(1.67 x 10^.27 kg)=((1.6 x 10^.19 coul)(0.68 T)(0.68T)(r))/(2.48 x 10^4 V/m)

r=.0067m

Is this correct :confused:

As for the the ions being doubly charged wouldn't I just double, q.

Thank You :smile:
 
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  • #2
Your answer of r = 0.0067 m is correct for C12, but remember that if a particle travels a semicircle, the separation between lines will be the difference in the diameter (or 2*r) of the ion trajectories.

If the atoms are doubly ionized, then q is doubled. The electric force is twice, but so is the magnetic field.

Remember, if B is the field in the electrostatic field, and the forces of the electric field and magnetic field balance, then

q E = q v B, or v = E/B, thus v is independent of charge.

B' is the deflection field and r = mv / qB' .
 
  • #3


Your calculations for the first part seem to be correct. To answer your second question, yes, if the ions were doubly charged, you would simply double the charge (q) in your calculations. This would result in the ions being closer together on the photographic film, as they would experience a stronger force in the electric field. However, the exact distance between the lines formed would depend on the specific charge of each isotope (q/m ratio), which may differ for different isotopes. It would also depend on the strength of the magnetic field, as this affects the radius of the ion's path.
 

FAQ: Mass Spectrometer and Electric Field Problem

What is a mass spectrometer and how does it work?

A mass spectrometer is a scientific instrument used to measure the mass-to-charge ratio of ions. It works by first ionizing a sample, then separating the ions based on their mass-to-charge ratio using an electric or magnetic field, and finally detecting and measuring the amount of each ion. This information can then be used to identify the individual components of the sample.

What is the purpose of using an electric field in a mass spectrometer?

An electric field is used in a mass spectrometer to accelerate the ionized particles towards the detector. This acceleration allows for the ions to be separated based on their mass-to-charge ratio, as heavier ions will be deflected less by the electric field compared to lighter ions. This separation is crucial in accurately identifying the components of a sample.

What are some common problems that can occur in a mass spectrometer?

Some common problems that can occur in a mass spectrometer include instrumental errors, such as incorrect calibration or contamination of the instrument, and sample preparation errors, such as improper ionization or sample handling. These issues can lead to inaccurate results and should be carefully monitored and corrected.

How is an electric field problem diagnosed and fixed in a mass spectrometer?

An electric field problem in a mass spectrometer can be diagnosed by analyzing the ion signals and their relative intensities. If the signals do not match the expected pattern, it could indicate an issue with the electric field. To fix this problem, the instrument may need to be recalibrated or repaired, or the sample preparation process may need to be adjusted.

How is a mass spectrometer used in different fields of science?

A mass spectrometer is a versatile instrument used in various fields of science, such as chemistry, biology, and physics. It can be used for qualitative analysis, identifying the components of a sample, or quantitative analysis, measuring the amounts of each component. It is commonly used in environmental analysis, drug development, and forensic investigations, among other applications.

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