$$\newcommand{\uvec}[1]{\underline{#1}}$$
That's more or less Cayley's theorem: A rigid body with one point fixed is rotating around this point. Taking this point as the origin of both the space-fixed (inertial) reference frame and the body-fixed reference frame, there must be a rotation matrix mapping the body-fixed Cartesian (righthanded) basis to the space-fixed one
$$\vec{e}_i'=D_{ji} \vec{e}_j.$$
The position vector of a fixed point in the body ##\vec{r}=r_i' \vec{e}_i'## has ##r_i'=\text{const}## (that's the rigidity condition). The same point is described in the space-fixed frame by
$$\vec{r}=r_i' \vec{e}_i' = r_{i}' D_{ji} \vec{e}_j \; \Rightarrow\; r_j=D_{ji} r_i'.$$
So if we write ##\uvec{r}=(r_1,r_2,r_3)^{\text{T}}## and ##\uvec{r}'=(r_1',r_2',r_3')## you have
$$\uvec{r} = \hat{D} \uvec{r}'.$$
Now ##\hat{D}## is a orthogonal ##(3 \times 3##-matrix with ##\mathrm{det} \hat{D}=1##. Thus it's a normal matrix, i.e., ##\hat{D} \hat{D}^{\text{T}}=\hat{D}^{\text{T}} \hat{D}=\hat{1}##, and thus it's diagonalizable. The characteristic polynomial of a real matrix is a real polynomial, and thus you have at least one real eigenvalue, because a real polynomial has only pairs of roots that are conjugate complex or real ones. Since it's a polynomial of degree 3 you must have at least one real eigenvalue. All eigenvalues obey ##|\lambda|=1##. So the three eigenvalues must be ##\lambda_1=\exp(\mathrm{i} \varphi)##, ##\lambda_2=\exp(-\mathrm{i} \varphi)##, and ##\lambda_3 \in \{\pm 1 \}## with some real phase ##\varphi##. Further ##\lambda_1 \lambda_2 \lambda_3=\mathrm{det} \hat{D}=+1##, and from that ##\lambda_3=1##. That means an ##SO(3)## matrix has always one eigenvalue 1. This means the matrix describes a rotation around the direction given by the corresponding real eigenvector.
Of course ##\hat{D}## is in general a function of time, and in general also the rotation axis will be in general time dependent. This momentary rotation axis is given by the momentary angular velocity of the rotating body, but that's another story.