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None.GarberMoisha said:Bound quantum states that collectively act classically... Okayish for a description but hardly any reason why they have to. What law of physics postulates that quanta must form bound states and act classically as chairs?
All we have is that if the initial configuration is ##10^{25}## particles forming a chair, forward quantum mechanical evolution of that multiparticle system will, with probability very close to certainty, lead to continued chair-like behavior (as opposed to something bizarre such as the chair tunneling through the floor).
But that is also the case with classical analysis of macroscopic systems. It’s tempting to think that the classical treatment starts with our ##10^{25}## particles in a known configuration; we turn that configuration over to Laplace’s demon; the demon calculates the forward evolution into some other configuration which is also a well-behaved chair; low-probability weird behavior is precluded because the entire process is deterministic.
But of course we do nothing of the sort - we describe the chair using the bulk properties of the materials it’s made from, and these are inherently statistical in nature. Out of all the inconceivably huge number of possible microstates that correspond to the macrostate “chair” there will be some in which Laplace’s demon finds that eventually all the molecules in the seat are thermally moving in the same direction at the same time, and we would observe decidedly unchairlike weird behavior. As with quantum mechanical weirdness, the probability of actually observing such things in a chair-sized system is vanishingly small so we don’t consider it.
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