Problems related to Maxwell relations

AI Thread Summary
The discussion revolves around a homework problem involving the entropy of a system expressed as S = AU^αV^βN^{1-α-β}. The task is to establish conditions for the derivatives of temperature, pressure, and chemical potential with respect to internal energy, volume, and particle number, respectively. The participant expresses confusion regarding the application of Maxwell relations and attempts to derive relationships using the differential form of the Helmholtz free energy. They seek guidance on transforming variables to solve the problem and mention that the solution will be shared once available. The conversation highlights the complexities of applying thermodynamic principles in this context.
Mayan Fung
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Homework Statement


Given the entropy of a system :
$$ S = AU^αV^βN^{1-α-β} $$
The problem requires me to write
$$ (\frac{∂T}{∂U})_{V,N} > 0,  (\frac{∂P}{∂V})_{U,N} < 0, (\frac{∂μ}{∂N})_{U,V} > 0$$
to find the mathematical constraint of α and β

Homework Equations


dU = TdS - PdV + μdN

The Attempt at a Solution


Actually, I don't quite understand the rationale behind Maxwell relations.
I tried to write
dF = SdT - PdV + μdN
I can then get
$$ (\frac {∂T} {∂F})_{V,N}$$
but I just don't know how to transform the variable. Can anyone give me an idea of these kind of problems. Thanks!
 
This is actually a bonus question in my HW. It wrote something but I think they are wrong. The solution should be ready in the coming few days. I will share the ideas once it is released.
 
you can check it.http://odysriwo8.bkt.clouddn.com/wo.PNG
 
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Likes Mayan Fung
Thanks! I will try it!
 
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