The discussion centers on the relationship between the angle of incidence and the angle of refraction in a prism, specifically noting that their sum equals 60 degrees. This is explained through the geometry of a triangle formed by the light ray and the prism's borders, where the sum of the interior angles is always 180 degrees. One angle in this triangle is established as 60 degrees, while the other two angles are defined as 90 degrees minus the angle of incidence (i) and 90 degrees minus the angle of refraction (r). The conversation emphasizes the importance of understanding the geometric principles at play in refraction. Overall, the geometric relationships help clarify the behavior of light as it passes through a prism.