Spectrophotometry and Beer-Lamberts Law

  • Thread starter Thread starter joeyjo100
  • Start date Start date
  • Tags Tags
    Law
Click For Summary
The discussion centers on calculating the wavelength and frequency of a molecule with a spectral line at 27319 cm-1. It highlights confusion regarding the relationship between frequency and wavelength, clarifying that frequency is not simply the inverse of wavelength. Instead, frequency is determined by dividing the speed of light by the wavelength. Participants emphasize the importance of unit consistency in these calculations. Overall, the conversation underscores the need for a clear understanding of spectrophotometric principles and the Beer-Lambert Law.
joeyjo100
Messages
23
Reaction score
1

Homework Statement


A molecule has a spectral line at 27319 cm-1

what is its wavelength?
what is its frequency?


Homework Equations


A=εCl
where A=absorbance, ε=molar extinction coefficient, C=concentration and l=path length

The Attempt at a Solution


thought about doing 1 over the spectral line for the wavelength, and correcting the units, but then realized frequency is 1 over the wavelength, which would just be the original answer

If I'm honest, i am not sure what it means by a spectral line, think the question may be badly worded
 
Physics news on Phys.org
Frequency is not 1/wavelength. It's easy to see that this equation is not true by looking at the units. Frequency has units of inverse time (e.g. s-1). Wavelength has units of distance (e.g. m). 1/wavelenght does not give units of inverse time.

Frequency is (speed of the wave)/wavelength. You can check the units to see that dividing a speed by a distance give units of inverse time.
 

Similar threads

  • · Replies 5 ·
Replies
5
Views
2K
  • · Replies 11 ·
Replies
11
Views
5K
  • · Replies 7 ·
Replies
7
Views
2K
Replies
1
Views
7K
  • · Replies 1 ·
Replies
1
Views
2K
  • · Replies 8 ·
Replies
8
Views
12K
  • · Replies 9 ·
Replies
9
Views
5K
  • · Replies 10 ·
Replies
10
Views
6K
  • · Replies 4 ·
Replies
4
Views
5K
  • · Replies 5 ·
Replies
5
Views
6K