Thermodynamic cycle and entropy

In summary, thermodynamic cycles cannot achieve 100% efficiency due to the fact that some heat is always rejected and not all processes are 100% reversible. This results in an increase in entropy, which is a measure of energy that cannot be used. Even by using all reversible processes, it is impossible to build a cycle with no heat rejection, as this would require devices that do not exist.
  • #1
EvilKermit
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Alright, I'm confused about why thermodynamic cycles can never have 100% efficiency. There reversible processes right? And a reversible process has zero change in entropy, so then why can't they achieve 100% efficiency. I thought entropy was the measure of energy that cannot be used. How would you measure efficiency if the system increases in entropy?
 
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  • #2
In a thermodynamic cycle, not all of the energy inputted is converted into work. Some heat is always rejected. Not all processes are 100% reversible.
 
  • #3
...so why no try buiding a cycle with all reversible processes, so no heat is rejected? You'll find you can't. Real processes that can be combined into real thermodynamic cycles will always result in a cycle with some entropy.

Try drawing a cycle with no heat rejection on a t-s diagram and see if you can find real processes (devices) that do what the t-s diagram suggests.
 
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FAQ: Thermodynamic cycle and entropy

What is a thermodynamic cycle and how does it work?

A thermodynamic cycle is a series of processes that a system undergoes and eventually returns to its initial state. This cycle allows for the transfer of heat and work to and from the system, while maintaining a constant internal energy. These cycles can be used to convert heat into mechanical work, and are fundamental in understanding and analyzing energy systems.

What is entropy and how does it relate to thermodynamic cycles?

Entropy is a measure of the disorder or randomness of a system. In thermodynamics, it is closely related to the concept of energy and the direction of heat flow. In a thermodynamic cycle, the entropy of a closed system will either remain constant or increase, as energy is transferred and work is done. Entropy can also be used to determine the efficiency of a thermodynamic cycle, as systems with higher entropy tend to be less efficient.

Can thermodynamic cycles be used to convert heat into other forms of energy?

Yes, thermodynamic cycles can be used to convert heat into other forms of energy, such as mechanical work. This is the basic principle behind many heat engines, including steam turbines and internal combustion engines. These cycles rely on the transfer of heat from a high-temperature source to a low-temperature sink, resulting in the production of work.

What are the laws of thermodynamics and how do they apply to thermodynamic cycles?

The laws of thermodynamics are fundamental principles that govern the behavior of energy in a system. The first law states that energy cannot be created or destroyed, only transferred or converted from one form to another. The second law states that the total entropy of a closed system will always increase over time. These laws apply to thermodynamic cycles by dictating how energy is transferred and how entropy changes within the system.

How do real-world factors, such as friction and inefficiencies, affect thermodynamic cycles?

In an ideal thermodynamic cycle, all processes would be reversible and no energy would be lost due to friction or inefficiencies. However, in the real world, these factors cannot be completely eliminated. Friction can cause energy to be lost as heat, reducing the efficiency of the cycle. Inefficiencies, such as leaks or imperfect heat transfer, can also decrease the efficiency of the cycle. In order to improve the performance of thermodynamic cycles, engineers often work to minimize these real-world factors.

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