Time Independence of the Momentum Uncertainty for a Free Particle Wave

In summary, the momentum uncertainty in a situation without a potential is governed by two functions that are constant in time.
  • #1
uxioq99
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Homework Statement
Prove that ##\frac{\sigma_p}{dt} = 0## for a freely moving wave packet in the absence of a potential. (Here, ##\sigma_p## denotes momentum uncertainty.)
Relevant Equations
##\frac{\sigma_p}{dt} = 0##
Mine is a simple question, so I shall keep development at a minimum. If a particle is moving in the absence of a potential (##V(x) = 0##), then
##\frac{\langle\hat p \rangle}{dt} = \langle -\frac{\partial V}{\partial x}\rangle=0##
will require that the momentum expectation value remains constant in time. Now, I must prove that ##\langle \hat p^2 \rangle## is also constant in time. I used the kinetic energy formula ##\hat T = \frac{\hat p^2}{2m}## to assert that ##\frac{d\langle p \rangle}{dt} = 2m\frac{d\langle T\rangle}{dt}=0## because the total kinetic energy of a freely moving particle is conserved. I justified my claim by arguing that there cannot be any work in the absence of a potential so that potential must be constant. Then, the momentum uncertainty ##\sigma_p = \sqrt{\langle p^2 \rangle - \langle p \rangle^2}## is formed from two functions that are constant in time is consequently time-invariant itself.
 
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  • #2
It seems all right to me.  You may check it directly from momentum wavefunction which you get from Gaussian coordinate wavefunction with growing dispersion, by Fourier transform.
 
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  • #3
uxioq99 said:
Homework Statement:: Prove that ##\frac{\sigma_p}{dt} = 0## for a freely moving wave packet in the absence of a potential. (Here, ##\sigma_p## denotes momentum uncertainty.)
Relevant Equations:: ##\frac{\sigma_p}{dt} = 0##

Mine is a simple question, so I shall keep development at a minimum. If a particle is moving in the absence of a potential (##V(x) = 0##), then
##\frac{\langle\hat p \rangle}{dt} = \langle -\frac{\partial V}{\partial x}\rangle=0##
will require that the momentum expectation value remains constant in time. Now, I must prove that ##\langle \hat p^2 \rangle## is also constant in time. I used the kinetic energy formula ##\hat T = \frac{\hat p^2}{2m}## to assert that ##\frac{d\langle p \rangle}{dt} = 2m\frac{d\langle T\rangle}{dt}=0## because the total kinetic energy of a freely moving particle is conserved. I justified my claim by arguing that there cannot be any work in the absence of a potential so that potential must be constant. Then, the momentum uncertainty ##\sigma_p = \sqrt{\langle p^2 \rangle - \langle p \rangle^2}## is formed from two functions that are constant in time is consequently time-invariant itself.
I'm not totally convinced. Why can you assume conservation of KE? The concept of "work" is not very QM.

An alternative is to consider the relationship between momentum and a potential-free Hamiltonian.
 
  • #4
I'd solve the time-dependent Schrödinger equation in momentum representation, given an arbitrary square-integrable ##\psi(t=0,\vec{p})=\psi_0(\vec{p})## and then think about, how to calculate ##\sigma_p(t)## with it.
 

FAQ: Time Independence of the Momentum Uncertainty for a Free Particle Wave

What is the concept of momentum uncertainty in quantum mechanics?

In quantum mechanics, momentum uncertainty refers to the inability to precisely determine the momentum of a particle. This is a direct consequence of the Heisenberg Uncertainty Principle, which states that the more precisely we know the position of a particle, the less precisely we can know its momentum, and vice versa. Mathematically, this is expressed as Δx * Δp ≥ ħ/2, where Δx is the position uncertainty, Δp is the momentum uncertainty, and ħ is the reduced Planck constant.

Why is the momentum uncertainty time-independent for a free particle wave?

For a free particle, the Hamiltonian (total energy) is solely kinetic and does not depend on position. Consequently, the wave function describing a free particle evolves in time in such a way that the momentum distribution remains unchanged. This results in the momentum uncertainty being time-independent because the wave packet's spread in momentum space does not change over time.

How does the wave function of a free particle evolve over time?

The wave function of a free particle evolves according to the Schrödinger equation. For a free particle, the solution can be expressed as a plane wave or a superposition of plane waves. The time evolution of the wave function involves a phase factor exp(-iEt/ħ), where E is the energy of the particle. This phase factor does not affect the probability distribution of momentum, thereby keeping the momentum uncertainty constant over time.

What is the significance of a Gaussian wave packet in this context?

A Gaussian wave packet is often used to describe a free particle because it has a well-defined momentum and position uncertainty. The Gaussian form minimizes the product of position and momentum uncertainties, adhering closely to the Heisenberg Uncertainty Principle. When a Gaussian wave packet evolves over time, its shape in momentum space remains unchanged, leading to a constant momentum uncertainty.

Can external forces affect the time independence of momentum uncertainty?

Yes, external forces can affect the time independence of momentum uncertainty. When a particle is subjected to an external potential, the Hamiltonian is no longer solely kinetic, and the interaction with the potential can change the momentum distribution over time. This results in a time-dependent momentum uncertainty. For a free particle, however, in the absence of external forces, the momentum uncertainty remains time-independent.

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