Time independent Schrödinger Eqn in a harmonic potential

AI Thread Summary
The discussion focuses on solving the time-independent Schrödinger equation for a harmonic oscillator using dimensionless variable substitutions. The user is attempting to simplify the equation but is struggling to match the final form after making substitutions for the variables. They seek clarification on how to properly adjust for the change of variables in the derivative. The response highlights the importance of using the chain rule to correctly transform the derivatives during the substitution process. Understanding this adjustment is crucial for newcomers to quantum mechanics to derive the simplified equation accurately.
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Homework Statement


I am currently reading a textbook on solving the Schrödinger equation for the harmonic oscillator using the series method;
$$-\frac{\hbar^{2}}{2m}\frac{\mathrm{d}^2 \psi }{\mathrm{d} x^2}+\frac{1}{2}m\omega ^{2}x^2\psi =E\psi $$

It starts by using these two dimensionless variable substitutions (which I gather is standard practise): $$\xi \equiv \sqrt{\frac{m\omega }{\hbar}}x$$and$$K\equiv \frac{2E}{\hbar\omega }$$
to produce the simplified equation: $$\frac{\mathrm{d} ^2\psi }{\mathrm{d} \xi ^2}=\left ( \xi ^2-K \right )\psi $$

I cannot match the final equation using these substitutions alone. Surely there must be some adjustment for the change of variables in the derivative? Please can someone explain how to get the final (simplified) equation? (I am a newcomer to quantum mechanics!)

Thanks in advance.
 
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You need to use the chain rule: ##\frac{d}{dx} = \frac{d\xi}{dx} \frac{d}{d\xi}##.
 
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