Understanding electronic configuration

  • #1
Chijioke
14
3
Homework Statement
How is electronic configuration an element shown?
Relevant Equations
Aufbau Principle
I don't really understand this electronic configuration of a thing. Suppose I want show the electronic configuration of calcium, how do I show it? Is like this
  1. 2, 8, 8, 2 or
  2. $$1s^22s^22p^63s^23p^64s^2$$
 
Physics news on Phys.org
  • #2
#2 is the winner!
 
  • #3
chemisttree said:
#2 is the winner!
What then do we call #1?
 
  • #4
I don't think it has a special name. Yes, it is a correct number of electrons on each shell, but it is filling of subshells that is much more important for chemical properties. That's why we prefer #2, as it tells as much more.

And yes, thanks to Aufbau principle they are to some degree equivalent.
 
  • #5
Borek said:
I don't think it has a special name. Yes, it is a correct number of electrons on each shell, but it is filling of subshells that is much more important for chemical properties. That's why we prefer #2, as it tells as much more.

And yes, thanks to Aufbau principle they are to some degree equivalent.
Why then is the filling of subshell much more important for chemical properties?
 
  • #6
You must represent it as in 2. for generality. The Madelung ordering principle has exceptions within the transition metals.
 
  • #7
Chijioke said:
Why then is the filling of subshell much more important for chemical properties?
Because it tells you which orbitals the valence electrons are in, and they are the most important electrons to understand things like the spectrum of atoms and chemical reactivity.
 
  • #8
Chijioke said:
Why then is the filling of subshell much more important for chemical properties?

In a way the only answer you can get is: because that's the way it is.

We don't create these rules, we observe reality and we try to understand and describe it. Sometimes we can - after creating a model of how something works - try to rationalize observed effects and rules and explain them in terms of for example energies involved, but it is not that these rationalizations are the "real" thing. The only real thing is - no pun intended - the observed reality.
 
  • Like
Likes Chijioke
  • #9
Thatdburownnotationknownonly2u

That would be your own notation known only to you. We also have syntax rules for language and agreed upon spellings for words. It conveys better information in a clearer manner.
 
  • Like
Likes jim mcnamara

Related to Understanding electronic configuration

What is electronic configuration?

Electronic configuration is the distribution of electrons of an atom or molecule in atomic or molecular orbitals. It describes the arrangement of electrons around the nucleus of an atom in its different energy levels or shells.

How do you determine the electronic configuration of an element?

The electronic configuration of an element can be determined using the Aufbau principle, Hund's rule, and the Pauli exclusion principle. Electrons fill orbitals starting from the lowest energy level to the highest, with each orbital holding a maximum of two electrons with opposite spins.

What is the significance of electronic configuration in chemistry?

Electronic configuration is crucial in chemistry as it determines an element's chemical properties, reactivity, and placement in the periodic table. It helps predict how an element will interact with others, its ionization energy, electronegativity, and other chemical behaviors.

Why do some elements have irregular electronic configurations?

Some elements have irregular electronic configurations due to electron-electron interactions and the relative energies of orbitals. For example, copper and chromium have configurations that differ from the expected pattern to achieve a more stable, lower-energy state by having half-filled or fully filled d-orbitals.

What are the exceptions to the Aufbau principle?

Notable exceptions to the Aufbau principle include elements like chromium (Cr) and copper (Cu). Instead of following the expected pattern, chromium has an electronic configuration of [Ar] 3d5 4s1, and copper has [Ar] 3d10 4s1. These configurations provide extra stability due to half-filled or fully filled d-subshells.

Similar threads

Replies
2
Views
18K
Replies
11
Views
2K
Replies
4
Views
7K
Replies
6
Views
2K
Replies
4
Views
2K
Replies
4
Views
2K
Replies
5
Views
1K
Back
Top