The voltage in a capacitor can equal the voltage of a power supply under certain conditions, particularly in circuits with inductance. Inductance can cause overshooting of the charging voltage, leading to a phenomenon known as "ringing," observable as decaying oscillations on an oscilloscope. Even in the absence of inductance, the capacitor voltage can match the supply voltage within a small range due to discrete charge carrier sizes and thermal energy effects. These factors contribute to fluctuations around the equilibrium point. Overall, while the voltage in a capacitor typically does not exceed that of the power supply, it can reach equality under specific circumstances.