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One128
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I'm not sure what point you're trying the make here.
Clausius-Duhem inequality, like the 2nd law, only works in one direction - up, towards irreversibility, towards the increase of entropy. But your claim was that physical entropy decreases (and mass increases) with "information". It should therefore be obvious that you can't invoke Clausius-Duhem inequality to justify the alleged effect.
And even if we ignored that the direction is wrong, this wouldn't make anything depend on the data there is, but at best on what the memory has been through. But that has nothing to do with the subject of the thread.
If I understand correctly, you seem to be essentially saying the participating in a process that involves flow of heat can have entropy effects on the material. Putting aside whether that is the case or not - how would that support any point of yours?Andy Resnick said:It's important to remember that the existence of state variables (or even the existence of a thermodynamic state) comes before the definition of reversible, cyclic processes, not the other way around. Also, it's important to realize that the flow of heat can have material effects other than a change in temperature.
So, yes- the actual, measured change in entropy acummulated after a process has occurred depends on the specific process that takes a system from state 1 to state 2. However, the lower bound (the equality in the equation) of the change in entropy is invariant to coordinate changes, satisfies the principle of material indifference-the response of a material is independent of observer- and also satisfies the principle of equipresence (all observers agree on the set of independent variables).
Clausius-Duhem inequality, like the 2nd law, only works in one direction - up, towards irreversibility, towards the increase of entropy. But your claim was that physical entropy decreases (and mass increases) with "information". It should therefore be obvious that you can't invoke Clausius-Duhem inequality to justify the alleged effect.
And even if we ignored that the direction is wrong, this wouldn't make anything depend on the data there is, but at best on what the memory has been through. But that has nothing to do with the subject of the thread.