What is the Time Evolution of a Particle in a Harmonic Potential Energy Well?

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A particle in a harmonic potential well has an initial wave function that combines two energy eigenstates, ψ1 and ψ3. The time evolution of the wave function is expressed as Ψ(x, t) incorporating the classical angular frequency ω0. The probability density function at any time t is derived from the squared modulus of the wave function, yielding an expression that includes terms from both eigenstates and a sine function of time. The symmetry of the probability density function confirms that the expectation value of position, <x>, is zero at all times due to the odd nature of the integrand. The discussion highlights the importance of careful mathematical manipulation in quantum mechanics.
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1. A particle in a harmonic potential energy well is in a state described by the initial wave function

Ψ(x, 0) = (1/√2) (ψ1(x)+ iψ3(x))

where ψ1(x)and ψ3(x) are real normalized energy eigenfunctions of the harmonic oscillator with quantum numbers n =1 and n = 3 respectively.

(a)
Write down an expression for Ψ(x, t) that is valid for all t> 0. Express your answer in terms of ψ1(x), ψ3(x)and ω0, the classical angular frequency of the oscillator.

(b)
Find an expression for the probability density function at any time t> 0. Express your answer in terms of ψ1(x), ψ3(x), ω0 and t.Use the symmetry of this function to show that the expectation value,<x> = 0 at all times.

Homework Equations





The Attempt at a Solution




I have reached Ψ(x, t) = (1/√2) (ψ1(x)exp(-3iw_{}0t/2+ iψ3(x)exp(-7iw_{}0t/2)


for part (b) I'm not sure how to calculate the probability density function at any time t>0 ?

I know that the probability density needs to be even function of x and so therefore being symmetrical about the centre of the well at all times.

Then using the sandwich integral to calculate <x>, it will yield zero as the integrand is an odd function.
 
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What is the definition of the probability density function?
 
it's just the |Ψ|^2 is it not? I don't know how to do the math
 
That's correct, do you now that \psi^* \psi=|\psi|^2, with \psi^* the conjugated wave function?
 
so the conjugate of Ψ(x, t) is (1/√2)(ψ1(x)exp(+3iwt/2) + iψ3(x)exp(7iwt/2)) ?
 
The exponentials disappear and then |Ψ|^2 = (1/2)(ψ1(x) - ψ3(x)).

Am I on the right tracks here?
 
That doesn't look correct to me. Write out the whole expression and show your steps, start with showing what you got for\psi^*.
 
i get \Psi\ast=(1/√2)(ψ1(x)exp(+3iwt/2) + iψ3(x)exp(7iwt/2)) for
 
That is not correct. Note that there is an i in front of \psi_3.
 
  • #10
\Psi\ast=(1/√2)(ψ1(x)exp(+3iwt/2) - iψ3(x)exp(7iwt/2))
 
  • #11
Looking good. Now multiply and be careful when working out the brackets.
 
  • #12
Right so I should have

|\Psi|^2 = 1/2 |\psi1|^2 + |\psi3|^2

+ 2\psi1\psi3sin(2wot)
 
  • #13
Almost correct, don't forget that the entire expression is multiplied by 1/2 not just the first term.

Now write down the expression for <x>.
 
  • #14
that should have been

|\Psi|^2 = [1/2][|\psi1|^2 + |\psi3|^2

+ 2\psi1\psi3sin(2wot)]
 
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