When do cyanide ligands form a tetrahedral geometry with Co2+ ?

In summary, cyanide ligands form a tetrahedral geometry with Co2+ when the coordination number is four, typically in scenarios where steric hindrance or specific electronic preferences favor this arrangement over octahedral coordination. This occurs under certain conditions, such as lower ligand concentration or specific environmental factors that stabilize the tetrahedral configuration.
  • #1
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cyanide ligands form a tetrahedral geometry when?
Is there something about the repulsion of the lone pair on thenitrogen that prevents the cyanides being all on the same plane?
 
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  • #2

When do cyanide ligands form a tetrahedral geometry with Co2+ ?​

Do they? Wikipedia (yes, I know) suggests that Co2+ forms Co(CN)53-:
https://en.wikipedia.org/wiki/Cyanometalate
Ni(CN)42- is square planar, so there's nothing preventing 4 cyanides being in the same plane.
 

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