When do cyanide ligands form a tetrahedral geometry with Co2+ ?

  • #1
adf89812
37
1
TL;DR Summary
cyanide ligands form a tetrahedral geometry when?
Is there something about the repulsion of the lone pair on thenitrogen that prevents the cyanides being all on the same plane?
 
Chemistry news on Phys.org
  • #2

When do cyanide ligands form a tetrahedral geometry with Co2+ ?​

Do they? Wikipedia (yes, I know) suggests that Co2+ forms Co(CN)53-:
https://en.wikipedia.org/wiki/Cyanometalate
Ni(CN)42- is square planar, so there's nothing preventing 4 cyanides being in the same plane.
 

Similar threads

Back
Top