You purchase a bond with a face value of $1000 and a coupon rate of 9.8% compounded semi-annually. The bond has a maturity of 10 years. How mush is the bond worth if you sell it after 3.5 years and the interest rate for similar bonds is 8% compounded semi-annually? Assume you clip the latest...
Consider the hypothetical molecule 1,3,5-cyclohexatriene (not benzene, I am referring to a molecule where no resonance takes place - a molecule with three C=C bonds and 3 C-C bonds). Each carbon atom in this molecule would be participating in one double bond, and so each carbon atom would be sp2...
Is there an equation or algorithm around to calculate bond energies of specific bonds in a molecule purely from atomic properties and the arrangement of the molecule without using lookup tables per molecule?
This assignment is translated from another language, so some words be not be completely correct
Homework Statement
(Annual market rate might be yield to maturity?)
Face value = 1000
Obligation----Condition----Payment profile----Maturity------Annual Coupon Rate-----Annual market rate...
When determining the bond angle of an atom, is it not applicable if you have an atom bonded to only one other atom? such as for CO2, would you only be able to write the angle for C, 180 degrees, but not for oxygen despite the lone pairs?
Hey, guys, I have just watced a fantastic animation of the microscopic process of sound wave traveling, in which model was described as many balls connected by springs.
But the problem is what we learned in thermodynamics chapter is that there is no bonds between molecules in gas, then how...
Homework Statement
Compound X has the following composition by mass : carbon(64.3%) , 7.1% of hydrogen and oxygen (28.6%) . X reduces Fehling's solution to CuO . Copper( I) oxide .0.1 mol of X react with 4480cm3 of hydrogen gas in the presence of nickel catalyst. What 's the possible...
Homework Statement
why acyl chloride can't form hydrogen bond?
there's C=O , which O atom can form hydrogen bond . am i right?Homework Equations
The Attempt at a Solution
OK so we have a dipolar bond between two elements. This bond makes the other electrons redistribute in order to rest in peace. Everything's OK up until now. What happens, however, when two of these other electrons have the same spin an yet they end up together because of this redistribution? I...
This is a question in "Chemical Principles, 6th Edition, Steven Zumdahl":
Bond energy has been defined in the text as the amount of energy required to break a chemical bond, so we have come to think of the addition of energy as breaking bonds. However, in some cases the addition of energy can...
Homework Statement
From a journal I read that the cobalt-based perovskite cathode usually has better ionic and electrical conduction but higher TEC compare to Maganite-based perovskite cathode. Because of the Co-O bond is weaker than Mn-O bond.
e.g.
Cobalt-based perovskite cathode...
Homework Statement
how many is total number of C-C sigma bond in phenylethene?
Homework Equations
The Attempt at a Solution
i have drawn the the strucutre as in the photo. i ended up getting 8 C-C sigma bond. but the ans from my book is 12. How to get 12?
Homework Statement
Choose correct order of C-F bond length
A)C-HF2<C-H2F<C-F3
B)C-F3<C-HF2<C-H2F
C)C-F3<C-H2F<C-HF3
D)C-HF2<C-F3<C-H2FThe Attempt at a Solution
What factors should I look for while measuring bond lengths?
Homework Statement
Prove that if bonding-pair repulsions were maximized in CH3X, then the sum of the bond angles would be 450°.
Homework Equations
In a perfect tetrahedral molecule (e.g. methane), the sum of the bond angles is about 438 degrees (109.5° times 4).
The Attempt at a...
Homework Statement
Consider the geometric isomer of PBr2F3 with a Br-P-Br bond angle somewhat larger than 120 degrees. It is also true that for this isomer ...
There are two sets of identical bond angles.
Homework Equations
PBr2F3 is trigonal bipyramidal (although distorted)...
Homework Statement
I need help rationalizing the following:
a) Bond angle for H2S is only 92o whereas bond angle for H2O is 104.5o.
b) If bond-pair<-> bond-pair repulsion is maximum for the C-H bonds in CH3X, ∑ all bond angles is 450o for CH3X
c) For CH2Br2, the H-C-Br will be the smallest...
The bond enthalpies for these bonds are:
C-C 347 kJ/mol
C-N 276 kJ/mol
C-O 351 kJ/mol
Why is carbon-nitrogen bond enthalpy lower? What factor makes that?
And also the halogens bond enthalpies:
F-F 157 kJ/mol
Cl-Cl 243 kJ/mol
Br-Br 193 kJ/mol
I-I 151 kJ/mol
Why has fluorine lower enthalpy? I...
Hi!
Just wondering if anyone could help with this question:
"now price a bond that is of a 4 year maturity and if it defaults in year t+k incurs a loss of 20%, but it does not terminate, and continues to be traded up to and including the fourth year"
as I understand this is a defaultable...
Homework Statement
What are the number of different bond angles for the isomer of F_{3}PCl_{2} with each chlorine equatorial? What about for the isomer of BrPF_{4} with the bromine axial?
According to the key the the first molecule has 5 unique bond angles.
Homework Equations
Trigonal...
I was recently learning average bond enthalpies and was wondering if it varies at different temperatures. I know that in different molecular configurations, bond strength is affected by the arrangement of the atoms, but at higher temperatures, there is higher vibrational energy, right? So, if we...
Hello,
Theoretical physicists assert that quantum mechanic and relativistic world use distinct mathematical models that can not united into one so far. The reason of it, which I do not understand, is the gravity. Once we encompass the gravity in the quantum world (or vice versa), we (maybe)...
Homework Statement
Steel has a theoretical strength of 4 x 10^10 Pa a density of 7860 kg/m^3, Youngs Modulus of 2 x 10^11 Pa and the mass number of iron, the main ingredient in steel, is 56.
Calculate the bond energy of the steel using the expression for theoretical strength and surface...
I was wondering if a quadruple bond between two carbon atoms would be possible. I found this on wikipedia about "dicarbon": http://en.wikipedia.org/wiki/Diatomic_carbon, which is related to this question, since what I'm describing is an isomer of dicarbon. Anyone have any ideas?
If the bond length of two atoms is the distance where the force of repulsion is equal to the force of attraction, then one could figure out what the bond length of H2 is by setting the net force of attraction to the net force of repulsion and solving for distance. However when I try this ...
Homework Statement
Estimate the bond energy between two water molcules (liquid) in the following way
A: From the density of water and its molecular weight calculate the average distance between the molecules
B:hence show that there are 10^19 molcules per m^2 of surace
C:from the...
I need some maths for a program to determine the exact (or as close as it can be mathed) bond energy of bonds from the first two rows of the periodic table S and P orbitals
all the websites I can find tell you what the average bond energy for a specific common bond is but that won't do for...
Homework Statement
In which of the following pairs of bonds is the shorter bond length not followed by the longer
bond length?
(1) S―O, P―O
(2) C≡C, C=C
(3) C=O, C=S
(4) C―Si, C―S
(5) N≡O, N=O
Homework Equations
Bond length is determined by the bond order (number of bonds)...
I am not in Atomic physics,
Everywhere is the standard picture of a bond with 2 atoms sharing 2 electrons.
Why is it not possible to share 3 or more electrons that it would form something like a tetrahedron (see attachment)
Why does "phosphodiester bond" have "diester" as part of it's name?
Why does "phosphodiester bond" have "diester" as part of it's name?
I don't see two esters. I must be overlooking something. Maybe it's because the two riboses can dissociate into ester form? Thanks.
Hi,
I am looking for a good reference on the relative strengths of several bonds. (I think this is the same as bond dissociation energy?)
I.E., C-C, C-S, C-N, S-Au, etc.
Is there a good reference out there? thanks
I googled it and got both answers, "yes" and "no."
What I mean is: O-H-S, F-H-S, N-H-S, etc.
Ex.'s of "yes": http://www.ncbi.nlm.nih.gov/pubmed/19089987 [PLAIN]http://pubs.rsc.org/en/content/artic.../ce/c0ce00760a[/URL]
Ex. of "no": http://www.nature.com/nature/journal.../149218a0.html
In the compunds below, are the bonds most ionic or covalent?
CH3-Mg-Cl (Grignard reagent), C-Mg bond
[Ag(NH3)2]+ (Tollens' reagent), Ag-N bond
Thanks
John
Consider NH3, if it forms a dative bond with an H+ to form an ammonium ion, will the oxidation number of N change from +3 to +5? My reasoning is that it uses 5 electrons in bonding.
Is that correct?
Homework Statement
My textbook wrote that haloalkanes are generally insoluble in water.It is because the polar
C-X bonds are not polar enough to make the haloalkanes soluble in water.
Consider tetrafluoromethane
Difference in electronegativity between F and C = 4.0 - 2.5 = 1.5
Difference in...
Question Statement:
Which of the above is less stable and more reactive?
Relevant Equations:
None really.
Attempt at solution:
Well, the C-O bond's bond energy is lower so I argued that since it takes less energy to break this bond than it does to break the C=C double bond, then it (C-O) is...
Einstein discovered that general covariance allows his GR equation to have just TWO gravitational/geometric constants: Newton G and a curvature constant he called Lambda. So the symmetry of the theory requires us to put both constants into the equation and investigate empirically whether or not...
Homework Statement
Please refer to the image
Why is y 109 degrees?(given by my teacher)
Homework Equations
None.
The Attempt at a Solution
There are four atoms around the carbon atom, I assumed it to be tetrahedral.
Why is that wrong?
When making the Morse Potential graphs of diatomic molecules going through a transition, the excited state sometimes has a different equilibrium bond length. A visual example is here: http://en.wikipedia.org/wiki/File:Franck-Condon-diagram.png
I was wondering how the average bond length of...
I've learned that there are three types of p shells, namely Px, Py and Pz, each in a different direction. I've also learned that when different atoms bond together, they form specific shapes depending on the number of bonds and electrons.
I want to ask, will the shape of the p or d subshells...
Homework Statement
I know that The diameter is 0.33nm but I am not sure if this is relevant.
The Attempt at a Solution
The sources I have found say that bond strength is not something you calculate but look up. This seems unlikely to be the case for this question however I cannot find a...
A hanging wire made of an alloy of titanium with diameter 0.14 cm is initially 2.9 m long. When a 97 kg mass is hung from it, the wire stretches an amount 1.49 cm. A mole of titanium has a mass of 48 grams, and its density is 4.54 g/cm3.
Based on these experimental measurements, what is...
Hi all,
This forum has been a great resource for me for quite some time, but this is my first time posting a thread.
A fund management company is willing to sponsor my undergraduate studies in engineering at a top university. The 'catch' is I have to work 5 years for them after I graduate...
Homework Statement
What has more ionic character NaF or NaCl?Covalent?
Homework Equations
Measured Dipole moment of NaF 27.2e^-30
Measured dipole moment of NaCl 30e^-30
Dipole moment=qd
Fractional ionic character=measured dipole moment/qd
Equilibrium separation of NaCl =.236nm...
Homework Statement
Calculate the bond length for the NaCl molecule given that three successive wavelengths for rotational transitions are 23.1 mm, 11.6, mm and 7.71 mm.
Homework Equations
I = h*wavelength/4pi*speed of light.
The Attempt at a Solution
I don't understand how to...