Molecular Definition and 583 Threads

A molecule is an electrically neutral group of two or more atoms held together by chemical bonds. Molecules are distinguished from ions by their lack of electrical charge.
In quantum physics, organic chemistry, and biochemistry, the distinction from ions is dropped and molecule is often used when referring to polyatomic ions.
In the kinetic theory of gases, the term molecule is often used for any gaseous particle regardless of its composition. This violates the definition that a molecule contain two or more atoms, since the noble gases are individual atoms.A molecule may be homonuclear, that is, it consists of atoms of one chemical element, as with two atoms in the oxygen molecule (O2); or it may be heteronuclear, a chemical compound composed of more than one element, as with water (two hydrogen atoms and one oxygen atom; H2O).
Atoms and complexes connected by non-covalent interactions, such as hydrogen bonds or ionic bonds, are typically not considered single molecules.Molecules as components of matter are common. They also make up most of the oceans and atmosphere. Most organic substances are molecules. The substances of life are molecules, e.g. proteins, the amino acids they are made of, the nucleic acids (DNA & RNA), sugars, carbohydrates, fats, and vitamins. The nutrient minerals ordinarily are not molecules, e.g. iron sulfate.
However, the majority of familiar solid substances on Earth are not made of molecules. These include all of the minerals that make up the substance of the Earth, soil, dirt, sand, clay, pebbles, rocks, boulders, bedrock, the molten interior, and the core of the Earth. All of these contain many chemical bonds, but are not made of identifiable molecules.
No typical molecule can be defined for salts nor for covalent crystals, although these are often composed of repeating unit cells that extend either in a plane, e.g. graphene; or three-dimensionally e.g. diamond, quartz, sodium chloride. The theme of repeated unit-cellular-structure also holds for most metals which are condensed phases with metallic bonding. Thus solid metals are not made of molecules.
In glasses, which are solids that exist in a vitreous disordered state, the atoms are held together by chemical bonds with no presence of any definable molecule, nor any of the regularity of repeating unit-cellular-structure that characterizes salts, covalent crystals, and metals.

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  1. K

    Chemistry Chemistry: Molecular vs. Atomic Iodine

    Hello, This question is a theory question: I have calculated the moles of molecular iodine in a problem (I2) and the next question asks to calculate the moles of atomic iodine. Do I just multiply the number I have by two (as iodine is a diatomic molecule) or is it a "trick" question and the...
  2. E

    Chemistry Nomenclature, molecular mass, moles help (attempted problems already)

    Alright, below are screen captures of some work that I'm tackling. They show my attempts and answers at the problems. I would like to know whether I'm correct or wrong and how to correct the mistakes. The one I need most help with is, the one where you're given density and asked to find...
  3. M

    The molecular field approximation

    MFA \hat{A}\hat{B}\approx \hat{A}\langle\hat{B}\rangle+\hat{B}\langle\hat{A}\rangle-\langle\hat{A}\rangle\langle\hat{B}\rangle What this mean physically? What we neglect here? If I calculate Neel temperature using this method T_N^{MFA} and using RPA method T_N^{RPA} is there some relation...
  4. K

    Molecular phase shift in a non-enclosed area – how ?

    Hi I have read this and to put it mildly I am confused, so maybe someone can clear this up. The dew point is defined as the point/temperature at which the Partial Pressure of the water vapour within the air packet equals the Saturated Vapour Pressure. I understand that the dew point is a...
  5. A

    Chemistry Styrene and Bromine Reaction: Determining Molecular Formula

    Homework Statement A student allowed a 0.500 gram sample of styrene to react with an excess of bromine.* An unknown product with a mass of 1.27 grams was obtained.**The student repeated the experiment several times and always obtained the same result.**What is the likely molecular formula of...
  6. N

    Textbooks for Atomic and Molecular quantum mechanics?

    Hi, i am self studying quantum mechanics. I completed reading of "Quantum Physics_Eisberg, Resnick" and "Introduction to Quantum Mechanics - D. Griffiths". I want to study further on Atomic and Molecular quantum mechanics. Can anyone suggest me textbook on those topics? Thanks in advance.
  7. R

    Chemistry Molecular formula of combustion?

    complete combustion of 1.1g of a compound of C,H and O gives 2.2g of CO2 and 0.9g of H2O. The compound has a relative molar mass close to 130. Find the molecular formula and true molar mass? dont even no where to begin
  8. K

    Molecular work in an Adiabatic process ?

    Molecular "work" in an Adiabatic process ? I have studied Adiabatic cooling in connection with a rising parcel of air. I’m confused. I understand that temperature is a macroscopic principle (not a Microscopic); molecules do not have a temperature, only velocity and Kinetic energy. I have read...
  9. M

    Border conditions on Molecular Dynamics Simulation

    I'm building a code for Molecular dynamics (in C). I'm employing Lennard Jones Potential, periodic border conditions and I integrate Newton's equations by making use of Verlet Integration. When I plot Time vs Energy graph, what I get isn't a constant! but when border condition are remove, then...
  10. H

    Molecular Assemblers - Tech Challenges & Debate Between Drexler & Smalley

    What technological challenges stand in the way of making molecular assemblers? I mean, what exactly would it entail to generate some sort of nanotechnology that could assemble, from scratch, a car or something? I've heard something about the "fat fingers" and "sticky fingers" problem and...
  11. Y

    Molecular Geometrical Representation

    I would like to have a setup/software to geometrically simulate or represent the given molecule. For example I will input ; 2 hydrogen + 1 oxygen and it will output h2o and draw it's molecular shape. Also it would be much better if the software could give all the possible combinations of the...
  12. B

    Mass speed molecular stability

    If you increase mass with speed does the forces that hold molecules’ together increase in per portion ? If not do the molecules’ fall apart with speed ? If the forces increase in per portion Why does the energy released from the muluation of those forces decrease with speed.
  13. S

    Confusion with molecular geometry [carbon tetrachloride]

    Confusion with molecular geometry [carbon tetrachloride] I'm trying to understand the molecular geometry of four different compounds: CCl_{4} ,CHCl_{3} ,CH_{2}Cl_{2} ,CH_{3}Cl Please tell me whether my thinking is right or not[conceptually]. If it's wrong kindly correct me. for...
  14. G

    Microwaves and heating on molecular level

    hi i am currently dealing with this problem here: i have some water and want to heat it up with microwaves. how do I determine the change in temperature of the water when i just know the characteristic features of the radiation? is there an equation for it? of course this process is not...
  15. J

    Full-Atom Molecular Dynamics embryo -> adult?

    What would be a rough estimate of the computational complexity to simulate an embryo in a full-atom scale from the instant of conception to the death of the aging adult? Its a purely theoretical question and I know that its something like daydreaming for the current technology, but I would...
  16. S

    Programs Pursuing PhD in Molecular Biology & Microbial Genetics

    Iam really interested in molecular biology and microbial genetics, did masters in microbiology and want to get into doctoral program and do serious research in my interesting field. Is it not the good reason to get into phd.
  17. B

    Localization of Molecular Orbitals

    Just curious why chemical physicists bother with localization procedures for molecules. Because atomic orbitals become de-localized when they form molecular bonds, but then it seems people wish to come up with procedures to re-localize. I've read quite a bit on how the de-localization...
  18. M

    Chemistry What Is the Correct Molecular Formula for a Decomposing Nitrogen Hydride?

    Homework Statement 1)When 0.1mol of a hydride of nitrogen , Y, decomposes completely, it produces 0.3mol of gaseous elements. Y might be A)NH3 B)N2H4 C)N2H6 D)N3H6 2) Under the same conditions, 10cm3 of an oxide of nitrogen produces 10cm3 of nitrogen when reduced. The formula of the...
  19. V

    Molecular Opposites: Can We Determine Exact Opposite?

    Is our current technology advanced enough to determine the exact opposite of a certain molecule or chemical? If we are not advanced enough, what would be required for this to be possible? Any thoughts on this please respond. I posted this in physics because there might be some advanced math...
  20. S

    Absorption spectra of molecular hydrogen

    I've been looking everywhere for information on the absorption spectra of molecular hydrogen. I need some pretty exact numbers. If anybody can point me in the right direction it would be greatly appreciated.
  21. A

    Molecular Orbital Diagrams, learning how to draw?

    Hi, So I'm a phd student of physics, but my research overlaps a little with inorganic chemistry, specifically transition metal oxides and spectroscopies of them. I can glean some information MO diagrams and find them quite useful when writing about what I'm doing... however it's difficult to...
  22. Vorde

    Molecular Cloud Clumping Question

    Molecular Cloud "Clumping" Question I have been told that mysterious 'density waves' hit molecular clouds and that these are what cause these large gas and dust fields to condense into stars and from there planets. What I don't understand is why don't we assume that the clouds own gravity...
  23. J

    Chemistry Molecular orbital theory of heterodiatomics?

    Homework Statement What determines the order of the Molecular orbitals in heterodiatomics? The Attempt at a Solution In my book, I have NO with an order of 1s 2s 3s 1p 2p 4s Where s means sigma and p means pi. Also sometimes I see in the book the ordering being 1sigma...
  24. T

    Sherwood number - effective and molecular diffusion

    I'm having a little trouble understanding the Sherwood number, (Sh, mass transfer Nusselt number), which gives the ratio of convective to diffusive mass transfer. My question is: given a system that has a molecular diffusion coefficient of D, the effective diffusion coefficient is measured to De...
  25. D

    Electronic Molecular Spectra - significance of band origin?

    Can anybody tell me the significance of the band origin for a P(Q)R structure in the ultraviolet region of a molecules spectrum? In standard vibrational spectra, I understand that its roughly the harmonic frequency of the oscillator, and that the rotational constant can also be found from...
  26. R

    What Happens to Water Molecules When They Can't Expand?

    I've always been curious about the following: What would happen to water on a molecular level if water were frozen but was unable to expand? Would it just not freeze? Or would the molecules lose their physical properties, particularly in relation to one another? And what would happen to...
  27. B

    Chemistry Probability of molecular states and arrangement

    Homework Statement http://s825.photobucket.com/albums/zz175/bobey/?action=view&current=bbb.jpg" The Attempt at a Solution my attempt to the question is as follow : W is the arrangement factor where N is the total number of states while n is the are the number of particles in energy state...
  28. L

    TINKER molecular mechanics modeling

    Hello PF, I've been given the daunting task of performing energy minimization calculations for my undergraduate research assignment. Is there someone with experience using TINKER? I wanted to use the dynamics.exe for calculations of a protein peptide sequence and it's asking me to enter a...
  29. F

    Molecular Geometry: Experiment vs Modeling

    All general chemistry textbooks have sections about molecular geometry, explaining that H2O is “bent”, NH3 is “trigonal pyramidal” and CH4 is “tetrahedral”, etc. But in a typical introductory textbook, it’s not easy to figure out how much is from experimental (observed) facts and how much is...
  30. B

    Angular dependence (atomic and molecular physics)

    Homework Statement > 'from the form of the spherical harmonic function Y00=1/(sqrt(4pi)), what > can be said about the angular probability distribution of the ground state > of the hydrogen atom?' Homework Equations The Attempt at a Solution notes and textbook don't help its...
  31. L

    What are the rules for drawing molecular diagrams?

    If I have a molecule of pb2SO4 for example, how would I draw that? What are the rules that tell me what attaches to what? When it's only 3 or 4 atoms, it's pretty easy to draw them, but when it's more than that, I have no clue what to do.
  32. T

    Chemistry Molecular weight of unknown acid through titration

    Homework Statement The molecular weight of a monoprotic acid HX was to be determined. A sample of 15.126 grams of HX was dissolved in distilled water and the volume were brought to exactly 250mL in a volumetric flask. Several 50mL portions of this solution were titrated against NaOH solution...
  33. J

    CPMD ( Car-Parrinello Molecular Dynamics)

    What is a wave function optimisation? What is a plane wave cut-off? Thanks
  34. J

    Molecular Dynamics: Classical vs Non-Classical

    For classical molecular dynamics what does the classical bit refer to? What is non-classical molecular dynamics?
  35. S

    Electric potential of hydrogen molecular ion

    Homework Statement The hydrogen molecular ion , with one electron and two protons, is the simplest molecule. The equilibrium spacing between the protons is 0.11nm . Suppose the electron is at the midpoint between the protons and moving at 1.5 m/s perpendicular to a line between the protons...
  36. S

    Molecular Bonding: Questions & Answers

    I have some questions about molecular bonding. I understand that intramolecular bonds (forces holding a molecule together) are stronger than intermolecular bonds (forces between molecules). I also understand that the strength of intermolecular bonds determines whether something is gas (no bond)...
  37. A

    MATLAB How to numerically simulate molecular diffusion

    I want to simulate molecular diffusion in MATLAB. The idea is as follows: http://www.math.chalmers.se/Math/Grundutb/GU/MVG300/V11/Laborationer/anim1.jpg The picture represents a gas container and the red part is a barrier which the gas molecules cannot pass through except for the small...
  38. C

    Chemistry Molecular Biology (Molecular Chaperone Proteins)

    The study of viral particles has revealed significant information regarding protein folding. Many proteins hae been shown to often spontaneously fold into their functional structures and give an active viral particle. Yet some are incapable of proper folding on their own. It was shown in 1973...
  39. J

    Looking for particular Diatomic Molecular Constants

    Hello, I've been looking for a few rotational/vibrational diatomic molecular constants for N2 and O2. I've got a some good literature values for most constants I need involving the calculation in possible vibrational and rotational energy states. I'm looking for the centrifugal distortion...
  40. G

    Molecular physics (easy stupid questions )

    [PLAIN]http://img560.imageshack.us/img560/6712/fizika5.jpg Homework Statement The electric energy is used to heat the liquid in the metalic bowl.. 1.Why is the liquid warmer at the top of the bowl than the bottom? 2. Why does the liquid's temperature raise faster if the metalic bowl has...
  41. D

    How Do Quantum Numbers Encode Molecular Rotational Levels?

    Im doing a study on a polyatomic molecule which is assigned by six quantum numbers, namely the three vibrational modes, and the Rotational quantum number J, and its projections on the A and C axes, (Ka and Kc): J, Ka, Kc, v1, v2, v3 Each combination of these numbers has an energy in...
  42. N

    A Beginner's Guide to Cell and Molecular Biology

    science book :) hi ,i am high school student it's my final year and i am interested in science . i am wondering about a book that i want to buy "cell and molecular biology by gerald karp" is it usefull for me .
  43. D

    Programs Can a molecular biology major do NMR?

    I am a junior molecular biology major. I plan to go into graduate school and currently my #1 topic of interest is using solid state NMR to determine molecular structure. I am doing research on the unrelated topic of bacteriophage genomics but do not want to change labs because I am well...
  44. P

    Chemistry A compound with a molecular weight of 110.1 g

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  45. S

    Coefficient of molecular diffusivity for hot air within room temperature air

    Hi, I have to calculate the Peclet number for a room. This room can be assumed to be at room temperature, and has a heat source within it which causes a temperature difference between the air near it, and the general room temperature. I have been unable to find an equation which will allow me...
  46. C

    New open-shell molecular electronic structure program: What to do with it?

    Hello forum members, I got a nifty new multireference CI program at my hands and now I'm wondering what to do with it. The program is able to correlate general MCSCF wave functions, and as such basically any kind of molecular electronic structure imaginable; in particular also electronic...
  47. I

    Predicting molecular shape without drawing lewis structure

    Is their a method for predicting the molecular shape of molecules without drawing the Lewis structure? I am preparing for an ACS exam and would like to try to save some time on these problems. I think I could determine the steric number by counting the total electrons available, and...
  48. T

    Chemistry Calculating Average Molecular Weight and Equilibrium Constants for Gas Mixtures

    Homework Statement I'm trying to figure out how to compute the average molecular weight of a gas mixture (nitrogen dioxide and dinitrogen tetroxide). I think I'm suppose to use this equation: M(mix)=X(NO2)M(NO2)+ X(N2O4)M(N2O4) , where I would just need to calculate the mole fractions and the...
  49. T

    Chemistry Finding net, ionic and molecular equations

    These are practice problems (not hw) that I'm trying to work on, if anyone could help me out, thanks! I'm trying to find the net, ionic and molecular eq. 1)CaCO2+HCl=CaCl2+CO2(g)+H2O I just know that CO2 AND H2O doesn't break down because it's a gas and liquid. 2)NaHCO3+HBr=NaBr+CO2(g)+H2O
  50. K

    Whats the max molecular weight for a single polymer strand of styrne

    Few quick questions, too lazy to look up this info my self: 1. Whats the max molecular weight for a single polymer strand of styrne (i.e what's the max number of styrenes you can link up). 2. Anyone know about the industrial process to produce ABS? 3. What is a good solvent for Styrene...
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