Molecular Definition and 583 Threads

A molecule is an electrically neutral group of two or more atoms held together by chemical bonds. Molecules are distinguished from ions by their lack of electrical charge.
In quantum physics, organic chemistry, and biochemistry, the distinction from ions is dropped and molecule is often used when referring to polyatomic ions.
In the kinetic theory of gases, the term molecule is often used for any gaseous particle regardless of its composition. This violates the definition that a molecule contain two or more atoms, since the noble gases are individual atoms.A molecule may be homonuclear, that is, it consists of atoms of one chemical element, as with two atoms in the oxygen molecule (O2); or it may be heteronuclear, a chemical compound composed of more than one element, as with water (two hydrogen atoms and one oxygen atom; H2O).
Atoms and complexes connected by non-covalent interactions, such as hydrogen bonds or ionic bonds, are typically not considered single molecules.Molecules as components of matter are common. They also make up most of the oceans and atmosphere. Most organic substances are molecules. The substances of life are molecules, e.g. proteins, the amino acids they are made of, the nucleic acids (DNA & RNA), sugars, carbohydrates, fats, and vitamins. The nutrient minerals ordinarily are not molecules, e.g. iron sulfate.
However, the majority of familiar solid substances on Earth are not made of molecules. These include all of the minerals that make up the substance of the Earth, soil, dirt, sand, clay, pebbles, rocks, boulders, bedrock, the molten interior, and the core of the Earth. All of these contain many chemical bonds, but are not made of identifiable molecules.
No typical molecule can be defined for salts nor for covalent crystals, although these are often composed of repeating unit cells that extend either in a plane, e.g. graphene; or three-dimensionally e.g. diamond, quartz, sodium chloride. The theme of repeated unit-cellular-structure also holds for most metals which are condensed phases with metallic bonding. Thus solid metals are not made of molecules.
In glasses, which are solids that exist in a vitreous disordered state, the atoms are held together by chemical bonds with no presence of any definable molecule, nor any of the regularity of repeating unit-cellular-structure that characterizes salts, covalent crystals, and metals.

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  1. P

    Statistical Mechanics, Molecular Flux, Kinetic Theory

    Question 1: The mean speed for escaping molecules from a hole is 1.88*(k*T)/m)^1/2 (Eq.1) The mean speed for molecules in the Maxwell-Boltz Distribution is 1.596*((k*T)/m)^1/2 (Eq.2 If you were to calculate molecular flux for an ideal gas, which expression would you use? In my...
  2. D

    How does non-ideal behavior of a vapor affect the calculated molecular mass?

    If the vapor of a liquid is NOT really ideal, how would this affect the calculated molecular mass?
  3. S

    Chemistry Molecular Orbital Theory: Why is There Mixing?

    Hi guys i came across molecular orbital theory and i don't understand why sometimes there is orbital mixing. For example B,C,N have no orbital mixing while O,F have orbital mixing. May i know how to know when there is orbital mixing?
  4. X

    What are two molecular states ?

    In molecular orbital theory, there are two molecular states. (see below) I don't know the differences between these two states?
  5. F

    Chemistry How Can You Determine Which Layer Is Which Without Using Densities?

    How would you determine which layer is which without using the densities?
  6. J

    Chemistry Why Do Water and Chloroform Form Separate Layers?

    Q: When water and chloroform, CHCl3, are mixed, the two components separate into two distinct layers, each of which smells strongly of chloroform. Account for these observations in terms fo the polarity of the two substances involved. Describe how you could very quickly determine which of the...
  7. B

    What Is the Molecular Geometry of ClF3?

    Hi, I thought that ClF3 is trigonal bipyramid or triangular bipyramidal. But it is not, so I don't know what it should be named in molecular geometry. Thank you so much to whom ever will answer my confusing thoughts right now! Thank you!
  8. B

    Schools Molecular Biophysics Graduate Schools For Studying Learning and Memory

    Question Based on my background and interests, what graduate schools and programs would be best for me as a PhD-seeking biophysics student intending to ultimately study learning and memory? Background I am a undergraduate in the USA that is preparing to receive four B.S. degrees by Summer...
  9. I

    Chemistry What Is the Molecular Formula of C3H2O with a Molar Mass of 192.8?

    Homework Statement The empirical formula of a compound is C3H2O. If the molar mass of this compound is 192.8, what is its molecular formula? 1. C12H8O4 2. C7H4O 3. C9H6O3 4. C15H10O5Homework Equations The Attempt at a Solution I'm having trouble with this question, I am not getting a whole...
  10. T

    Chemistry Find the molecular and empiral formula

    Homework Statement Digiton is a substance that technologists use to determine cholesterol levels. It contains only (C,H, and O) and its percent composition is 54.71% C, 7.54% H, and 37.74% O by mass. The experimentally determined molecular mass is 1229g/mol. What is the empirical amd molecular...
  11. M

    Difference between Valence bond theory and molecular orbital theory?

    I am having trouble identifying the difference between VB theory and molecular orbital theory. To me, they seem to be one and the same. In VB theory, two atomic orbitals overlap and share electrons forming a bond... Wouldn't this combination of two Atomic orbitals make a molecular orbital?
  12. S

    Molecular orbitals don't get it

    Molecular orbitals... don't get it Hi I'm new, to this forum and molecular science Reading a bit about molecular orbitals, and I have to say the whole concept of anti bonding orbitals and bonding orbitals got me quite confused. when atomic wave functions add you get bonding orbitals when...
  13. K

    Calculating Equilibrium Distance for HCl Electric Dipole and Electron

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  14. C

    Molecular Vibrations - Numerical

    Homework Statement I'm trying to do some numerical stuff with vibrations of H20 and I'm working in mdyne, angstroms, atomic mass units, and angles are given in radians. What would the corresponding unit of time be when I calculate my normal mode frequencies? femtosecond, 10e-15?
  15. O

    Control of matter on an atomic and molecular scale

    Nanotechnology, is a study of the control of matter on an atomic and molecular scale right? I'm currently studying taking this course in my college and I'm wondering if Nanotechnology plays a part in researching cancer cells. Does Nanotechnology helps in treatment of cancer cells? If...
  16. A

    Asking to make sure I understand: Valence bond vs. Molecular Orbital theory.

    Hello. I am currently a freshman in college and finding the chapter on Quantum Mechanics incredibly interesting. Whether I decide to delve into this field is still up in the air, but I am having trouble fully understanding the concepts behind Molecular Orbital Theory and how it relates to the...
  17. C

    Question on Molecular dynamics programming

    Dear all, I am not sure if this is the right place to ask the following. (Moderators, please move this thread to the right sub-forum if necessary.) The question I am having is related to molecular dynamics. In the book "Molecular Dynamics Simulation: Elementary Methods" by J. M. Haile, a...
  18. M

    Molecular Orbital Theory: 2s/3s & 2p Orthogonality Questions

    I have a few questions on molecular orbital theory which I hope you guys can help me settle! So I understand orthogonality meaning that the molecular orbitals have zero overlap, due to the Pauli Exclusion Principle. How do a 2s and 3s molecular orbital achieve orthogonality? Is it due to a...
  19. ~christina~

    Chemistry Molecular structure and analysis method

    Homework Statement \Delta9-Tetrahydrocannabinol (THC) is the primary psychoactive constituent of marijuana. Its metabolites include 11-hydroxy- \Delta9-THC (11-OH-THC) and 11-nor-9-carboxy- \Delta9-THC (THC-COOH). 1)Write down the molecular structure of these three compounds. 2)Develop an...
  20. K

    Physics Molecular biology or particle physics

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  21. E

    How would one collapse a molecular wavefunction?

    In NMR for molecules, one can collapse the nuclear spin wavefunction \psi_{nucspin} by applying the magnetic moment operator \mu. That is, \psi_{nucspin} becomes one of the eigenfunctions of \mu. This physically corresponds to hitting the nuclei with photons in the radiofrequency range. In...
  22. F

    Chemistry Chemistry freezing point and determination of molecular formula

    1. Homework Statement [/b] question 1: Calculate the mole fraction of benzene in benzene-toluene solution that is in equilibrium at 25 deg. Celsius with a vapor pressure that contains 62% mol Benzene. At 25 deg. Celsisus the vapor pressures of benzene and toluene are 95.1 mm Hg and 28.4 mm Hg...
  23. Z

    Potential and distribution in molecular dynamics

    I get this formula in a MD paper:Wavelet-based multi-scale coarse graining approach for DNA molecules P(d)=A*exp(-U(d)/kT) P(d) is the distribution function, U(d) is the potentital. How does this formula come? In the paper I read about this, they get the distribution first, and obtain the...
  24. A

    I must find Temperature, The Distribution of Molecular Speeds.

    Homework Statement A certain gas is at a temperature of 27 degrees Celcius. What would the temperature of the gas have to be to increase the rms speed of the molecules in the gas by 12 percent? Homework Equations V rms = √((3RT)/(M)) The Attempt at a Solution We know R and T...
  25. P

    Heat enthelpy of molecular hydrogen

    Homework Statement Look up the enthalpy of formation of atomic hydrogen in the back of the book. This is the enthalpy change when a mole of atomic hydrogen is formed by dissociating 1/2 mole of molecular hydrogen (the more stable state of the element). From this number, determinethe energy...
  26. M

    Chemistry Liquid Chlorine-Inter and Intra Molecular Forces

    This is the question I was given: "Describe the bonding within and between the molecules in liquid chlorine." I suppose the obvious problem is, I have no idea what the answer is. Any help will be appreciated! :D
  27. M

    Atomic, Molecular, and Optical Physics Grad Programs

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  28. F

    Why Hamiltonian and L^2 Don't Commute in Linear Molecules

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  29. F

    Atomic & Molecular Symbols: What Do They Mean?

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  30. F

    Question about Rydberg equation and molecular orbital

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  31. M

    Chemistry Boltzmann's constant/Maxwell-Boltzmann dist. of molecular speed help

    Homework Statement Calculate the Vrms for U235F6 at 375 degrees C. What % of the molecules have Vrms>500 m/s? I'm not entirely sure on what direction to go in, sadly I missed the day he covered making these graphs and doing these types of problems. I do have all the formulas though...but...
  32. Y

    Can molecular complementation act as a protein inhibitor?

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  33. D

    Molecular Shape Class: AX2E Explained

    I have never come across this term before in my few years of chemistry. At first, i thought it meant molecular shape, such as "trigonal planar" or linear. But apparently, that is not the case. Apparently, it is in some form of AX2E (2 being a subscript), but that's all i can find on the matter...
  34. S

    Chemistry Electronic & Molecular geometry: XeO3F2

    Find the electronic & molecular geometry and polarity of the molecule XeO3F2 For both electronic and molecular geometry I found to be trigonal bipyramid. The polarity of this molecule is Polar. Is this correct?
  35. J

    Ab initio methods molecular polarizability

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  36. S

    Chemistry Lewis dot, electronic and molecular geometry

    Draw the lewis dot, identify the electronic and molecular geometry and determine the polarity of a) NO2Cl and b) SOCl2 a) N has 6 valence electrons O has 6(2) = 12 valence electrons Cl has 7 valence electrons Total : 25 For the Lewis Structure: (* is for space) O-N-O **| **Cl I...
  37. H

    Chemistry I with making some molecular and net ionic equations

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  38. O

    Chemistry Empirical and Molecular Forumla calculation

    Homework Statement Reductic acid contains 52.63% carbon, 5.30% hydrogen and 42.07% oxygen by mass. a) Determine the empirical formula of reductic acid b) If 1.23 g of reductic acid contains 3.25x10^22 atoms of carbon, what is the molecular formula of reductic acid ? c) Calculate the...
  39. E

    Chemistry H NMR Spectrum - Molecular Structure

    Homework Statement Give the structure of C8H8O3.Homework Equations IR tells us that there is an OH group and a C=O group Degree of saturation = 5 --> Benzene ring + C=O H NMR spectrum shows: Peak at ~7.8ppm integrating for 1H and is a doublet Peak at ~7.45ppm integrating for 1H and is a...
  40. X

    Chemistry What is the Molecular Mass of an Unknown Acid Based on Titration Data?

    this is from a lab. i titrated NaOH into 2 grams of an unknown acid with NaOH the equivalence point was at 38.25ml so using 2 grams of an unknown acid and 38.25ml NaOH i have to find molecular mass of the acid. i tried adding 2 to 38.25, but i don't think that is right.
  41. S

    Expirements used to find avagadro's number and molecular dimensions

    :cool: I'm doing my doctorate dissertation on the determination of molecular dimensions. I alredy know avagadro's constant and can understand the science of it, but the math is very complex and difficult to understand.:confused: I also need to know the different experiments that can be used...
  42. I

    Chemistry Help with finding molecular formula at a specific P, V, T

    Homework Statement A gaseous compound is 30.4% nitrogen and 69.6% oxygen by mass. A 5.25 g sample of the gas occupies a volume of 1.00 L and and exerts a pressure of 1.26 atm at -4.0C. Which of the following is its molecular formula? Variables: 30.4% Nitrogen 69.6% Oxygen M(sample)= 5.25g P=...
  43. U

    Chemistry What Is the Molecular Geometry of NH2CH2COOH?

    Hi. Can someone please help me find out the molecular geometry for the NH2CH2COOH-molecule, and tell me how they found it? Thank you so much.
  44. J

    Chemistry How to find the molecular formula out of the molar mass?

    Here is the problem. I have a series of questions that I don't know how to do. They are all basically the same so I will just give an example of one and if I could get a point the right direction that would be great! The molar mass of an important industrial solvent is 78.0 g and its...
  45. K

    Chemistry What is the Molecular Formula of Gallium Oxide from 1.25g Ga and 1.68g GaxOy?

    The question is as follows: Gallium Oxide GaxOy forms when gallium is combined with oxygen. Suppose you allow 1.25 grams of gallium (Ga) to react with O2 and obtain 1.68 g of GaxOy. What is the formula of the product? Can you explain how to solve this problem any help is appreciated, thank you.
  46. M

    Chemistry What are the molecular geometry structures for SeO3, SeO2, and SCl2?

    Homework Statement What are the molecular geometry structure? 1. SeO3 2. SeO2 3. SCl2 The choices are: a.linear b. square planar c. tetrahedral d. trigonal planar e. trigonal pyramidal f. V-shaped
  47. D

    Chemistry How Do You Calculate Moles and Concentration of Ca(2+) in CaC2O4H2O?

    Homework Statement I did an experiment and found the weight of CaC(2)O(4)H(2)0 to be 31.4966 subtracted by the weight of a crucible which is 31.2612. I put this for my weight of CaC204H20 (as I can't think of any other weight that it would be requested). I followed the next question...
  48. T

    Chemistry Honors molecular biology homework help please

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  49. M

    Chemistry Calculate Molecular Weight of Polyethylene from Osmotic Pressure

    WOuld someone be able to give us a hand for this question, I am stumped. Polyethylene is a synthetic polymer or plastic with many uses. 2.06 g of a polyethylene sample was dissolved in enough benzene to make 100 mL of solution, and the osmotic pressure was found to be 1.86 torr at 25oC. What is...
  50. N

    Distribution of speeds in a molecular beam.

    I'm struggling to understand the basis for the following formula. The goal is to find the distribution of molecular speeds emerging from a smal hole in an oven where molecules are allowed to come to thermal equalibrium with the oven walls before exiting through the small whole. The book...
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