A molecule is an electrically neutral group of two or more atoms held together by chemical bonds. Molecules are distinguished from ions by their lack of electrical charge.
In quantum physics, organic chemistry, and biochemistry, the distinction from ions is dropped and molecule is often used when referring to polyatomic ions.
In the kinetic theory of gases, the term molecule is often used for any gaseous particle regardless of its composition. This violates the definition that a molecule contain two or more atoms, since the noble gases are individual atoms.A molecule may be homonuclear, that is, it consists of atoms of one chemical element, as with two atoms in the oxygen molecule (O2); or it may be heteronuclear, a chemical compound composed of more than one element, as with water (two hydrogen atoms and one oxygen atom; H2O).
Atoms and complexes connected by non-covalent interactions, such as hydrogen bonds or ionic bonds, are typically not considered single molecules.Molecules as components of matter are common. They also make up most of the oceans and atmosphere. Most organic substances are molecules. The substances of life are molecules, e.g. proteins, the amino acids they are made of, the nucleic acids (DNA & RNA), sugars, carbohydrates, fats, and vitamins. The nutrient minerals ordinarily are not molecules, e.g. iron sulfate.
However, the majority of familiar solid substances on Earth are not made of molecules. These include all of the minerals that make up the substance of the Earth, soil, dirt, sand, clay, pebbles, rocks, boulders, bedrock, the molten interior, and the core of the Earth. All of these contain many chemical bonds, but are not made of identifiable molecules.
No typical molecule can be defined for salts nor for covalent crystals, although these are often composed of repeating unit cells that extend either in a plane, e.g. graphene; or three-dimensionally e.g. diamond, quartz, sodium chloride. The theme of repeated unit-cellular-structure also holds for most metals which are condensed phases with metallic bonding. Thus solid metals are not made of molecules.
In glasses, which are solids that exist in a vitreous disordered state, the atoms are held together by chemical bonds with no presence of any definable molecule, nor any of the regularity of repeating unit-cellular-structure that characterizes salts, covalent crystals, and metals.
I'm trying to understand how to draw MO diagram for molecules such as CO, HF, and NO. I am finding so much conflicting information on how to order the σ and pi boxes in the diagram. Now, I know that the more electronegative atom's orbitals are going to be lower in energy than the less...
The bond enthalpies for these bonds are:
C-C 347 kJ/mol
C-N 276 kJ/mol
C-O 351 kJ/mol
Why is carbon-nitrogen bond enthalpy lower? What factor makes that?
And also the halogens bond enthalpies:
F-F 157 kJ/mol
Cl-Cl 243 kJ/mol
Br-Br 193 kJ/mol
I-I 151 kJ/mol
Why has fluorine lower enthalpy? I...
Homework Statement
https://ia701205.us.archive.org/11/items/Mechanics_541/LandauLifshitz-Mechanics.pdf
Page 72 of the book itself, but Page 81 of the PDF. Problem 1.
Homework Equations
See Section 24 of the book.
The Attempt at a Solution
So far I have completed and...
I would be most grateful for some tips of interactive software, which shows the hybridized atomic orbitals overlapping in the molecule (I don't mean resulting molecular orbitals but atomic orbitals of which overlapping forms MO).
And does this works also in Mathematica?
Homework Statement
What are the number of different bond angles for the isomer of F_{3}PCl_{2} with each chlorine equatorial? What about for the isomer of BrPF_{4} with the bromine axial?
According to the key the the first molecule has 5 unique bond angles.
Homework Equations
Trigonal...
Homework Statement
An ideal gas is kept in a container of constant volume. The pressure of the gas is also kept constant. The number of molecules in the gas is doubled. If the initial rms speed is 1300m/s, what is the final rms speed?
Homework Equations
Vrms=sqrt[(3kT)/m]
PV=NkT...
If there is a molecule that is negatively charged after gaining an electron and it only needs one hydrogen to be hydrogenated, in the presence of H2 will one of the hydrogen leave the hydrogen pair to hydrogenate the negatively charged molecule? Or does the hydrogen have to be already separated...
Homework Statement
A container of volume 10−3 m3 has a pressure of 10−7 mbar.
Surrounded by air at 1 bar and 290 K, how long does it take the pressure inside to rise to 10−6 mbar when air effuses through a small hole of area 10−17 m2?
Homework Equations
The Attempt at a Solution
Flux ø =...
Hi,
assuming I have the potential for a diatomic molecule in the groundstate i=o and excited state i=1
V_i( r ) = D( 1 − exp[ −β ( r − r_i)] )^2+ C_i
Using collisional excitation with fast electrons.
What is the vibrational quantum number of the state the molecule will most likely be...
I read in my Chemistry workbook that:
"At higher temperatures, vapour pressure increases as more energy is provided to the liquid molecules, allowing them to escape into the gas phase."
At the boiling point, all energy is gone into breaking bonds and to convert liquid phase molecules into...
I have two files with atomic coordinates for the same generated strucutre (cycle made of eight sulphur atoms), but produced by two different progams (so that output files have different coordinates supposedly connected by translation/rotation). Is there some kind of software to compare the two...
Do molecules have intrinsic magnetic fields to them? Let's say you have a water molecule H20. Would the oxygen have a field due to the orientation of it's electrons, and possibly the hydrogens fields act to reduce that field? I'm just curious.
Homework Statement
A scuba tank has a volume of 2800cm3. For very deep dives, the tank is lled with 50%
(by volume) pure oxygen (O2) and 50% pure helium (He). The molar mass of helium
is 4 g mol/1, and for oxygen is 32 g mol/1.
How many molecules are there of each type in the tank if it is...
Homework Statement
Estimate the bond energy between two water molcules (liquid) in the following way
A: From the density of water and its molecular weight calculate the average distance between the molecules
B:hence show that there are 10^19 molcules per m^2 of surace
C:from the...
Estimate the probability that in a room of volume V, all the N molecules of air are found in volume \frac{3V}{4} and none at all in the reaining volume V/4
My take to the solution is
Pr of finding N molecules in \frac{3V}{4} : \frac{N}{3V/4}= \frac{4N}{3V}
Pr finding none in V/4...
Today in 9th grade ADV Biology, we learned about how the two Hydrogen atoms in a Water molecule are relatively positive compared to the Oxygen atom. This is because the Oxygen's pull on Hydrogen's electron is greater than the Hydrogen's, or that its Electronegativity is greater. This unequal...
I have read that the structure of almost all organic molecules can be represented visually as Planar Graphs, i.e. 2-dimensional lattice-like structures consisting of nodes (points) connected by lines in which no lines cross. From the perspective of Physical Chemistry, does anybody know why this...
I have read that relaxation of a rotational or vibrational mode in gases occurs through collisions of molecules , transferring energy of an excited vibrational mode into heat.
But isn't it possible that an excited vibrational mode in molecules relaxes directly by emission of radiation...?
I...
Given that molecules, atoms, protons, and neutrons are overwhelmingly space (i assume quarks and electrons are more than just fields), when an object reaches relativistic speeds, is length contraction the result of a decrease in the geometric space within the molecules, or is it a decrease in...
Homework Statement
Some gas is heated in a sealed container. How do the average distance between the gas molecules, and the frequency of the molecules' collision with the walls, change when the container
(A) has a fixed volume, and
(B) is allowed to expand outwards?
The attempt...
Hi guys,
I hope you don't mind me posting here, I am doing some research into atoms, molecules and microscopes. I have no knowledge of physics, the quantum world or microscopy so if my questions seem silly, please look past that and help me. Thank you
I have two questions. Is there a way...
Homework Statement
Show how you would find the average distance between gas molecules at a specific volume, pressure and temp?
Given;
Pressure=P (torr)
Temp=T (Kelvin)
n=number of mol
N=number of molecules
Volume=V (cm)^3
Homework Equations
pv=nRT N=n*(NA)...
Are there not dipole-dipole interactions between CHBr3, CH3Br, CH3Cl, and CHCl3? Assume they are all separate pure substances. My professor today said that the only intermolecular forces present were dispersion forces. Are the dipole attractions negligible due to fact they are too weak?
Is it true that in general, larger molecules will have smaller HOMO-LUMO gaps?
In this case consider that we are comparing long vs short saturated molecules,
and long vs. short conjugated molecules.
How do I write a full Schrodinger equation, pre-approximation, for a mixture? Let's say 75% H2 and 25% He by number of particles.
I already know the form and very basic applications of the Schrodinger equation and the Hamiltonian. What I want to know is, the specifics, such as how to specify...
Memory Allocation and Basis Sets problems and in Gaussian09
I am starting off with Gaussian09 and GaussView software packages. When I did simulations for single molecules it was fine.
But for crystal structures, I am giving the necessary values of a,b,c,β etc for a simple monoclinic...
Hello fellow physics lovers,
I wish to predict the behaviour of a organic molecule under an electric field (High Voltage). I wish to know how much E-field can this molecules withstand before being fragmented.
Can anyone point toward a freeware than might compute such a field?
It is...
What is the general method for finding symmetry in molecules which would allow you to find which nuclei are equivalent in an NMR spectrum?
I know it sounds vague but it seems inevitable. Any good guides on the Internet would be great. My main issue is with larger molecules whose structures are...
Homework Statement
Look at the image please. The image shows 3 pairs of compounds. Explain why the first two are not chiral but the last one is chiral.
Homework Equations
Ar means Aromatic ring
Aquirais means aquiral
Quirais means chiral
The Attempt at a Solution...
What is the equivalent weight of ozone molecule?
I mean how can I find out the equivalent weight of molecules?
Is it same as the equivalent weight of element?
For example,
FeCl3 ,what will be the equivalent weight of chlorine ?
Homework Statement
A sample of oxygen gas with molar mass 32 g/mol contains 5.0 moles and is at a temperature of 500 K. How many moles of the gas have speeds between 375 m/s and 380 m/s?
Homework Equations
Maxwell Boltzmann Distribution:
f(v) = 4\pi[\frac{M}{2pi RT}]^(3/2) * v^2 *...
The kinetic theory states that the gas molecules are randomly colliding with each other and with the wall of the container with high speed.The area of each molecule is very less and as they are moving with high speed,they exert great force. since the pressure is force/area , the pressure should...
Hello,
The formula for average kinetic energy of molecule is:
k=3/2KT.
Can anyone please explain the derivation without using calculus?
Thanks,
-- Shounak
When we use Boyle's Law it means that as pressure increases the volume of the container would decrease. In my notes they stated that if I were to halve the volume there would be two times the number of collisions per second which implies that the force exerted is doubled. But why is this so? I...
We can simulate physical movements of atoms and molecules and how they interact with many software like ascalaph or abalone.
But can we one day simulate complex interaction of molecules like the interactions that happens inside a simple organism like a simple bacteria?
And going further, can...
When making the Morse Potential graphs of diatomic molecules going through a transition, the excited state sometimes has a different equilibrium bond length. A visual example is here: http://en.wikipedia.org/wiki/File:Franck-Condon-diagram.png
I was wondering how the average bond length of...
Many times, I find it hard to draw correct Lewis structure of molecules with nitrogen. For instance: the Lewis structure of H2CNN. I thought it should be double bond between C and N and single bond between N and N, like this:
But actually it's not. I have done many problems like this wrong...
I'm way outside my realm of knowledge here so perhaps I need some help polishing my question or the concepts behind it. Thank you for your patience.
Does the orientation of circularly polarized light (CPL) as a reaction mechanism influence the chirality of the molecule in a general manner...
I have a need to capture some free sulfur and graphite molecules in the anodizing layer of aluminum, preferably a hard anodizing which uses higher current levels and lower temperature than normal anodizing. I had imagined puting DMSO for the sulfur molecule in the sulfuric anodizing solution and...
Homework Statement
When we have a liquid, there are Van der Waals forces of attraction in between each molecule. Hence, the negatively charged electron cloud would be attracted to the positive nucleus of the neighboring molecule. However, there seems to be a gap in between the molecule (least...
By changing the arrangement of electrons in a molecule's energy levels (without adding or removing any electrons), can the molecule become destabilized or come apart? An example or two would really help.
Thanks,
Jake
I have simulated a box water molecules (1500 water molecules) using molecular dynamics method in NpT ensemble.
I got the time auto-correlation function (C(t) vs t, time) where its function line is parallel to x-axis. Which means the C(t) is zero.
I understand the water molecules are...
Homework Statement
Let a box of height h be filled with classical ideal gas molecules of mass m in a constant gravitational filed g. As will be shown later, the distribution molecular height z obeys:
f(z) = C exp (-mgz/KT)
Where C is the normalization constant
a) find the average height...
Author: Wolfgang Demtröder
Title: Atoms, Molecules and Photons: An Introduction
Amazon Link: https://www.amazon.com/dp/3642102972/?tag=pfamazon01-20
Prerequisities:
Contents:
If molecules generally move at sound speed, given they are accelerated at Mach 1, does this mean there are less arbitrary collisions? or less collisions in general and more molecules move in the direction of mach 1 speed??