A molecule is an electrically neutral group of two or more atoms held together by chemical bonds. Molecules are distinguished from ions by their lack of electrical charge.
In quantum physics, organic chemistry, and biochemistry, the distinction from ions is dropped and molecule is often used when referring to polyatomic ions.
In the kinetic theory of gases, the term molecule is often used for any gaseous particle regardless of its composition. This violates the definition that a molecule contain two or more atoms, since the noble gases are individual atoms.A molecule may be homonuclear, that is, it consists of atoms of one chemical element, as with two atoms in the oxygen molecule (O2); or it may be heteronuclear, a chemical compound composed of more than one element, as with water (two hydrogen atoms and one oxygen atom; H2O).
Atoms and complexes connected by non-covalent interactions, such as hydrogen bonds or ionic bonds, are typically not considered single molecules.Molecules as components of matter are common. They also make up most of the oceans and atmosphere. Most organic substances are molecules. The substances of life are molecules, e.g. proteins, the amino acids they are made of, the nucleic acids (DNA & RNA), sugars, carbohydrates, fats, and vitamins. The nutrient minerals ordinarily are not molecules, e.g. iron sulfate.
However, the majority of familiar solid substances on Earth are not made of molecules. These include all of the minerals that make up the substance of the Earth, soil, dirt, sand, clay, pebbles, rocks, boulders, bedrock, the molten interior, and the core of the Earth. All of these contain many chemical bonds, but are not made of identifiable molecules.
No typical molecule can be defined for salts nor for covalent crystals, although these are often composed of repeating unit cells that extend either in a plane, e.g. graphene; or three-dimensionally e.g. diamond, quartz, sodium chloride. The theme of repeated unit-cellular-structure also holds for most metals which are condensed phases with metallic bonding. Thus solid metals are not made of molecules.
In glasses, which are solids that exist in a vitreous disordered state, the atoms are held together by chemical bonds with no presence of any definable molecule, nor any of the regularity of repeating unit-cellular-structure that characterizes salts, covalent crystals, and metals.
Homework Statement
The graph below shows all of the quantized energies (bound states) for one of these molecules. For this molecule, E0 = -2.5 eV, E1 = -1.20 eV, E2 = -0.72 eV, and E3 = -0.30 eV. What is the minimum amount of energy required to break a molecule apart, if it is initially in the...
Homework Statement
Below about 80 K the heat capacity at constant volume for hydrogen gas (H2) is 3/2k per molecule, but at higher temperatures the heat capacity increases to 5/2k per molecule due to contributions from rotational energy states. Use these observations to estimate the distance...
Does the rms speed of a gas change when the no of molecules are lowered, isothermally?
I know that at same temp, avg kinetic energy remains the same.
m1 (v1)2 = m2 (v2)2
If m2 = m1/2, v22 = 2 v12
Is this correct?
Some chem students need help with homework problems similar to these later this week. and I want to make sure I've got the concepts down before I try to explain anything. This is for introductory chemistry.
1. Can a molecule have only nonpolar bonds and have a dipole?
My first thought was...
Homework Statement
A test tube of cylindrical shape having a length of 10 cm and a diameter of 2 cm contains 20 * 10 ^23 molecules (molecular size d = 3 * 10^-10 m). What is the mean free path of these molecules??
Homework Equations
λ = 1/ pi * d^2 * n
The Attempt at a Solution...
Homework Statement
Explain why molecules in water at room temperature behave like classical particles.
Homework Equations
E = \frac{3}{2}kT = \frac{p^{2}}{2m}
p = \frac{h}{p}
\lambda = \frac{h}{\sqrt{3mkT}}
for room temp, T = 300K.
m is mass of water molecule
k is boltzmanns...
I was browsing about the double slit experiment and found the following tidbit on Wiki:
(emphasis mine)
I knew that electrons could interfere with themselves - I understand how an electron can act like a wave. Even an atom I can understand.
But a molecule?
This isn't merely suggesting...
Homework Statement
There are 3.344 x 10^25 molecules in 1 kg (1 litre) of water. What is the distance between the molecules?
Homework Equations
The Attempt at a Solution
I found the density of water in kg/m^3, then found # moles in 1 litre (55.6) and then from that using Na I...
I've read in quite a few textbooks, chemistry and physics, that we can approximate a gas as many molecules which are floating in space and bouncing off each other. I want to know on what basis we make this approximation. What forces do we ignore and why?
Here are some of the questions I...
Homework Statement
http://img406.imageshack.us/img406/6418/problemo.jpg Homework Equations
<V>=( Integral-from-0-to-inf(V*f(V)*dV) ) / ( Integral-from-0-to-inf (f(V)*dV) )
(second integral is for normalisation)The Attempt at a Solution
http://img32.imageshack.us/img32/529/thermalphysics.jpg
I want to know if there is a way to push or disrupt air molecules around an object, or the device. Like some time of electrical field maybe?
How would one attempt to go about creating a space evacuated of air around the device, with a field, or a vacuum nearing evacuation.
Homework Statement
This question is about microwave (rotational) spectroscopy.
Which of the following molecules have a microwave spectrum?
H2, N2, NO, N2O, CH4, CO2, OCS, H2O, Ethene, Benzene.
The Attempt at a Solution
According to my textbook, it appears that all molecules have a...
Homework Statement
Microwave oven I. The glass window isn't important to the microwave oven's operation, but the metal grid associated with that window certainly is. The grid forms the sixth side of the metal box that traps the microwaves so they cook food effectively. What is the approximate...
Homework Statement
I am doing an exercise from my physics book right now.
I am given:
1 molecule of hydrogen corresponds to 3.7x10^-26 m^3
1 molecule of led corresponds to 2.99x10^-29 m^3
the ratio of these volumes is 1.22x10^3
Q: Determine that the order of magnitude of the ratio...
So, I was playing around with this virtual lab online. I could add light gas or heavy gas to try to make the piston move. I got the same results using both gases..in other words, it took the same amount of light gas to move the piston as it did using heavy gas. Why is that? One would think it...
How many number of moles of molecules are there in 1 mol dm-3 of HCl?
Is it correct to find it this way?
Number of moles of HCl = 1 mol
Number of moles of H2O = 1000/18 = 55.6 mol
So, total number of moles = 55.6 + 1 = 56.6 molesIf i change the question of 3 mol dm-3 of HNO3,
Then the total...
Homework Statement
What is the total translational kinetic energy of the gas molecules of 0.450 mol of air at atmospheric pressure that occupies a volume of 5.00 L (0.00500 m3)?
Homework Equations
P=2/3(N/V)<Ktr>
N= 0.450 mol
V= 5.00L
Want to find Ktr
The Attempt at a Solution...
A hydrogen bond is the attractive force between one electronegative atom and a hydrogen covalently bonded to another electronegative atom. Doesn't this apply to hydrochloric acid?
Homework Statement
For the following molecules, predict the order of their boiling points from highest to lowest.
1. CH_{3}F
2. C_{2}H_{6}
3. CH_{3}OH
4. C_{2}H_{4}
The Attempt at a Solution
I think the answer is 3 4 2 1. I put 3 first because it is an alcohol and has hydrogen...
Homework Statement
A glass of water has a volume of 6.0 x 10*-4 cubic metres.
How many moles of water molecules are there in the glass?
Homework Equations
The Attempt at a Solution
I know it has something to do with Avogadro’s number but can’t figure out exactly what to do...
I've heard molecules are constantly moving or vibrating. What is the mechanism behind this? Where does the energy come from, and go? Is it always a function of temperature/pressure?
Homework Statement
(a)What is the mean free path for oxygen molecules at 300K and atmospheric
pressure (105 Pa) and the average frequency of collisions for a particular molecule?
(The diameter of an oxygen molecule is 0.29 nm).
(b)What is the mean free path of oxygen molecules at an...
I don't know how to distribute large amount of molecules(say a million) to many ro-vibrational states(say 100 states), according to the relative population of these states. As is very important when I want to simulate numerically the classical trajectory of these molecules in a spatially...
Homework Statement
It is hard to imagine that there can be enough air between a book and a table so that there is a net upward (buoyant) force on the book despite the large downward force on the top of the book. About how many air molecules are there between a textbook and a table, if there is...
Hello
I was just revising for my Quantum Mechanics A exam and was considering the 1D double well model of an H2+ molecule. As I understand it Psi2 is non zero between the wells and therefore there is some negative charge present to which the H+ nuclei are attracted resulting in a covalent...
Consider a compressible fluid such as air. Assume we can neglect viscosity. We might describe such a fluid at some small region with a set of numbers. Three numbers would give the components of the velocity vector of the air at that small region and two more numbers would give the density and...
I've been doing some research on singlet-triplet molecular states, and one things I can't perfectly settle is a rigorous demonstration of why the triplet state is a higher energy than the singlet.
One way I can qualitatively understand why the singlet state has lower energy is this: If the...
Homework Statement
given that in a system, there are 5 % oxygen and 8 % nitrogen. it's also given the molecular mass of the two gasses. find the distance between molecules
Homework Equations
The Attempt at a Solution
i don't know what the percentage is for. is it the percentage...
Homework Statement
Millikan: A tiny, charged, sphere of water, with a radius of 1.25 microns is suspended at rest, in a vacuum, between the parallel plates of a capacitor. If the plates are 1 cm. apart, and have a potential difference of 500 volts between them, find the number of individual...
So far I've managed to draw a sort of diamond structure but i want to put spheres on some of the connecting vertices, put figuring out the angles and distances is quite tough, i was wondering whether there was any way of moving a sphere along a connecting vertex line directly.
Any one any...
a) Show that the typical speed of air molecules in the room where you're sitting is about 500 m/s.
b) Show that the typical speed is about 420 m/s at Mt. Everest. (Neglect the temperature difference between sea level and mountaintop, and assume that the air consists of only nitrogen...
Hi
I'm currently studying cell biology, and I'm reading about the hydrophobic parts of the plasma membrane of the animal cell. But I'm wondering, what exactly makes a molecule hydrophilic or hydrophobic? What is the chemistry behind it, and how can I tell which molecules are which? I know that...
Homework Statement
What volume of CH4 at 0°C and 1.00 atm contains the same number of molecules as 0.58 L of N2 measured at 35.0 °C and 1.50 atm?
Homework Equations
I think you just need to use Avogadro's Number and multiply by the molar mass?
I guess my question is what equation would...
Homework Statement
Think about forces between molecules, and explain why we might expect B(cm^3/mol) to be negative at low temperatures but positive at high temperatures.
Homework Equations
The Attempt at a Solution
Well at low temperatures the motion of particles are not as...
Homework Statement
4.60×1023 nitrogen molecules collide with a 20.0cm^2 wall each second. Assume that the molecules all travel with a speed of 450m/s and strike the wall head on.
What is the pressure on the wall in pascals (Pa)?
Homework Equations
p=(1/3)*(N/V)*(m*v_rms^2)
where...
Hi, the question, I'm having problems with is this:
A 1.0 mol sample of hydrogen gas has a temperature of 30 C. What is the total kinetic energy of all the gas molecules in the sample? How fast would a 75 kg person have to run to have the same kinetic energy?
Relevant equations:
K = (3/2)kT...
chemistry, how do i draw the lewis structures for these molecules?
i have tried all sorts of ways but keep on geting stuck with atoms which i can't connect, don't have enough non paired valence electrons to join em all up
H_{5}IO_{6}
TeF_{6}
IF_{7}
SF_{4}
BrCL_{3}
In high school I've been told that the molecules of gases have generally speed of severals kilometers per second. Hence why the wind is not always present, and why not that fast? (I guess it has to see with the huge number of particles... I never studied such a system in Physics yet, I...
Homework Statement
(from Goldstein, problem 3.12)
Suppose that there are long-range interactions between atoms in a gas in the form of central forces derivable from potential
U(r) = \frac{k}{r^m},
where r is the distance between any pair of atoms and m is a positive integer. Assume further...
Homework Statement
In a period of 1 s, 5 x 10^23 nitrogen molecules strike a wall with an area of 8 cm^2. Assume the molecules move with a speed of 300 m/s and strike the wall head-on in elastic collisions. What is the pressure exerted on the wall? (The mass of one N2 molecule is 4.68 x...
Homework Statement
I have a 3 compounds with the same formula: C6H12O2
I need to find the molecules by interpreting the H NMR spectroscopy
http://aceorganic.pearsoncmg.com/epoch-plugin/tempfiles/1867_430.jpg
http://aceorganic.pearsoncmg.com/epoch-plugin/tempfiles/1869_524.jpg...
Homework Statement
What is the total number of atoms in the molecules?
NH3 - 2.5 mole
Homework Equations
Would you multiply the number of atoms in NH3 by Avogadro constant to find the number of atoms?
(4 atoms)(6.02*10^23)
=answer
Or would you multiply the number of moles by Avogadro...
If one considers an ideal gas, what does the mean time between collissions of the molecules depend upon? molecular size? number per unit volume? temperature of the gas?
I'm thinking so far, it must def depend on number density. It would usually depend on molecular size (but I thought an ideal...
In a gas, do the molecular centers of gravity align significantly toward the dominant source of gravity? E. g., do atmospheric water vapor molecules tend to have their oxygen atoms facing Earth's center?
I am kind of confused by the conflict of the following two concepts.
If I understood correctly, internal energy of a system is independent of the volume occupied by the gas molecules. This is because the gas molecules are assumed to be ideal and therefore have no intermolecular interactions...
Do the atoms in molecules separate quicker if they are moved more vigourously in their lifetime and therefoe cause death of the living organism they makes up sooner? For example: A giant tortoise is slower than a cheatah during its life and lives longer. A tree is slower than a tortoise and...
I have a question about something that has been bothering me for a while...
In all of my chemistry classes, my professors have always told me that it is impossible to predict which way a chiral molecule will rotate plane-polarized light (i.e., you will see if a molecule is D or L, but, saying...