Molecules Definition and 561 Threads

A molecule is an electrically neutral group of two or more atoms held together by chemical bonds. Molecules are distinguished from ions by their lack of electrical charge.
In quantum physics, organic chemistry, and biochemistry, the distinction from ions is dropped and molecule is often used when referring to polyatomic ions.
In the kinetic theory of gases, the term molecule is often used for any gaseous particle regardless of its composition. This violates the definition that a molecule contain two or more atoms, since the noble gases are individual atoms.A molecule may be homonuclear, that is, it consists of atoms of one chemical element, as with two atoms in the oxygen molecule (O2); or it may be heteronuclear, a chemical compound composed of more than one element, as with water (two hydrogen atoms and one oxygen atom; H2O).
Atoms and complexes connected by non-covalent interactions, such as hydrogen bonds or ionic bonds, are typically not considered single molecules.Molecules as components of matter are common. They also make up most of the oceans and atmosphere. Most organic substances are molecules. The substances of life are molecules, e.g. proteins, the amino acids they are made of, the nucleic acids (DNA & RNA), sugars, carbohydrates, fats, and vitamins. The nutrient minerals ordinarily are not molecules, e.g. iron sulfate.
However, the majority of familiar solid substances on Earth are not made of molecules. These include all of the minerals that make up the substance of the Earth, soil, dirt, sand, clay, pebbles, rocks, boulders, bedrock, the molten interior, and the core of the Earth. All of these contain many chemical bonds, but are not made of identifiable molecules.
No typical molecule can be defined for salts nor for covalent crystals, although these are often composed of repeating unit cells that extend either in a plane, e.g. graphene; or three-dimensionally e.g. diamond, quartz, sodium chloride. The theme of repeated unit-cellular-structure also holds for most metals which are condensed phases with metallic bonding. Thus solid metals are not made of molecules.
In glasses, which are solids that exist in a vitreous disordered state, the atoms are held together by chemical bonds with no presence of any definable molecule, nor any of the regularity of repeating unit-cellular-structure that characterizes salts, covalent crystals, and metals.

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  1. C

    Quantized Energy of Molecules: Minimum Energy to Break Apart

    Homework Statement The graph below shows all of the quantized energies (bound states) for one of these molecules. For this molecule, E0 = -2.5 eV, E1 = -1.20 eV, E2 = -0.72 eV, and E3 = -0.30 eV. What is the minimum amount of energy required to break a molecule apart, if it is initially in the...
  2. E

    Distance between hydrogen molecules in H2 using specific heat capacity

    Homework Statement Below about 80 K the heat capacity at constant volume for hydrogen gas (H2) is 3/2k per molecule, but at higher temperatures the heat capacity increases to 5/2k per molecule due to contributions from rotational energy states. Use these observations to estimate the distance...
  3. S

    Does Halving Molecules Double RMS Speed?

    Does the rms speed of a gas change when the no of molecules are lowered, isothermally? I know that at same temp, avg kinetic energy remains the same. m1 (v1)2 = m2 (v2)2 If m2 = m1/2, v22 = 2 v12 Is this correct?
  4. B

    Chemistry Questions on polar and nonpolar molecules

    Some chem students need help with homework problems similar to these later this week. and I want to make sure I've got the concepts down before I try to explain anything. This is for introductory chemistry. 1. Can a molecule have only nonpolar bonds and have a dipole? My first thought was...
  5. N

    Calculating Mean Free Path of Molecules in a Test Tube

    Homework Statement A test tube of cylindrical shape having a length of 10 cm and a diameter of 2 cm contains 20 * 10 ^23 molecules (molecular size d = 3 * 10^-10 m). What is the mean free path of these molecules?? Homework Equations λ = 1/ pi * d^2 * n The Attempt at a Solution...
  6. A

    Why molecules exhibit classical behaviour at room temp

    Homework Statement Explain why molecules in water at room temperature behave like classical particles. Homework Equations E = \frac{3}{2}kT = \frac{p^{2}}{2m} p = \frac{h}{p} \lambda = \frac{h}{\sqrt{3mkT}} for room temp, T = 300K. m is mass of water molecule k is boltzmanns...
  7. DaveC426913

    Double slit experiment - with molecules?

    I was browsing about the double slit experiment and found the following tidbit on Wiki: (emphasis mine) I knew that electrons could interfere with themselves - I understand how an electron can act like a wave. Even an atom I can understand. But a molecule? This isn't merely suggesting...
  8. R

    Distance between water molecules.

    Homework Statement There are 3.344 x 10^25 molecules in 1 kg (1 litre) of water. What is the distance between the molecules? Homework Equations The Attempt at a Solution I found the density of water in kg/m^3, then found # moles in 1 litre (55.6) and then from that using Na I...
  9. W

    Gas considered as lots of molecules

    I've read in quite a few textbooks, chemistry and physics, that we can approximate a gas as many molecules which are floating in space and bouncing off each other. I want to know on what basis we make this approximation. What forces do we ignore and why? Here are some of the questions I...
  10. V

    Average speed of effusing molecules

    Homework Statement http://img406.imageshack.us/img406/6418/problemo.jpg Homework Equations <V>=( Integral-from-0-to-inf(V*f(V)*dV) ) / ( Integral-from-0-to-inf (f(V)*dV) ) (second integral is for normalisation)The Attempt at a Solution http://img32.imageshack.us/img32/529/thermalphysics.jpg
  11. F

    Is there a way to disrupt air molecules?

    I want to know if there is a way to push or disrupt air molecules around an object, or the device. Like some time of electrical field maybe? How would one attempt to go about creating a space evacuated of air around the device, with a field, or a vacuum nearing evacuation.
  12. T

    Chemistry Molecules with Microwave/Rotational spectrum

    Homework Statement This question is about microwave (rotational) spectroscopy. Which of the following molecules have a microwave spectrum? H2, N2, NO, N2O, CH4, CO2, OCS, H2O, Ethene, Benzene. The Attempt at a Solution According to my textbook, it appears that all molecules have a...
  13. C

    Chemistry Chemistry - Trying to name aromatic compounds and organic chemistry molecules

    Im trying to name the following molecules 1- CH3-CH2-CH-CH2-CH-CH2-CH2-CH3 l l CH3 CH2 l CH3 2- CH3-CH2-CH-CH2-CH-CH3 l l CH2 CH2...
  14. G

    Secrets of the Microwave Oven: Grid Dimensions & Polar Molecules

    Homework Statement Microwave oven I. The glass window isn't important to the microwave oven's operation, but the metal grid associated with that window certainly is. The grid forms the sixth side of the metal box that traps the microwaves so they cook food effectively. What is the approximate...
  15. F

    Volume, moles, density, molar mass =>separation of molecules

    Homework Statement I am doing an exercise from my physics book right now. I am given: 1 molecule of hydrogen corresponds to 3.7x10^-26 m^3 1 molecule of led corresponds to 2.99x10^-29 m^3 the ratio of these volumes is 1.22x10^3 Q: Determine that the order of magnitude of the ratio...
  16. A

    Why does mass not affect gas pressure in ideal gas law?

    So, I was playing around with this virtual lab online. I could add light gas or heavy gas to try to make the piston move. I got the same results using both gases..in other words, it took the same amount of light gas to move the piston as it did using heavy gas. Why is that? One would think it...
  17. F

    Chemistry How Many Total Moles Are in a 1 Mol dm-3 Solution of HCl?

    How many number of moles of molecules are there in 1 mol dm-3 of HCl? Is it correct to find it this way? Number of moles of HCl = 1 mol Number of moles of H2O = 1000/18 = 55.6 mol So, total number of moles = 55.6 + 1 = 56.6 molesIf i change the question of 3 mol dm-3 of HNO3, Then the total...
  18. T

    What is the total translational kinetic energy of the gas molecules

    Homework Statement What is the total translational kinetic energy of the gas molecules of 0.450 mol of air at atmospheric pressure that occupies a volume of 5.00 L (0.00500 m3)? Homework Equations P=2/3(N/V)<Ktr> N= 0.450 mol V= 5.00L Want to find Ktr The Attempt at a Solution...
  19. K

    Why are intermolecular HCl molecules among them not considered hydrogen bonds?

    A hydrogen bond is the attractive force between one electronegative atom and a hydrogen covalently bonded to another electronegative atom. Doesn't this apply to hydrochloric acid?
  20. T

    Predict Boiling Points of Molecules: CH_{3}F, C_{2}H_{6}, CH_{3}OH, C_{2}H_{4}

    Homework Statement For the following molecules, predict the order of their boiling points from highest to lowest. 1. CH_{3}F 2. C_{2}H_{6} 3. CH_{3}OH 4. C_{2}H_{4} The Attempt at a Solution I think the answer is 3 4 2 1. I put 3 first because it is an alcohol and has hydrogen...
  21. C

    How Many Water Molecules in a Glass?

    Homework Statement A glass of water has a volume of 6.0 x 10*-4 cubic metres. How many moles of water molecules are there in the glass? Homework Equations The Attempt at a Solution I know it has something to do with Avogadro’s number but can’t figure out exactly what to do...
  22. N

    Molecular Vibrations: Mechanism, Energy Source & More

    I've heard molecules are constantly moving or vibrating. What is the mechanism behind this? Where does the energy come from, and go? Is it always a function of temperature/pressure?
  23. K

    Calculating Mean Free Path & Avg. Separation of Oxygen Molecules

    Homework Statement (a)What is the mean free path for oxygen molecules at 300K and atmospheric pressure (105 Pa) and the average frequency of collisions for a particular molecule? (The diameter of an oxygen molecule is 0.29 nm). (b)What is the mean free path of oxygen molecules at an...
  24. D

    C/C++ How to distribute molecules to states using C++

    I don't know how to distribute large amount of molecules(say a million) to many ro-vibrational states(say 100 states), according to the relative population of these states. As is very important when I want to simulate numerically the classical trajectory of these molecules in a spatially...
  25. J

    Buoyant Force and air molecules

    Homework Statement It is hard to imagine that there can be enough air between a book and a table so that there is a net upward (buoyant) force on the book despite the large downward force on the top of the book. About how many air molecules are there between a textbook and a table, if there is...
  26. hagopbul

    Studying the Zeeman Effect on Molecules

    hello all how we can study the zeeman effect on molecule what is the bases to do it or it is the same for atoms.
  27. T

    Why do molecules not fall apart under observation?

    Hello I was just revising for my Quantum Mechanics A exam and was considering the 1D double well model of an H2+ molecule. As I understand it Psi2 is non zero between the wells and therefore there is some negative charge present to which the H+ nuclei are attracted resulting in a covalent...
  28. Spinnor

    Velocity, density, ect. : air : molecules spinor field :?:?

    Consider a compressible fluid such as air. Assume we can neglect viscosity. We might describe such a fluid at some small region with a set of numbers. Three numbers would give the components of the velocity vector of the air at that small region and two more numbers would give the density and...
  29. S

    Triplet vs. Singlet diatomic molecules: Why the energy difference?

    I've been doing some research on singlet-triplet molecular states, and one things I can't perfectly settle is a rigorous demonstration of why the triplet state is a higher energy than the singlet. One way I can qualitatively understand why the singlet state has lower energy is this: If the...
  30. H

    Average distance between water molecules

    Does anyone know what the average distance between water molecules at rtp is, or how I could work this out? Thanks hgbreton
  31. S

    What is the relationship between gas composition and molecular distance?

    Homework Statement given that in a system, there are 5 % oxygen and 8 % nitrogen. it's also given the molecular mass of the two gasses. find the distance between molecules Homework Equations The Attempt at a Solution i don't know what the percentage is for. is it the percentage...
  32. C

    Unraveling Millikan's Experiment: Calculating Electrons & Water Molecules

    Homework Statement Millikan: A tiny, charged, sphere of water, with a radius of 1.25 microns is suspended at rest, in a vacuum, between the parallel plates of a capacitor. If the plates are 1 cm. apart, and have a potential difference of 500 volts between them, find the number of individual...
  33. P

    Drawing Molecules using openGL?

    So far I've managed to draw a sort of diamond structure but i want to put spheres on some of the connecting vertices, put figuring out the angles and distances is quite tough, i was wondering whether there was any way of moving a sphere along a connecting vertex line directly. Any one any...
  34. K

    Typical Speed of Air Molecules at Different Elevations

    a) Show that the typical speed of air molecules in the room where you're sitting is about 500 m/s. b) Show that the typical speed is about 420 m/s at Mt. Everest. (Neglect the temperature difference between sea level and mountaintop, and assume that the air consists of only nitrogen...
  35. U

    Cell Biology: What Makes Molecules Hydrophobic & Hydrophilic?

    Hi I'm currently studying cell biology, and I'm reading about the hydrophobic parts of the plasma membrane of the animal cell. But I'm wondering, what exactly makes a molecule hydrophilic or hydrophobic? What is the chemistry behind it, and how can I tell which molecules are which? I know that...
  36. B

    Chemistry How to Calculate Equivalent Gas Volumes Using Avogadro's Law?

    Homework Statement What volume of CH4 at 0°C and 1.00 atm contains the same number of molecules as 0.58 L of N2 measured at 35.0 °C and 1.50 atm? Homework Equations I think you just need to use Avogadro's Number and multiply by the molar mass? I guess my question is what equation would...
  37. P

    Why Does B(cm^3/mol) Change Sign with Temperature?

    Homework Statement Think about forces between molecules, and explain why we might expect B(cm^3/mol) to be negative at low temperatures but positive at high temperatures. Homework Equations The Attempt at a Solution Well at low temperatures the motion of particles are not as...
  38. S

    Pressure on a wall due to n N2 molecules (close to ans)

    Homework Statement 4.60×1023 nitrogen molecules collide with a 20.0cm^2 wall each second. Assume that the molecules all travel with a speed of 450m/s and strike the wall head on. What is the pressure on the wall in pascals (Pa)? Homework Equations p=(1/3)*(N/V)*(m*v_rms^2) where...
  39. D

    Kinetic Energy of gas Molecules

    Hi, the question, I'm having problems with is this: A 1.0 mol sample of hydrogen gas has a temperature of 30 C. What is the total kinetic energy of all the gas molecules in the sample? How fast would a 75 kg person have to run to have the same kinetic energy? Relevant equations: K = (3/2)kT...
  40. D

    Chemistry Chemistry, how do i draw the lewis structures for these molecules?

    chemistry, how do i draw the lewis structures for these molecules? i have tried all sorts of ways but keep on geting stuck with atoms which i can't connect, don't have enough non paired valence electrons to join em all up H_{5}IO_{6} TeF_{6} IF_{7} SF_{4} BrCL_{3}
  41. fluidistic

    Unformal question about molecules of gases

    In high school I've been told that the molecules of gases have generally speed of severals kilometers per second. Hence why the wind is not always present, and why not that fast? (I guess it has to see with the huge number of particles... I never studied such a system in Physics yet, I...
  42. G

    Gas with interacting molecules (from goldstein)

    Homework Statement (from Goldstein, problem 3.12) Suppose that there are long-range interactions between atoms in a gas in the form of central forces derivable from potential U(r) = \frac{k}{r^m}, where r is the distance between any pair of atoms and m is a positive integer. Assume further...
  43. L

    Ideal Gas- molecules applying pressure

    Homework Statement In a period of 1 s, 5 x 10^23 nitrogen molecules strike a wall with an area of 8 cm^2. Assume the molecules move with a speed of 300 m/s and strike the wall head-on in elastic collisions. What is the pressure exerted on the wall? (The mass of one N2 molecule is 4.68 x...
  44. S

    Chemistry Find the molecules by interpreting the H NMR spectroscopy

    Homework Statement I have a 3 compounds with the same formula: C6H12O2 I need to find the molecules by interpreting the H NMR spectroscopy http://aceorganic.pearsoncmg.com/epoch-plugin/tempfiles/1867_430.jpg http://aceorganic.pearsoncmg.com/epoch-plugin/tempfiles/1869_524.jpg...
  45. K

    Chemistry How Many Atoms in 2.5 Moles of NH3?

    Homework Statement What is the total number of atoms in the molecules? NH3 - 2.5 mole Homework Equations Would you multiply the number of atoms in NH3 by Avogadro constant to find the number of atoms? (4 atoms)(6.02*10^23) =answer Or would you multiply the number of moles by Avogadro...
  46. H

    Mean Time Between Collisions of Ideal Gas Molecules: What Factors Matter?

    If one considers an ideal gas, what does the mean time between collissions of the molecules depend upon? molecular size? number per unit volume? temperature of the gas? I'm thinking so far, it must def depend on number density. It would usually depend on molecular size (but I thought an ideal...
  47. Loren Booda

    Do gas molecules align with gravity?

    In a gas, do the molecular centers of gravity align significantly toward the dominant source of gravity? E. g., do atmospheric water vapor molecules tend to have their oxygen atoms facing Earth's center?
  48. P

    Internal energy does or does not depend on volume of molecules?

    I am kind of confused by the conflict of the following two concepts. If I understood correctly, internal energy of a system is independent of the volume occupied by the gas molecules. This is because the gas molecules are assumed to be ideal and therefore have no intermolecular interactions...
  49. D

    Molecules back to singular atoms.

    Do the atoms in molecules separate quicker if they are moved more vigourously in their lifetime and therefoe cause death of the living organism they makes up sooner? For example: A giant tortoise is slower than a cheatah during its life and lives longer. A tree is slower than a tortoise and...
  50. S

    Predicting absolute configuration of molecules

    I have a question about something that has been bothering me for a while... In all of my chemistry classes, my professors have always told me that it is impossible to predict which way a chiral molecule will rotate plane-polarized light (i.e., you will see if a molecule is D or L, but, saying...
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