A molecule is an electrically neutral group of two or more atoms held together by chemical bonds. Molecules are distinguished from ions by their lack of electrical charge.
In quantum physics, organic chemistry, and biochemistry, the distinction from ions is dropped and molecule is often used when referring to polyatomic ions.
In the kinetic theory of gases, the term molecule is often used for any gaseous particle regardless of its composition. This violates the definition that a molecule contain two or more atoms, since the noble gases are individual atoms.A molecule may be homonuclear, that is, it consists of atoms of one chemical element, as with two atoms in the oxygen molecule (O2); or it may be heteronuclear, a chemical compound composed of more than one element, as with water (two hydrogen atoms and one oxygen atom; H2O).
Atoms and complexes connected by non-covalent interactions, such as hydrogen bonds or ionic bonds, are typically not considered single molecules.Molecules as components of matter are common. They also make up most of the oceans and atmosphere. Most organic substances are molecules. The substances of life are molecules, e.g. proteins, the amino acids they are made of, the nucleic acids (DNA & RNA), sugars, carbohydrates, fats, and vitamins. The nutrient minerals ordinarily are not molecules, e.g. iron sulfate.
However, the majority of familiar solid substances on Earth are not made of molecules. These include all of the minerals that make up the substance of the Earth, soil, dirt, sand, clay, pebbles, rocks, boulders, bedrock, the molten interior, and the core of the Earth. All of these contain many chemical bonds, but are not made of identifiable molecules.
No typical molecule can be defined for salts nor for covalent crystals, although these are often composed of repeating unit cells that extend either in a plane, e.g. graphene; or three-dimensionally e.g. diamond, quartz, sodium chloride. The theme of repeated unit-cellular-structure also holds for most metals which are condensed phases with metallic bonding. Thus solid metals are not made of molecules.
In glasses, which are solids that exist in a vitreous disordered state, the atoms are held together by chemical bonds with no presence of any definable molecule, nor any of the regularity of repeating unit-cellular-structure that characterizes salts, covalent crystals, and metals.
Homework Statement
Calculate the mean spacing between hemoglobin molecules inside a red blood cell?
Homework Equations
Diameter of red blood cell = 5 microns
3*10^8 hemoglobin molecules in each red blood cell
Volume of hemoglobin molecule = 8.71*10^-26 m
The Attempt at a Solution...
Homework Statement
For a biology lab dealing with chemistry, we are supposed to make models (ball and stick) of molecules, and then we need to write the structural and molecular formulas. The models should represent single or double bonds based on the molecular composition. The problem is...
Hello all,
I understand that an increase in pressure yeilds an increase in temperature (in gases). However, I was wondering if extreme pressures can raise the temperature of organic molecules (such as the tissues in a human body) to melting point.
Thanks!
So I'm trying to teach myself MO Theory and Spectroscopy. I was just wondering why symmetry was so important in understanding these and what characters are used to do. I know this is a broad question, but I've been reading a lot (Cotton, etc..) so I know they have to do with integrals and...
Homework Statement
Estimate the average spacing between molecules of 1 mol of an ideal gas at a pressure of 1atm and a temperature of 300K.
Homework Equations
PV=nRT
The Attempt at a Solution
I was able to calculate the volume occupied by the gas (0.0246m^3). Using the ideal...
In the explicitly-unsolvable Hamiltonian for a chemical system, approximations are made to solve the energy of the system. In particular we see CNDO (ZDO), INDO and MNDO theories.
CNDO - complete neglect of differential overlap; two-center electron integrals are zero.
INDO - intermediate...
My lecturer writes the following in his lecture notes:
“Van der Waal’s : Fluctuating dipole of molecules induces dipoles in molecules or other-
wise neutral atoms (eg noble gases)”
Does a fluctuating dipole refer to a dipole that is changing its orientation in space?
How causes a dipole...
How to count molecules and determine density, partial pressure and total pressure?
Homework Statement
Consider three identical boxes each containing a different mixture of O2 and N2. In box #1 are 3 molecules of O2 and 7 molecules of N2. In box #2 are 1 molecule of O2 and 2 molecules of...
Homework Statement
The speed of a group of molecules are 2, 3 , ... 11 km/sec. find the average speed of the group and also find the R.M>S speed of the group ?
Homework Equations
The Attempt at a Solution
by summation of all 2+3+4+... 11 / 11 . is it right ... and how i find RMS...
Hi all,
As sound travels through air, does the air molecules travel with the same speed as well?
In other words, if sound is traveling in air at 340m/s, does it also then mean that the mean speed of all the affected air molecules is 340m/s?
I personally do not think so. I guess that...
I would like to see how far I can get writing some novel & simplified simulator code for molecular modeling based on QM.
------ Background follows ---- skip to next post to get to the details of the project & starter QM question..
My son took chemistry this last semester (High-school...
can anyone tell me how i should approach this problem
calculate the number of molecules of air in a beach ball of volume 6.0*10^-2m^3. The air is at temperature 35degrees, a pressure of 1.1*10^5Pa and can be trested as an ideal gas.
i just want to know what area of classical physics it is
As you know I've been asking questions about alternative fuels and honestly its getting me no where, because I desire a lot more power than what our time has to offer with electricity and other things lol
BUT if there is one thing i know about, it is a flippin car motor and how to make a lot...
If a diatomic molecule's vibrational energy is increased to the dissociation energy of that molecule, will that cause the molecule to rip itself apart? Is it the change in vibrational energy that causes the molecule to dissociate?
I think I did understand this once but now I am confused. If we choose the center-of-mass frame for a diatomic molecule, it also obeys the force law F=-kr, where r=(x,y,z), so why isn't it a 3-d harmonic oscillator, like an atom in solid? I know it may have something to do with the fact that gas...
An excellent laboratory vacuum has a pressure of 4.00x10^-18 atm, or 4.04x10^-13 Pa. How many gas molecules are there per cubic centimeter in such a vacuum at 297 K?
n/v = p/rt
n/v = 4.04x10^-13 / (8.31x297) = 1.66x10^-16 mol/m³
1.66x10^-16 mol/m³ * (1/100cm)³ = 1.66x10^-22 mol/cm³...
Homework Statement
What is the potential energy between the atoms in a body?
Its a huge exercise, so I am not going to type the whole thing, but this is where I got stuck.
Homework Equations
You tell me.
The Attempt at a Solution
I found out what the temperature of the body was...
I know that KE=3/2KbT, but doesn't the KE of gas molecules also equal U=3/2nRT? When do I use which? And also for the second equation if it is for a monoatomic gas, n=1, why isn't the n deleted?
Homework Statement
The mass of the deuterium molecule D2 is twice that of the hydrogen molecule H2. If the vibrational frequency of H2 is 1.22 × 1014 Hz, what is the vibrational frequency of D2, assuming that the “spring constant” of attracting forces is the same for the two species?
Answer...
Question:
If two aspirin tablets, each having a mass of 325mg, are dissolved in a full stomach whose volume is 1L and whose pH is 2, what percent of the aspirin is in the form of neutral molecules? (At body temperature, the Ka for aspirin = 3*10^-5)
My Work:
I know that the molecular...
Homework Statement
From the average separation between air molecules at STP, and their mean speed, estimate how long it would take one molecule to move into the region occupied by another. Assume that air consists mainly of nitrogen molecules.
Homework Equations
v(rms)=sq root(3kT/m)...
How easily do benzene molecules interact with london forces?
I imagine that the relatively large surface area of the aromatic ring coupled with the pi-ring, which is a pretty large orbital makes london forces of a pretty large magnitude possible, but I am not certain.
Does anyone have any...
1. A quantity of molecular hydrogen (H2) gas fills a one liter container at a temperature of 200 K and pressure of 1 atm.
What is the average (rms) speed of the molecules?
Homework Equations
KE_trans = 1/2 M<v^2>
Energy_trans = 3/2kT = 3/2RT
H2 = 2g/mol
The Attempt at a Solution...
Hi,
I need to know what is the product I would get from the reaction between Linolenic Acid 8http://dl.clackamas.edu/ch106-06/images/fatty10.jpg) and Luteolin (http://upload.wikimedia.org/wikipedia/commons/archive/f/f9/20070124191456!Luteolin.png)
I think Linolenic Acid would act as an...
This may seem like a simple question, but I am hoping to find a rather in depth answer. My father and I were discussing a lesson I had learned in Chemistry on Absolute Zero, when we got to the topic of why Molecules move. I answered him, that it was because they receive heat, and...
Dear all,
Any quantum mechanical software (e.g., Gaussian03) can compute the fundamental frequencies (3N-6) and force constant for each frequency..
I don't understand exactly about force constant..??
For a particular mode of vibration what does this force constant mean?
For a molecular with...
Hello guys,
This might be a stupid question but artery has an inner endothelium and muscle outside. So if molecules diffuse out from the endothelium do they diffuse out of the muscle cells as well. How is that done, do muscle cells have the same membrane proteins as endothelium? Thanks :smile:
What do i and j stand for here? My teacher substituted them for masses (in our example, atoms in a molecule) although I'm not sure that makes sense since when you take the Hessian force constant matrix (on the next page of the link) I believe it must have dimensions determined by the number of...
hi
before anything don't blame me much cause I'm chemical Eng & don't know physics much!
I'm about to run a computer simulation which is strongly related to physics so I need your help.
I need to simulate the motion of molecules when I heat them up likely a heavy liquid
perhaps some...
Is it possible for one kind of molecule to be the cause of various odors?
Maybe... this will happen when different parts of the molecule bind to the receptors in my nose?
1. You have a container of 3300 cm^3. Half of it is diatomic oxygen and half is monotonic helium. Pressure is 17 atm and temperature is 25 degrees C. How many molecules of each substance are in it?
2. PV = 2/3 N(1/2 mv^2) -> PV = 2/3 N (K) -> N = 1.5 PV/K
K_monotonic = 3/2kT = 3/2...
1. Homework Statement
"A perfect gas containing a single species of molecular weight M is in a container at equilibrium. Gas escapes into a vacuum through a small circular hole of Area A in the wall of the container. Assume wall container is negligibly thick and planer in vicinity to hole. The...
Homework Statement
"A perfect gas containing a single species of molecular weight M is in a container at equilibrium. Gas escapes into a vacuum through a small circular hole of Area A in the wall of the container. Assume wall container is negligibly thick and planer in vicinity to hole. The...
Homework Statement
"A perfect gas containing a single species of molecular weight M is in a container at equilibrium. Gas escapes into a vacuum through a small circular hole of Area A in the wall of the container. Assume wall container is negligibly thick and planer in vicinity to hole. The...
Homework Statement
What is the number of moleules on human's body?
Homework Equations
The Attempt at a Solution
Is this some kind of theory question and I just have to memorize it or does it involve calculation?
I have tried searching a bit and found out that a person, about...
Homework Statement
A cubic centimeter of water has a mass of 1.00g. How many molecules does it contain?
How many atoms are in 1.00g ice cube?
Homework Equations
1 mole=6.02 x 10^23 molecules(or atoms)
1 mole of H20= 18g
The Attempt at a Solution
The answers are: 3.3 x10^22...
Homework Statement
The rms speed of molecules in a gas at 20.0°C is to be increased by 1.4 percent. To what temperature must it be raised?
k = 1.38E-23 (Boltzmann's Constant)
Ratio in speed: 1.014 : 1
Ratio in Volume: 1.014² = 1.0282 : 1
T1 = 20°C = 293°K
The Volume of 1 mol of an ideal...
Hey everyone, I'm not a math or physics major. I've just read a bit about quantum physics and find it interesting. If i understand it correctly, with the two slit experiment, when you send one particle at a time through without a particle detector by the slit, it results in an interference...
I took physics in high school many-many-many moons ago. Mr. Smith taught that molecules can only exist inside a three dimensional environment. Is that true?
temperature is the measure of average kinetic energy of the molecules of a gas , also temperature is the measure of hotness or coldness of a body , but how does this molecular motion motion produce heating effect that we can feel?!
How many molecules of H2O in 100kg of snow?? don't know where the density comes in!
Homework Statement
How many molecules of H2O are there in 100kg of snow? Density of snow is given as 800 kg/m3
Homework Equations
1 mole = 6.023x10^23 molecules
mass/molecular mass = number of moles...
1. A canister containing 150kg of an ideal gas has a volume of 8 m^3. If the gas exerts a pressure of 5*10^5 Pa, what's the rms speed of the modecules?
I can't get the temperature of the canister...
Homework Statement
Given that the integral [between infinity and 0] v3e-av2dv = 1/2a2
calculate the average speed vav of molecules in the gas using the maxwell-boltzmann distribution function
Homework Equations
The Attempt at a Solution
i don't really know what to do some...
I think the reason for molecules with 100 or so electrons to annihilate faster with a positron is because the electrons are quantum mechanicly smeared across a larger area.
1. At 100C the rms speed of nitrogen molecules is 576 m/s. Nitrogen at 100C and a pressure of 2.0 atm is held in a container with a 10cm x 10cm square wall.
2. N_coll / deltaT = 0.5(N/V)*A*v_x
3. I know that I have to use v_rms/3 = v_x = 192 m/s, and the area will be 0.01 m^2. Is...
Homework Statement
determine the electron dot structure of molecules a and b
http://session.masteringchemistry.com/problemAsset/1144353/2/MMAt.05.067.jpgHomework Equations
The Attempt at a Solution
A)
::O: H
| |
H-C=N-HB)
H
| ..
H-C-N=C=O::
|
H
I am not at all sure...