Quantum mechanics Definition and 994 Threads

Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistry, quantum field theory, quantum technology, and quantum information science.
Classical physics, the description of physics that existed before the theory of relativity and quantum mechanics, describes many aspects of nature at an ordinary (macroscopic) scale, while quantum mechanics explains the aspects of nature at small (atomic and subatomic) scales, for which classical mechanics is insufficient. Most theories in classical physics can be derived from quantum mechanics as an approximation valid at large (macroscopic) scale.Quantum mechanics differs from classical physics in that energy, momentum, angular momentum, and other quantities of a bound system are restricted to discrete values (quantization), objects have characteristics of both particles and waves (wave-particle duality), and there are limits to how accurately the value of a physical quantity can be predicted prior to its measurement, given a complete set of initial conditions (the uncertainty principle).
Quantum mechanics arose gradually from theories to explain observations which could not be reconciled with classical physics, such as Max Planck's solution in 1900 to the black-body radiation problem, and the correspondence between energy and frequency in Albert Einstein's 1905 paper which explained the photoelectric effect. These early attempts to understand microscopic phenomena, now known as the "old quantum theory", led to the full development of quantum mechanics in the mid-1920s by Niels Bohr, Erwin Schrödinger, Werner Heisenberg, Max Born and others. The modern theory is formulated in various specially developed mathematical formalisms. In one of them, a mathematical entity called the wave function provides information, in the form of probability amplitudes, about what measurements of a particle's energy, momentum, and other physical properties may yield.

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  1. F

    I How to define expectation value in relativistic quantum mechanics?

    In non relativistic quantum mechanics, the expectation value of an operator ##\hat{O}## in state ##\psi## is defined as $$<\psi |\hat{O}|\psi>=\int\psi^* \hat{O} \psi dx$$. Since the scalar product in relativistic quantum has been altered into $$|\psi|^2=i\int\left(\psi^*\frac{\partial...
  2. Dario56

    I Kinetic Energy and Potential Energy of Electrons

    Time indepedendent Schrödinger equation for a system (atom or molecule) consisting of N electrons can be written as (with applying Born - Oppenheimer approximation): $$ [(\sum_{i=1}^N - \frac {h^2} {2m} \nabla _i ^2) + \sum_{i=1}^N V(r_i) + \sum_{i < j}^N U(r_i,r_j)] \Psi = E \Psi $$ Terms in...
  3. entropy1

    I Quantum Mechanics without time?

    Is there a view in quantummechanics, of quantummechanics, without time as a concept?
  4. M

    I Informational Interpretation of quantum mechanics?

    I heard something today about the "informational interpretation" of quantum mechanics and a phrase used was "it from bit." Is there actually such a thing? What does it mean, and how is it distinguished from other interpretations like MWI or Copenhagen?
  5. Mr_Allod

    Probability of finding a pion in a small volume of pionic hydrogen

    Hello, I am trying to figure out the right way to approach this. First of all, other than the different Bohr radius value, does the change to a negative pion make any other difference to calculating the probability? Also what would be the correct way to apply the "small volume"? What I'm...
  6. K

    I Definition of magnetic moment in quantum mechanics

    * The general formula for the magnetic moment of a charge configuration is defined as ##\vec{\mu} = \frac{1}{2} \int \vec{r} \times \vec{J} \,d^3r##* For an electron it's said that the correct equation relating it's spin and magnetic moment is is ##\vec{\mu} =g\frac{q}{2m}\vec{S}## * It's...
  7. Ravi Mohan

    What Are the Dimensions of Hilbert Space Elements in Quantum Mechanics?

    Hi Fellas! My first post after a long hiatus from forums. Feeling nostalgia (this is the place where it all began, my fuel for quantum fascination so to speak). I am revisiting the mathematical formulation of quantum mechanics with the dimensional (MLT) perspective. I want to understand what...
  8. M

    Help on Learning Quantum Mechanics (Undergraduate)

    Summary:: I am in the highest level Quantum class at my university- technically considered a grad class. I am an undergrad and need advice on just how to learn it. What study tips? Good Youtubers? Physical simulations? Anything that helped you in quantum mechanics. Hello! I am an undergrad...
  9. Vectronix

    Quantum Modern Quantum Mechanics 3rd Ed: J. J. Sakurai & Jim Napolitano Review

    Is Modern Quantum Mechanics, 3rd Edition, by J. J. Sakurai and Jim Napolitano a good book to learn quantum mechanics from?
  10. Spathi

    I A thought experiment concerning determinism in quantum mechanics

    According to the uncertainty principle, when we measure a micro-object with a measuring device, we cannot predict what value the device will show. But if we knew exactly the wave function of this device, together with the wave function of the micro-object, could we exactly predict the result of...
  11. S

    Quantum Introductory quantum mechanics textbook for self-study

    Hi! I want to self study some of quantum mechanics so i need introductory textbook. I've taken courses on linear algebra that covers all "Linear algebra done right" by Sheldon Axler, multivariable calculus, two courses on general physics and the basics of differentials equations. I really like...
  12. K

    Quantum Finding the Perfect Self-Study Book for Intro Stats & Quantum Mechanics

    Can you please suggest a good introductory statistical and quantum mechanics book which can be self studied. My math background : I've done multivariate calculus, vector calculus, linear algebra ,some complex analysis all at the usual undergraduate level. The books I've self studied thus far...
  13. tworitdash

    A Applications of weak measurement of quantum mechanics in other domains

    This is a surface level question and I don't want to go into detail. Imagine an algorithm which when used with a sensor output gives the statistical moments of a variable in nature (for example mean and standard deviation of a variable). The sensor measures this once in a while (like once in a...
  14. Hamiltonian

    Quantum Buying my first Quantum mechanics book

    I recently started studying some quantum mechanics, so far I have been using online resources(like MIT OCW 8.04/8.05, and Tongs notes I think I have reached a stage where I understand the Schrodinger eqn and can solve it for various potentials(including for the H-atom) but I don't know anything...
  15. kbansal

    How to explain the Quantum Mechanics/Math of the stages of MRI imaging

    "B0 is a static magnetic field (produced by a superconducting magnet) that initially causes the protons in the body to align with the field and precess at the larmor frequency along the z axis . From a mathematical perspective this precession around the B0 axis occurs due to the time evolution...
  16. J

    A Quantum Field theory vs. many-body Quantum Mechanics

    A lot of people say that Quantum Field theory (QFT) an Quantum Mechanics (QM) are equivalent. Yet, I've found others who dispute these claims. Among the counter-arguments (which I admittedly do not have the expertise to pick apart and check their validity in full) are the following: 1) While QFT...
  17. A. Neumaier

    I Quantum mechanics via quantum tomography

    I just finished a new paper, A. Neumaier, Quantum mechanics via quantum tomography, arXiv:2110.05294. (later renamed to) A. Neumaier, Quantum tomography explains quantum mechanics, arXiv:2110.05294. Abstract: Starting from first principles inspired by quantum tomography rather than Born's...
  18. D

    I Physical interpretation of phase in solutions to Schrodinger's Eqn?

    Hello all, So I've been working through the solutions to some simple introductory problems for the Schrodinger Equation like the infinite square well, and I'm trying to make sense of how to think about the phase component. For simplicity's sake, let's start off by assuming we've measured an...
  19. Morbert

    A Retrodictive Inferences in Quantum Mechanics

    Take a simple case: A system is prepared in state ##\rho_i## at time ##t_0##, and a projective measurement is performed at time ##t_2## with an outcome ##b##. We can retrodict a projective measurement outcome ##a## at time ##t_1## where ##t_0<t_1<t_2##$$p(a|b) =...
  20. dextercioby

    A Can Quantum Mechanics be postulated to exclude humans?

    An axiomatization of classical mechanics such as the one by McKinsey et al. (1) does not contain any reference to humans or experiments, and does not contain the magic (irony!) words of quantum mechanics, i.e. observables and measurements. (1) McKINSEY, J. C. C., et al. “Axiomatic Foundations...
  21. ubergewehr273

    Finding unitary operator associated with a given Hamiltonian

    Now from the relevant equations, $$U(t) = \exp(-i \omega \sigma_1 t)$$ which is easy to compute provided the Hamiltonian is diagonalized. Writing ##\sigma_1## in its eigenbasis, we get $$\sigma_1 = \begin{pmatrix} 1 & 0\\ 0 & -1\\ \end{pmatrix} $$ and hence the unitary ##U(t)## becomes...
  22. J

    Problem using Griffiths Intro to Quantum Mechanics

    Summary:: The problem solutions contain a lot of unjustified steps, making them pointless. I am trying to use Griffiths Introduction to Quantum Mechanics. He states that the wave function ##\psi## approaches 0 as x approaches infinity to make normalization work. I can accept that. But then I...
  23. ZIKA99

    B Exploring Electron Motion in Quantum Mechanics

    I had two questions in the field of physics: We know that in quantum mechanics there is an electron in a certain distance from the distance to the nucleus as a cloud or a cover. But is motion for the cloud defined by the electron moving around the nucleus? And the main question is, can the...
  24. Wannabe Physicist

    Find the eigenfunction and eigenvalues of ##\sin\frac{d}{d\phi}##

    Here is what I tried. Suppose ##f(\phi)## and ##\lambda## is the eigenfunction and eigenvalue of the given operator. That is, $$\sin\frac{d f}{d\phi} = \lambda f$$ Differentiating once, $$f'' \cos f' = \lambda f' = f'' \sqrt{1-\sin^2f'}$$ $$f''\sqrt{1-\lambda^2 f^2} = \lambda f'$$ I have no...
  25. D

    A Fidelity for quantum state at t=0

    fidelity for pure state with respect to t=0 is 1. My teacher told me this. But I am not getting this. This is my detailed question the initial state(t=0)##|\psi\rangle=|\alpha\rangle|0\rangle## the final state (t) ##|\chi\rangle= |i\alpha\sin(t)\rangle|cos(t)\alpha\rangle## Fidelity between the...
  26. M

    I Blackbody radiation in quantum mechanics

    Hello! If I place a particle with more energy levels (of the order of kT) in a well defined state, in a thermal bath at temperature T, how will the blackbody radiation affect the internal state of the particle i.e. will the distribution be classical or QM? Basically, if I prepare that particle...
  27. Viona

    Spin-Orbit Coupling in Hydrogen Atom: Understanding the Calculation

    I was reading in the Book: Introduction to Quantum Mechanics by David J. Griffiths. In chapter Time-independent Perturbation Theory, Section: Spin -Orbit Coupling. I understood that the spin–orbit coupling in Hydrogen atom arises from the interaction between the electron’s spin magnetic moment...
  28. D

    I Discussion about quantum mechanics and spacetime

    Robert Lawrence Kuhn: It seems that special relativity suggests time is like gravity and electromagnetism, not built into the absolute fabric of reality like logic and causation. David J Gross: Yes, time is dynamical. The phenomena are dynamical and are labeled by what we call time. Including...
  29. DougFisica

    I Observables on the "3 polarizers experiment"

    Observables on the "3 polarizers experiment" Hi guys, I was analyzing the 3 polarizers experiment. This one: (first 2 minutes -> ) Doing the math (https://faculty.csbsju.edu/frioux/polarize/POLAR-sup.pdf) I realized that the process is similar to the Stern-Gerlach' experiment. Using spins...
  30. S

    Nobel prize in physics for quantum cryptography?

    Is it likely that this year's Nobel prize could be awarded to the field of quantum cryptography with Charles H Bennet, Gilles Brassard and Artur Ekert as possible nobel laureate candidates?
  31. steve1763

    A Derivation of recovery channel for bit flip error

    In general, if R is the recovery channel of an error channel ε, with state ρ, then and according to these lecture slides, we get the final result highlighted in red for a bit flip error channel. I am simply asking how one reaches this final result. Thank you (a full-ish derivation can be found...
  32. Vatsy31

    Admissions Can someone critique my statement of purpose? (Master's Degree in Quantum Engineering)

    I have written and rewritten a lot of times but I need some fresh eyes on my sop. It would be great if someone can help me out. I have less than a week to readjust it and send. My motivation to apply for the Masters Degree in quantum engineering at University of Wurzburg is to...
  33. Pipsqueakalchemist

    I Is quantum mechanics imply nature is deterministic or probabilistic?

    So initially I thought quantum mechanics was deterministic in the equations but was probabilistic in measurement. I’m aware of bell’s inequality which rules out hidden variables unless you assume super determinism. But recently I’ve come across something called decoherence and some people have...
  34. Viona

    B The average value of S operator

    While reading in the book of Introduction to Quantum Mechanics by David Griffith in the section of Fine structure of Hydrogen: spin- orbit coupling, he said that the average value of S operator is considered to be the projection of S onto J. I could not understand why he assumed that. please...
  35. U

    Studying Modern physics after quantum mechanics

    Hello everyone. I am studying physics as a self-study and would like advice on the next topics to study. So far I have been studying: -calculus, linear algebra and basic physics -classical mechanics (from Goldstein's textbook) -classical electrodynamics and special relativity (from Griffiths...
  36. yucheng

    Griffiths Quantum Mechanics Problem 1.18: Characteristic Size of System

    intermolecular distance means distance between particles. So, I imagine a sphere. $$\frac{4}{3} \pi d^3 = \frac{V}{N}$$ However, Griffitfhs pictures a box instead, where $$d^3 = \frac{V}{N}$$ And the difference between both models is a factor of ##(4\pi/3)^{2/5} \approx 1.8##, which is...
  37. J

    A Do we really need the Hilbert space for Quantum Mechanics?

    Let's play this game, let's assume the infinite Hilbert Space, the operators and all the modern machinery introduced by Von Neuman were not allowed. How would be the formalism? Thanks
  38. heslaheim

    I Some questions in "Introduction to quantum mechanics"

    A certain field has a singularity at the origin, and the divergence of its curl is zero at any point outside the origin, but surface integral of the curl is not zero in the area of any closed surface containing the origin. So how should the Stokes theorem related to this field be expressed at...
  39. M

    B Description of isolated macroscopic systems in quantum mechanics

    If we prepare a macroscopic system (something like Shrodinger's cat) in a known quantum-mechanical state and we let it evolve for a very long time completely isolated, for what I understand the position of all it's particles will become more and more spread in space. But if the evolution of the...
  40. B

    Help with Space Inversion Symmetry Problem

    {a} P = identity Matrix w/ -1 on diagonals {b} eigenvalues = +/- 1
  41. A

    Solving QM Problem: Fermi's Golden Rule & Transitional Probability

    Hello all, I would like some guidance on how to approach/solve the following QM problem. My thinking is that Fermi's Golden Rule would be used to find the transitional probability. I write down that the time-dependent wavefunction for the free particle is...
  42. J

    I Simulation of non-Hermitian quantum mechanics

    I noticed the research on NHQM in the following news release. New physics rules tested on quantum computer Published: 19.2.2021 Information for relevant paper is provided as follows. Quantum simulation of parity–time symmetry breaking with a superconducting quantum processor Shruti Dogra...
  43. tanaygupta2000

    How Do You Operate the Hamiltonian on a Coherent State?

    I am getting that we have to operate the given Hamiltonian on the given state |α>. But what is confusing me is that since this H contains position and momentum operators which just involve variable x and partial derivative, how do I operate this H on the given α, since it seems like α is...
  44. tanaygupta2000

    How Can Cylindrical Coordinates Simplify Complex Number Integration?

    I began this solution by assuming a = x+iy since a is a complex number. So I wrote expressions of <a| and |a> in which |n><n| = I. I got the following integral: Σ 1/πn! ∫∫ dx dy exp[-(x^2 + y^2)] (x^2 + y^2)^n I I tried solving it using Integration by Parts but got stuck in the (x^2 + y^2)^n...
  45. A

    A The exciton dynamics in the FMO complex

    I want to study the coherence transfer of the excitation in the FMO complex, so I have to solve the Lindblad master equation. Can I treat my system as a two level system?
  46. Sophrosyne

    A philosophy of quantum mechanics question

    There is an interpretation of quantum mechanics out there, and I was not sure if physicists take this seriously, or if it's one of those woo-woo popular misunderstandings of quantum mechanics. So I am posing it to our esteemed physicists here. It says that there can be all sorts of universes...
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