Relativistic quantum chemistry combines relativistic mechanics with quantum chemistry to calculate elemental properties and structure, especially for the heavier elements of the periodic table. A prominent example is the explanation of the color of gold: due to relativistic effects, it is not silvery like most other metals.The term relativistic effects was developed in light of the history of quantum mechanics. Initially quantum mechanics was developed without considering the theory of relativity. Relativistic effects are those discrepancies between values calculated by models that consider relativity and those that do not. Relativistic effects are important for the heavier elements with high atomic numbers. In the most common layout of the periodic table, these elements are shown in the lower area. Examples are the lanthanides and actinides.Relativistic effects in chemistry can be considered to be perturbations, or small corrections, to the non-relativistic theory of chemistry, which is developed from the solutions of the Schrödinger equation. These corrections affect the electrons differently depending on the electron speed compared to the speed of light. Relativistic effects are more prominent in heavy elements because only in these elements do electrons attain sufficient speeds for the elements to have properties that differ from what non-relativistic chemistry predicts.
Homework Statement
A particle with mass M at rest decays into two particles, one with mass m1, and the other with mass m2. Use conservation of energy and momentum to show that:
E1 = (M^2 + m1^2 - m2^2)(c^2)
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2M
Homework Equations...
do you know any text or reference with extensive treatment on electromagnetic field ,potential & electromagnetic energy of point particle moving straight at relativistic velocities?
Hey guys, I am attending my second course in quantum mechanics. At the moment we are studying two-particle-systems using Dirac notation. In our book (An introduction to quantum mechanics - Griffiths) the author wrote that one can prove from relativisitic quantum mechanics that particles with...
Hello. I am trying to better understand relativistic inelastic collisions for objects with mass and the setup for them.
Let's say that I have two objects with different masses, one of which collides with the other, which is stationary.
Without even specifying a reference frame, can I solve...
Hi all!
I'm doing a statistical mechanics class this semester where very often questions like "consider the limit of temperature going to..." pop up.
Now, if you consider a relativistic system (say some gas), to what extent does it make sense to talk about temperature going to 0? [to me...
Does anyone know of a derivation of the energy-momentum relation that does not make use of relativistic mass? In other words, a derivation that only uses invariant mass.
I'm having some problems trying to figure out how to derive relativistic momentum. The way it was explained to me, classically, p=mv=m(dx/dt),but dx/dt is measured differently in different reference frames. So, if you look at time dilation, t=ɣt' where ɣ= 1/(1-(v/c)^2)^1/2 and t' is time in the...
Homework Statement
A and B are trains on perpendicular tracks, radiating from the origin of a coordinate system S. Train A is moving along the positive Y axis at a velocity of 0.8c, and train B is moving along the positive X axis also at a velocity of 0.8c. All velocites are measures with...
I just recently heard about how this small but still existent flat-Earth society believe that gravity on our supposedly flat Earth is caused by the Earth always moving upward at a constant velocity.
Now obviously assuming the Earth is flat and that gravity isn't caused by mass attraction, then...
Homework Statement
i was looking through an undergrad's original research and i wanted to get how he derived w\some formula, the paper is "Relativistic dynamics without conservation laws,B. Rothenstein1, Ş. Popescu2"
since its open access here is the page with the paper...
Hi, I have an assignment due in the morning, and it is complete, there is just one tiny thing I am unsure of: In a rest frame, a mass m moves west at speed v, and another mass also m moves east at speed v. Now consider the setup as viewed by an observer going west at speed u.
I had to find the...
Homework Statement
Show that equation 14.13 reduces to equation 13.14 in the nonrelativistic limit.
Homework Equations
(14.13) K_{th} = -Q \frac{m_1 + m_2 + m_3 + ...}{2m_2}
(13.14) K_{th} = -Q ( 1 + \frac{m(x)}{M(X)} )
The Attempt at a Solution
For equation 13.14 m(x) is the...
In figure 3-1 (page 63) of Taylor and Wheeler's Spacetime Physics, the observer on the train determines that the lightning strikes are not simultaneous because the flashes do not reach her simultaneously.
I see two problems with this.
1. The narrative in figure 3-1 contradicts the text in...
Homework Statement
\frac{dp}{dt} = \frac{d}{dt}\frac{mv}{\sqrt{1-\frac{v^2}{c^2}}} = F
Find v(t) show that v -> c as t -> infinity & find the distance traveled in time t if the object starts from rest.
Homework Equations
The Attempt at a Solution
Ive tried rearranging it into either a...
Hi,
I can't say I've really ever done much relativity but this made me wonder. Imagine we have some frame where a muon and an electron are interacting where the electron's energy is so high that its relativistic mass can be said to be HIGHER than that of the muon in the same frame. I...
The phase of a pure momentum state for a single particle traveling freely is
(p.r – Et) / h-bar.
This also happens to be the Minkowski space-time dot product of the 4-momentum and the space-time 4-vector (relativistic action).
Is that just a coincidence or is phase inherently...
Homework Statement
I need help rearranging the relativistic momentum equation in terms of velocity.
Homework Equations
p = (mv)/sqrt(1-((v^2)/(c^2)))
The Attempt at a Solution
p = (mv)/sqrt(1-((v^2)/(c^2)))
p(sqrt(1-((v^2)/(c^2)))) = mv
sqrt(1-((v^2)/(c^2))) = mv/p...
Homework Statement
The sigma Baryon Σ0 is at rest and decays to form an Λ0 and a ɣ photon.
Homework Equations
Mass of Σ0 is 1193 MeV/c^2
Mass of Λ0 is 1116 MeV/C^2
The Attempt at a Solution
K obviously since the Σ0 is at rest, momentum must be conserved and the Λ0 and ɣ go...
Homework Statement
How fast must a body be traveling if its forrect relativistic momentum is 1% greater than the classical momentum
Homework Equations
P_r = mv/sqrt(1-(v^2/c^2))
P_nr = mv
p_r = 1.01P_nr
The Attempt at a Solution
mv/sqrt(1-(v^2/c^2)) = 1.01mv
mv =...
Hey, I'm pretty confused by this relativistic collision problem.
A particle of mass m moving along the x-axis collides elastically with a 2nd particle of identical mass at rest in the lab frame and scatters. Its final momentum makes an angle theta with the x-axis in the lab. If its initial...
Student here, please forgive...
I have a question about relativistic mass in galaxies. Is the mass of far away galaxies affected by expansion of universe? That is: Is mass of a far away galaxy is different for observer there compared to the observer here? Let's say there is a galaxy identical...
I happened to stumble across these books which seem to give decent backgrounds on the subject.
Nuclear Reactions for Astrophysics: Principles, Calculation and Applications of Low-Energy Reactions by Ian J. Thompson and Filomena M. Nunes...
Homework Statement
We have the decay process:
pion --> muon + anti muon neutrion
How long does the muon travel before it decays? (the pion is stationary before the decay)
The answer is supposed to be
d = c * t (m(pi)^2 + m(mu)^2) / (2 m(pi) * m(mu) )
where t is the mean lifetime of the...
I'm having trouble getting all of the relativistic dynamics information straight in my head. In particular, I'm having trouble with reference frames. It seems that when I am trying to solve problems, even simple ones, I am struggling with what each observer in the different frames should be...
I have been doing research lately. And I wanted to know if anyone could tell me what exactly in relativistic mechanics makes us not able to achieve the speed of light?
Homework Statement
A gamma ray photon with wavelength=2.0 * 10^-15m is traveling in the positive x direction undergoes a one dimensional collision with a stationary proton.
a.) find the relativistic momentum and energy of the photon and proton before the collision.
b.) assuming the...
I'm in a math class reading Einstein's original paper "On the Electrodynamics of Moving Bodies," from 1905.
I'm stuck in Section 8, "transformation of the energy of light rays." We're basically trying to show that that Placnk's constant is Lorentz invariant- if anyone has an easy way of...
Homework Statement
A source and detector are placed a certain angle \phi apart on the edge of a rotating disk. The source emits radiation in all directions at a frequency \omega_* in its instantaneous rest frame. What frequency is the radiation detected at? (Hint: Little information is...
If we have case \rho=0, \vec{j}=\vec{0}
then we have this equations
\Delta\vec{E}-\frac{1}{c^2}\frac{\partial^2 \vec{E}}{\partial t^2}
\Delta\vec{B}-\frac{1}{c^2}\frac{\partial^2 \vec{B}}{\partial t^2}
Particular solutions of this equation
\vec{E}=\vec{E}_0...
Homework Statement
Assume a particle moves along the x-axis. It is uniformly accelerated, in the sense that the acceleration measured in its instantaneous rest frame is always g, a constant. Find x and t as functions of the proper time tau if the particle is at x0 at t=0 with no velocity.
The...
Homework Statement
In a fission process, a slow neutron causes a uranium nucleus (m=218943.42 MeV/c^2) to split into a barium nucleus (m=131261.73) and a krypton nucleus (m=85619.32), plus two excess neutrons (actually 3 including the original neutron, but that is present before the process as...
Does photons actually slow down near a black hole?
Whenever I look up these info, I always read the mention of red shifting.
The problem is we don't have a detector that is immune from the effects of relativity to directly observe these events in real time.
However, does current...
Homework Statement
Let us consider a perfectly inelastic collision between two protons: an incident proton with mass m, kinetic energy K, and momentum magnitude p joins with an originally stationary target proton to form a single product particle of mass M. Due to conservation of momentum...
Homework Statement
Show that the addition of velocities implies the following:
- If | \vec V | < c in one inertial frame, then | \vec V | < c in any inertial frame
- If | \vec V | > c in one inertial frame, then | \vec V | > c in any inertial frameHomework Equations
V^{x'}=\frac{V^x...
I was solving this problem, and I was comparing my answers with a classmate, and we got very different answers. I don't think I made a mistake here, but I may have missed something.
Homework Statement
Tipler - Modern Physics 5e 1-57.
"Two observers agree to test time dilation. They use...
So, there is a sentence in my book, along with a graph, stating that "relativistic kinetic energy becomes infinite as v approaches c."
But then in a concept problem, it says "A proton is accelerated from rest by a constant force that always points in the direction of the particle's motion...
If a bike is running at v=0.866c, and it travels path of length L in time T, when observed from the stationary frame, same path will have length L/2 and be traveled in time T/2 in his, moving frame (because gamma=2 for v=0.866c).
Now, what I don't understand is:
If the bike is not...
Homework Statement
For a relativistic ideal gas, the momentum probability distribution is given by
where http://latex.codecogs.com/gif.latex?\epsilon_p=\sqrt[]{m^2c^4+c^2p^2}. Determine A
Homework Equations
The Attempt at a Solution
I know that...
For example, a top spinning near the speed of light, would the relativistic mass be affected by gravity and therefore increase the weight of the object?
If it does, then are the highest speeds which we could realistically get it to spin at it not even close to the speed of light, making any...
Homework Statement
Find the speed of a particle whose relativistic kinetic energy is 40% greater than the Newtonian value for the same speed.
Krel = relativistic kinetic energy
Knew = Newtonian kinetic energy
Homework Equations
Krel = (gamma - 1)mc^2
Knew = 0.5mv^2
gamma =...
I've been trying to graph an idea I had, but frankly I don't understand SR well enough to ensure my assumptions are correct, and that I'm using the correct formulas. I would appreciate any input/corrections you folks could give. Here's the idea, which I'll follow with my assumptions:
Idea...
For reference: http://arxiv.org/abs/astro-ph/9912312"
The paper linked above notes in the introduction:
The authors are performing this calculation for an isotropic electron distribution. However, for my work, I am considering an electron population with a relativistic macroscopic bulk...
Homework Statement
What is the most general mathematical form for the relativistic momentum which will prevent the velocity of an object from becoming greater than c, when the object is acted on by a constant force F and the equation of motion is dp/dt=F
Homework Equations
The...
While observing the Sun, which is 8 light-minutes 12 light-seconds away from us. We (by visible and invisible spectrum of the electromagnetic radiation) observe its state 8.20 minutes ago. Special relativity forbids any information to travel at speeds greater than that of light. This should...
Homework Statement
A car is getting closer to a radar as a speed of 135 km/h. If the radar works at a 2 \times 10 ^{9} Hz, what difference of frequency is observed for the radar?Homework Equations
\mu=\frac{\mu _0 \sqrt {1- \frac{v^2}{c^2}}}{1-\frac{v}{c}}The Attempt at a Solution
I converted...
Homework Statement
How does change acceleration of relativistic linear harmonic oscillator with distance of equilibrium point in laboratory reference system?
Homework Equations
The Attempt at a Solution
x=x_0sin(\omega t+\varphi)
\upsilon=\omega x_0cos(\omega...