Thermodaynamics Definition and 154 Threads

  1. Chemical Engineering Thermodynamics by Prof. M.S. Ananth (NPTEL):- Lecture 19: Vapour Liquid  Equilibria II

    Chemical Engineering Thermodynamics by Prof. M.S. Ananth (NPTEL):- Lecture 19: Vapour Liquid Equilibria II

    Copyright strictly reserved to Prof Prof. M.S. Ananth and NPTEL, Govt of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/103106070/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=103106070
  2. Chemical Engineering Thermodynamics by Prof. M.S. Ananth (NPTEL):- Lecture 20: Solvent-Solvent mixtures

    Chemical Engineering Thermodynamics by Prof. M.S. Ananth (NPTEL):- Lecture 20: Solvent-Solvent mixtures

    Copyright strictly reserved to Prof Prof. M.S. Ananth and NPTEL, Govt of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/103106070/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=103106070
  3. Chemical Engineering Thermodynamics by Prof. M.S. Ananth (NPTEL):- Lecture 21: Solvent-solute mixtures

    Chemical Engineering Thermodynamics by Prof. M.S. Ananth (NPTEL):- Lecture 21: Solvent-solute mixtures

    Copyright strictly reserved to Prof Prof. M.S. Ananth and NPTEL, Govt of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/103106070/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=103106070
  4. Chemical Engineering Thermodynamics by Prof. M.S. Ananth (NPTEL):- Lecture 22: Liquid-liquid equilibria

    Chemical Engineering Thermodynamics by Prof. M.S. Ananth (NPTEL):- Lecture 22: Liquid-liquid equilibria

    Copyright strictly reserved to Prof Prof. M.S. Ananth and NPTEL, Govt of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/103106070/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=103106070
  5. Chemical Engineering Thermodynamics by Prof. M.S. Ananth (NPTEL):- Lecture 23: An industrial example

    Chemical Engineering Thermodynamics by Prof. M.S. Ananth (NPTEL):- Lecture 23: An industrial example

    Copyright strictly reserved to Prof Prof. M.S. Ananth and NPTEL, Govt of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/103106070/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=103106070
  6. Chemical Engineering Thermodynamics by Prof. M.S. Ananth (NPTEL):- Lecture 24: Liquid-liquid equilibria/ Reaction Equilibria

    Chemical Engineering Thermodynamics by Prof. M.S. Ananth (NPTEL):- Lecture 24: Liquid-liquid equilibria/ Reaction Equilibria

    Copyright strictly reserved to Prof Prof. M.S. Ananth and NPTEL, Govt of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/103106070/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=103106070
  7. Chemical Engineering Thermodynamics by Prof. M.S. Ananth (NPTEL):- Lecture 25: Reaction Equilibria

    Chemical Engineering Thermodynamics by Prof. M.S. Ananth (NPTEL):- Lecture 25: Reaction Equilibria

    Copyright strictly reserved to Prof Prof. M.S. Ananth and NPTEL, Govt of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/103106070/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=103106070
  8. Chemical Engineering Thermodynamics by Prof. M.S. Ananth (NPTEL):- Lecture 26: Illustrative Examples I

    Chemical Engineering Thermodynamics by Prof. M.S. Ananth (NPTEL):- Lecture 26: Illustrative Examples I

    Copyright strictly reserved to Prof Prof. M.S. Ananth and NPTEL, Govt of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/103106070/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=103106070
  9. Chemical Engineering Thermodynamics by Prof. M.S. Ananth (NPTEL):- Lecture 27: Illustrative Examples II

    Chemical Engineering Thermodynamics by Prof. M.S. Ananth (NPTEL):- Lecture 27: Illustrative Examples II

    Copyright strictly reserved to Prof Prof. M.S. Ananth and NPTEL, Govt of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/103106070/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=103106070
  10. Chemical Engineering Thermodynamics by Prof. M.S. Ananth (NPTEL):- Lecture 28: Illustrative Examples III

    Chemical Engineering Thermodynamics by Prof. M.S. Ananth (NPTEL):- Lecture 28: Illustrative Examples III

    Copyright strictly reserved to Prof Prof. M.S. Ananth and NPTEL, Govt of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/103106070/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=103106070
  11. Chemical Engineering Thermodynamics by Prof. M.S. Ananth (NPTEL):- Lecture 29: Simultaneous Relations

    Chemical Engineering Thermodynamics by Prof. M.S. Ananth (NPTEL):- Lecture 29: Simultaneous Relations

    Copyright strictly reserved to Prof Prof. M.S. Ananth and NPTEL, Govt of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/103106070/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=103106070
  12. Chemical Engineering Thermodynamics by Prof. M.S. Ananth (NPTEL):- Lecture 30: Thermodynamic Consistency/ Reverse Osmosis

    Chemical Engineering Thermodynamics by Prof. M.S. Ananth (NPTEL):- Lecture 30: Thermodynamic Consistency/ Reverse Osmosis

    Copyright strictly reserved to Prof Prof. M.S. Ananth and NPTEL, Govt of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/103106070/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=103106070
  13. Chemical Engineering Thermodynamics by Prof. M.S. Ananth (NPTEL):- Lecture 31: Miscellaneous topics in phase equilibria

    Chemical Engineering Thermodynamics by Prof. M.S. Ananth (NPTEL):- Lecture 31: Miscellaneous topics in phase equilibria

    Copyright strictly reserved to Prof Prof. M.S. Ananth and NPTEL, Govt of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/103106070/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=103106070
  14. Chemical Engineering Thermodynamics by Prof. M.S. Ananth (NPTEL):- Lecture 32: Absorption Refrigeration

    Chemical Engineering Thermodynamics by Prof. M.S. Ananth (NPTEL):- Lecture 32: Absorption Refrigeration

    Copyright strictly reserved to Prof Prof. M.S. Ananth and NPTEL, Govt of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/103106070/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=103106070
  15. Chemical Engineering Thermodynamics by Prof. M.S. Ananth (NPTEL):- Lecture 33: Summary of  Classical Thermodynamics

    Chemical Engineering Thermodynamics by Prof. M.S. Ananth (NPTEL):- Lecture 33: Summary of Classical Thermodynamics

    Copyright strictly reserved to Prof Prof. M.S. Ananth and NPTEL, Govt of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/103106070/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=103106070
  16. Chemical Engineering Thermodynamics by Prof. M.S. Ananth (NPTEL):- Lecture 34: Molecular basis of Thermodynamics I

    Chemical Engineering Thermodynamics by Prof. M.S. Ananth (NPTEL):- Lecture 34: Molecular basis of Thermodynamics I

    Copyright strictly reserved to Prof Prof. M.S. Ananth and NPTEL, Govt of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/103106070/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=103106070
  17. Chemical Engineering Thermodynamics by Prof. M.S. Ananth (NPTEL):- Lecture 35: Molecular basis of Thermodynamics II

    Chemical Engineering Thermodynamics by Prof. M.S. Ananth (NPTEL):- Lecture 35: Molecular basis of Thermodynamics II

    Copyright strictly reserved to Prof Prof. M.S. Ananth and NPTEL, Govt of India. Duplication prohibited. Lectures: http://www.nptel.ac.in/courses/103106070/ Syllabus: http://www.nptel.ac.in/syllabus/syllabus.php?subjectId=103106070
  18. Krushnaraj Pandya

    Change in temperature when a gas is in a moving container

    Homework Statement Some gas at 300K is enclosed in a container. Now the container is placed on a fast moving train.is the change in temperature of the gas the same as the change dT observed when train suddenly stops? Homework Equations 1/2mv^2=dU?? or dU=0?? The Attempt at a Solution...
  19. T

    For the Boltzman equation, why is df/dt=0 when collisionless?

    From wikipedia, The general equation is $$\frac{df}{dt} = (\frac{∂f}{∂t})_{force}+(\frac{∂f}{∂t})_{diff}+(\frac{∂f}{∂t})_{coll}$$ where the "force" term external force, the "diff" term represents the diffusion of particles, and "coll" is the collision term. So shouldn't be df/dt=0 when it is...
  20. Hamza Abbasi

    Strain produced in a rod after expansion

    Homework Statement A rod of length ##L_o## is kept on a friction-less surface. The coefficient of linear expansion for the material of the rod is ##\alpha##. The the temperature of the rod is increased by ##\Delta T## the strain developed in the rod will be? Homework Equations $$ \Delta L=...
  21. Supernova00

    How can this thermodynamic phenomenon be explained

    Hi there. Earlier today I decided to pull out ice cream from the freezer. It is a magnum-type ice-cream and comes in a plastic wrapper. Once I opened the wrapper and removed the ice cream, I left the wrapper on the kitchen table and noticed something rather bizzarre (to me at least)...
  22. H

    Find the change in the Kinetic energy of an Ideal Gas

    Homework Statement Let 3/2kT be the kinetic energy of ideal gas per molecules. T the absolute temperature and N the avogadro number. Answer the following questions : 1) when the volume doubled at constant temperature. How many times the kinetic energy per molecule become greater than before...
  23. B

    Thermodynamics - temperature, pressure and heat

    Homework Statement The initial state of 0.1 mol of an ideal monatomic gas is P0=32 Pa and v0=8m3. The final state is P1=1 Pa and V1=64m3. Suppose that the gas undergoes a process along a straight line joining these two states with an equation P=aV+b, where a =31/56 and b=255/7. Plot this...
  24. EastWindBreaks

    Derivation process? (Heatsink Fin Heat Conduction Equations)

    Homework Statement I don't understand the derivation of the right side of the last equation. Homework EquationsThe Attempt at a Solution I got to this point, I also don't understand why it did not include C_2 for the variation of temp. along the fin. I am guessing the right side is the...
  25. EastWindBreaks

    What happened to the negative sign?

    Homework Statement Homework EquationsThe Attempt at a Solution I thought it would become d/dx(-kAc*dT/dx)+hp(T-T)=0 instead of where the equation in the red box? I don't see how are they equivalent [/B]
  26. M

    Conservation of energy (Waterfall)

    Homework Statement In a waterfall about 20 billion liters of water per hour drop about 110 m. What is the increase of the water temperature, assuming that the entire gain of heat is transferred to the water? Homework Equations I'm more curious about the question in itself. Perhaps I'm missing...
  27. R

    I Deriving the Boltzmann distribution

    I was reading the derivation of Boltzmann distribution using the reservoir model. lets call the reservoir by index R and the tiny system by index A. In the derivation they proposed that the probability for being at energy e (for A) is proportional to the number of states in reservoir. I didn't...
  28. Likith D

    Heat in Crowded Places: Origin and Explanation

    So, I have noticed that when people are crowded in small rooms, it feels hot. In fact, everyone in the crowd feels hot and starts sweating. I am wondering about the origin of all this heat. I do know that by first law of thermodynamics, if two people touch each other and if one of them feels...
  29. Hydrous Caperilla

    Thermodynamic Work: Non-Conducting Piston & Cylinder

    Homework Statement A non-conducting piston of mass m and area of cross section A is placed on a non-conducting cylinder. Intial height of piston is h and spring is relaxed with a spring constant k.Then,work done in displacing pistin by heating gas is (x is the displacement of the pistion)...
  30. Philip Koeck

    The exact formula for PV-work in an irreversible process

    I've written a short text adapted from a previous post by Count Iblis. I'll append it below. It shows that irreversible PV-work is always smaller than reversible, which fits very nicely with W = Pext ΔV. I'd be interested if there's a way to show that W is exactly equal to Pext ΔV for all...
  31. M

    Calculating work done by a Carnot engine

    "A Carnot engine operates using a heat source at 500 °C, and a heat sink at room temperature (20 °C). Suppose that as a heat source, you use the combustion of 100 cubic feet of natural gas at room temperature and pressure (e.g. in a fuel cell of some kind). Under ideal conditions, what is the...
  32. B

    Volume, pressure and final temperature

    Homework Statement a) A mass of 0.12 kg of air has an initial temperature of 500°C and pressure 0.8 MPa. If the air is expanded according to the law pV1.2 = c to a final volume of 90 litres, determine i) its initial volume, ii) its final pressure, iii) its final temperature...
  33. B

    Trying to reconcile two definitions of Entropy

    My question is regarding a few descriptions of Entropy. I'm actually unsure if my understanding of each version of entropy is correct, so I'm looking for a two birds in one stone answer of fixing my misunderstanding of each and then hopefully linking them together. 1) A measure of the tendency...
  34. F

    I Liquid-gas phase transition: metastable mixed states?

    Hello everybody. I am trying to understand better what happens at a liquid-gas phase transition for the Van Der Waals model. From what I have understood, from the Van Der Waals model we are able to plot the curve P(V) and to calculate the free energy F. Here are such curves : Then, we...
  35. kal

    I Trouble understanding the idea of a cavity radiator being a Black Body

    I have been trying to understand the role of a cavity as a black body radiator in the derivation of planks black body radiation law but it has left me with 5 main questions: 1. If an object is a perfect absorber it must also be a perfect emitter, meaning that (allowing for a cavity not being a...
  36. M

    Enthelpy in Throttle Process (Joule–Thomson expansion)

    Why is it written that enthalpy (##H##) is constant for Joule-Thompson expansion? It seems the essence of this process is to convert from one pressure to another with no heat loss. How does that connect with enthalpy being constant? When I learned about enthalpy it seemed to be most relevant to...
  37. EastWindBreaks

    Pressure of a piston cylinder device after heated

    Homework Statement I am confused on when will pressure of two states be the same for a piston cylinder device. Below are two problems where one's final pressure equals the initial pressure and one is not. Homework EquationsThe Attempt at a Solution Initially, I thought a piston-cylinder...
  38. EastWindBreaks

    What does sat. stands for in thermodynamic?

    Homework Statement The saturation temperature is given in the parentheses. then what is Sat. on the Temperature column? Homework EquationsThe Attempt at a Solution
  39. EastWindBreaks

    Heated piston & cylinder device with saturated water and vapor states

    [Mentor note: Thread title changed to describe actual problem being presented] 1. Homework Statement Homework Equations The Attempt at a Solution I understand you have to interpolate temperature and pressure of the saturated vapor from the table, since there is no matched final specific...
  40. Pushoam

    Change in entropy per mole for an isothermal process

    Homework Statement Homework EquationsThe Attempt at a Solution ## dS = \frac { dQ_{rev} } { T } ## Assuming that isothermal process is a reversible processes, ## dU = dQ – pdV## For isothermal process, dU = 0. ## dQ = pdV ## ## pV = nRT##, where n is number of moles. For one mole, ##...
  41. Pushoam

    Relation between chemical potential and S,V,T,P

    Homework Statement Homework EquationsThe Attempt at a SolutionChemical potential is defined as ## \mu = Gibbs potential per particle ##. So, is the system consists of N particles, ##\mu = \frac { G } {N } ##. Now, dG = VdP – SdT ## \frac {dG } { N } = \frac { VdP } { N } - \frac { SdT }...
  42. EastWindBreaks

    How to find specific volume given temperature?

    Homework Statement Homework Equations The Attempt at a Solution I don't understand how the solution got its values, not from the tables right? because I couldn't find such value from all of the tables. Since the pressure is less than the saturated pressure at given temperature, it is in...
  43. S

    Thermodynamics - Temperature change of Argon

    Homework Statement The temperature of n = 19 mol of argon gas is increased from T1 = 21 oC by Q = 4.4 kJ heat transfer, while the gas pressure is kept constant. What is the new gas temperature in Celsius degrees? Homework Equations and as its a monoatomic gas I think this means that the...
  44. G

    Change in Temperature for Stretched Surface

    Homework Statement The surface tension of a layer of water obeys ## \sigma = a- bT##, where ##T## is the temperature. Find the change in temperaure, ##\Delta T## when the area is increased isentropically. Homework Equations ## dU = dQ -dW## , ##dW = \sigma dA##, ##dU = C_A dT + [\sigma...
  45. G

    ##\alpha_P =\frac{V-b}{TV}## Find equation of State

    Homework Statement The coefficient of thermal expansion and isothermal compressibility of a gas are given by ##\alpha_P =\frac{V-b}{TV}## and ##\kappa_T = \frac{V-b}{PV}## find: a) The equation of state b) If the heat capacity at constant volume ##C_V## is constant, what is ##\delta U##? c)...
  46. F

    A Total force generated in a pneumatic cylinder-piston with kn

    I have also asked this question in SO and CFD online Assuming that we have a pneumatic cylinder-piston with arbitrary but known surface area A, a known clarence c, and a known length L. What is the best model to describe the total steady state force applied on the piston considering the...
  47. T

    Calculate minimum work input of refrigeration cycle

    Homework Statement The temperature of a 12-oz (0.354-L) can of soft drink is reduced from 20 to 5 ºC by a refrigeration cycle. The cycle receives energy by heat transfer from the soft drink and discharges energy by heat transfer at 20 ºC to the surroundings. There are no other heat transfers...
  48. KAM123

    Calculating Initial & Final Enthalpy, Kinetic Energy & Power in a Turbine

    A turbine operates under steady-flow conditions. It receives steam at a pressure of 15 bar, specific volume of 0.1318 m³/kg, velocity of 30 m/s and specific internal energy of 2594.5 kJ/kg. The steam leaves the turbine at a pressure of 30 kPa, velocity of 90 m/s, specific volume of 4.25 m³/kg...
  49. Matt James

    Thermodynamics: Calculating Pressure Increase From Work

    Homework Statement Estimate the pressure increase required to impart 1 J of mechanical work in reversibly compressing 1 mol of silver at room temperature. What pressure rise would be required to impart 1 J of work to 1 mol of alumina at room temperature? For alumina take the molar volume to be...
  50. EastWindBreaks

    Why is the height of point 2 same as point 3?

    Homework Statement Homework Equations The Attempt at a Solution Is it an assumption because the difference in height is small?
Back
Top