In summary: What is the chemical potential difference?But it can be very confusing...maybe you can clear it up for us.Chemical potential difference is the difference in energy that two molecules have due to the difference in the number of protons in their nucleus.
  • #71
mselectromagnetic said:
Since the battery has both inductance and capacitance, maybe this article by Tesla will help answer the question of whether a potential exists in relation to Earth ground:
https://www.thomastownsendbrown.com/petro/teslacap.htm
If there was anybody who understood this kind of thing, it was Tesla. What I think would be interesting would be to measure the potential of the battery's NEGATIVE pole in relation to Earth ground...at different elevations above the earth. In solar energy systems, the common practice is to use Earth ground to be compliant with code in most parts of the country. However, I bet you would never see the negative pole of the battery bank grounded in similar fashion...because there might actually be a parasitic potential there.
That's a bit typical of Tesla publications. No actual figures quoted and loads of Astrological style.
 
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  • #72
cianfa72 said:
Hi,

I've a question about electricity in the following scenario: consider an accumulator (e.g. a 9V battery) and an analog/digital voltmeter having a probe connected to the accumulator + clamp and the other to the ground (for instance connecting it to a metal rod stuck in the ground).

Do you think there will exist a electric potential difference as measured by the voltmeter ?

Thanks.
I like the way the OP asked this question, because they have embedded a little piece of 'natural philosophy' into it.

I will rephrase it to pose the question in a slightly different way; All isolated objects have their own distinct electric charge, which is (at least, theoretically) measurable compared to any other distinct object. So is the difference between the electric charges between two objects not a measure of 'potential difference'? If so, we know one terminal on the battery has more electrons than the other end, so we also know that there is more charge on one of the battery terminals to the other. So, "whatever that difference is" to ground, even if it is some imaginary number, the 'other terminal' should be a larger/smaller difference by 9V?

I will answer this in the following way;-
"Potential difference" is measured in Volts. Volts are Joules per coulomb of charge.

You are correct that the difference (to Earth) in the amount of charge on one battery terminal will be greater than the other terminal, whether or not that is practically measurable is a different question. Therefore, logically, it is inescapable that you would also be correct that one terminal has a bigger difference of charge to the other, with respect to any other object.

But here's the crunch - 'potential' means the potential to do work. There is a charge difference, but it is not (necessarily) a difference that can do work. Ergo, not related to 'potential difference'.

I will add one caveat on that, because it is not precisely true that 'zero' work is done, it is simply virtually unmeasurable in the scenario you mention. What happens when you connect your voltmeter to the negative terminals and ground is that you push up the positive terminal to +9V above ground by doing that. Likewise if you did that to the +ve you'd push the negative terminal low. In doing so, you would change the energy stored in the 'battery-Earth' capacitor system, because there would be some non-zero finite capacitance, thus energy stored. As the battery pushes its terminals up and down voltage relative to ground, it would 'do work'. But as the capacitance would be so small, any physical instrument would swamp that signal.

If, however, you connected one of the terminals to an actual capacitor, and the other end of the capacitor to ground, it would still not be connected to ground. But if you put your voltmeter on one of the terminals now, you'd likely see the meter giving an actual real reading, and it would likely change over time tending to zero as the capacitor charges up to the battery voltage. In practice with no capacitor, this happens virtually instantaneously because the battery-Earth capacitance is so small. The time taken will be according to the 'RC' curve where R is your voltmeter internal resistance.

So I would refute that the potential difference on an isolated battery terminal is undefined with respect to any other object. There has to be absolutely zero capacitance between the two objects for there to be no potential difference. OK, so that might be 10^-100 small and overwhelmed by even cosmic radiation coming along and upsetting the charges on the parts, but there will be a non-zero potential so long as there is a capacitance between them.

It will, of course, be completely unmeasurable by the OPs voltmeter, so that answers the question!
 
  • #73
Let's ask @cianfa72 if that answers the question ?
 
  • #74
cmb said:
What happens when you connect your voltmeter to the negative terminals and ground is that you push up the positive terminal to +9V above ground by doing that. Likewise if you did that to the +ve you'd push the negative terminal low. In doing so, you would change the energy stored in the 'battery-Earth' capacitor system, because there would be some non-zero finite capacitance, thus energy stored. As the battery pushes its terminals up and down voltage relative to ground, it would 'do work'. But as the capacitance would be so small, any physical instrument would swamp that signal.
in this model which are actually the two 'plates' of the 'battery-Earth' capacitor system ?

cmb said:
If, however, you connected one of the terminals to an actual capacitor, and the other end of the capacitor to ground, it would still not be connected to ground. But if you put your voltmeter on one of the terminals now, you'd likely see the meter giving an actual real reading, and it would likely change over time tending to zero as the capacitor charges up to the battery voltage. In practice with no capacitor, this happens virtually instantaneously because the battery-Earth capacitance is so small. The time taken will be according to the 'RC' curve where R is your voltmeter internal resistance.
Not sure to understand the model: how is the voltmeter connected here ? Are you considering a simple 'RC' series circuit ?

Thanks
 
  • #75
cianfa72 said:
in this model which are actually the two 'plates' of the 'battery-Earth' capacitor system ?
One of them is the battery and the other is the earth. (Don't be confused because neither of them look like "plates". Introductory textbooks generally work with the special case of parallel plate capacitors but that's not because capacitors have to be that way, it's because the parallel plate capacitor is an easy example of how to calculate approximate capacitance from first principles).
Not sure to understand the model: how is the voltmeter connected here ? Are you considering a simple 'RC' series circuit ?
No, we are not considering a simple RC circuit. After three pages of this thread, do we have say, yet again, that THERE IS NO CIRCUIT?

We have a capacitor with one terminal connected to the battery and the other terminal connected to the earth, and a voltmeter with its probes on each side of the capacitor. And this is equivalent to the configuration you started with, one probe on the battery and the other on the earth; it's only interesting to consider it because it's easy to buy a capacitor with much more capacitance than in your original setup.
 
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  • #76
cianfa72 said:
in this model which are actually the two 'plates' of the 'battery-Earth' capacitor system ?
The metallic conductor of each electrode in the battery.

In practice (if 'in practice' makes any sense in this scenario with virtually zero actual capacitance), assuming the battery case is metallic which it probably is, there will be a capacitance between the outer case of the battery and Earth (the two 'plates') then you will effectively have two further capacitors in parallel (but in series with the case-Earth 'capacitance') to the battery electrodes

cianfa72 said:
Not sure to understand the model: how is the voltmeter connected here ? Are you considering a simple 'RC' series circuit ?

Thanks
An ideal voltmeter has infinite resistance. But it is impossible for a real world voltmeter to have infinite resistance. They usually come with 1 MOhm or 10MOhm internal resistance, so that'll be your 'R'.

[In fact, I often measure kV/ua stuff with cheap multimeters (they tend to blow up on a regular basis, no point buying expensive ones) and I don't bother with the current selections, I just pass the current straight through the 'voltmeter' setting, giving me ua = volts based on a 1 MOhm internal resistance.]

FWIW There is no such thing as an infinite resistance. It's funny really, because intuitively you'd expect 'something' to be a perfect insulator and 'nothing' to be a perfect conductor, but reality treats us to something non-intuitive that there is no such thing as a perfect insulator, but there is such a thing as a perfect conductor! Your voltmeter will always pull the battery terminal to ground when you try to measure it, there is nothing connected to the other terminal to stop that. A capacitance would slow that down, but not stop it.
 
  • #77
Nugatory said:
No, we are not considering a simple RC circuit. After three pages of this thread, do we have say, yet again, that THERE IS NO CIRCUIT?
yes got it...there is no galvanic closed circuit through the Earth.

Nugatory said:
We have a capacitor with one terminal connected to the battery and the other terminal connected to the earth, and a voltmeter with its probes on each side of the capacitor. And this is equivalent to the configuration you started with, one probe on the battery and the other on the earth; it's only interesting to consider it because it's easy to buy a capacitor with much more capacitance than in your original setup.
here, let me say, we are basically considering a simple RC parallel where R is actually the internal voltmeter resistance
 
  • #78
sophiecentaur said:
That's a bit typical of Tesla publications. No actual figures quoted and loads of Astrological style.
I guess he was writing for the general public at the time. However, I have seen Youtube videos of people putting wires at the top of a pine tree and measuring a potential when putting a meter from that lead to a grounded lead. I don't recall seeing any astrology in that article.
 
  • #79
mselectromagnetic said:
I have seen Youtube videos of people putting wires at the top of a pine tree and measuring a potential when putting a meter from that lead to a grounded lead.

Could you find it URL so we could see it?
 
  • #80
gleem said:
Could you find it URL so we could see it?
 
  • #81
This is not the one I saw before, but still somewhat interesting. The other one will take some searching, but I think it was John Hutchison doing the experiment.
 
  • #82
mselectromagnetic said:
I don't recall seeing any astrology in that article.
I referred to astrological style and not astrology. Tesla did an awful lot of waffling and had his audience enthralled. I'm amazed that the 'enthraldom' seems to persist to this day. True, he made a choice about adopting the use of AC Power; lucky guess? There was a lot of 'general ignorance' about 'electricity' at the time and fortunes were won and lost on the strength of non-engineering hunches. ("So what's different now?", I hear you cry - but PF didn't exist in those days)
We haven't been shown that article but another article . . . . . .
mselectromagnetic said:
This is not the one I saw before, but still somewhat interesting. The other one will take some searching, but I think it was John Hutchison doing the experiment.
He says he's measuring "nine point nine volts" when the meter appears to read 0.99V. He has actually posted it! What does that say about experimental method? How long did the PD exist for and what was the drain current?
 
  • #83
sophiecentaur said:
He says he's measuring "nine point nine volts" when the meter appears to read 0.99V. He has actually posted it! What does that say about experimental method? How long did the PD exist for and what was the drain current?
Looks like he is using galvanized screws. I believe the emf of copper- zinc galvanic cell is about 1V. The man is an idiot.
 
  • #84
cianfa72 said:
Hi,

I've a question about electricity in the following scenario: consider an accumulator (e.g. a 9V battery) and an analog/digital voltmeter having a probe connected to the accumulator + clamp and the other to the ground (for instance connecting it to a metal rod stuck in the ground).

Do you think there will exist a electric potential difference as measured by the voltmeter ?

Thanks.
Answer to your question in one word is "no"
To clarify further we may split the question into two parts
1) Do you think there will exist a electric potential difference(between +clamp and earth)? Answer is "yes"
2) Can the above potential difference be measured by voltmeter? Answer is "no".Because voltmeter needs a closed circuit to work
 
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