- #7,911
etudiant
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Calvadosser said:I would be grateful if someone knowledgeable about such things would post a brief explanation of the principles of operation of a plant for decontamination of water containing a range of radioactive elements in solution.
I can see that distillation would do the job in principle but I find it difficult to imagine it being used on the scale needed here.
The idea is to precipitate out the radioactives by introducing chemicals that reacts with the cesium, iodine etc to form insoluble compounds that can then be filtered out. The usual illustration in chemistry textbooks is using H2S to precipitate silver sulfide out of a silver chloride solution. It is possible that for this case there needs to be more than one precipitation to sequester the different materials in the water. No idea exactly what the Areva chemistry is, how many steps are involved and what the individual stage efficiencies are.
The hope is of course that the volume of seriously radioactive material can be very much reduced
Distillation is probably not a way forward, as the boiling point for iodine or cesium is low enough that both materials have high enough vapor pressure at 100*C to contaminate the steam produced.