- #36
Saul
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vanesch said:That is a very elementary misunderstanding of the greenhouse effect, you know. When CO2 absorbs, it also emits thermal radiation. It is unfortunate that the popular explanation of the greenhouse effect concentrates on "absorption" by greenhouse gasses. They absorb, and they re-radiate. However, they re-radiate according to the temperature of the air where they are. A layer of CO2 that is at the same temperature than the surface has strictly no effect on the thermal radiation emanating from that surface, as it will emit exactly as much as it will absorb. It is only because the "last layer" is at a lower temperature than the "emitting surface" that there *seems to be* a net absorption.
Indeed, but what counts is what is re-emitted, and hence, at what altitude (and hence at what temperature) that "last emitting layer" is. As such, the fact that there is total absorption (several times over) of certain lines doesn't matter, because it also means that there is re-emission. More (evenly distributed) absorption gas simply means that the "last emitting layer" is higher up, and hence colder.
If you would have a thick layer of totally black gas, 50 meters thick, hovering over the Earth's surface, that wouldn't cause any greenhouse effect at all, because that layer of gas (at the same temperature as the surface) would absorb all of the surface's radiation, but would also emit exactly the same radiation upward.
My point is that CO2 only absorbs and emits specific frequencies. If the photons are frequency shifted off of those frequencies CO2 no longer is a factor. Do you understand that point?
Does any in the forum disagree with that assertion?
This is a good paper that describes the basic physics of greenhouse gases.http://www.warwickhughes.com/papers/barrett_ee05.pdfGreenhouse molecules, their spectra and function in the atmosphere by Jack Barrett
Comment:
In the above you state something about absorption and emission which appears to not be relavent to my point.
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