X ray crystallography - interpreting my graph

Click For Summary
The discussion centers on the use of X-ray crystallography to analyze NaCl, specifically addressing concerns about the continuous spectrum produced by a Molybdenum anode lamp and its implications for data interpretation. Participants clarify that bremsstrahlung radiation is detected because it scatters off the crystal, despite being generated in the X-ray tube. The importance of understanding the emission spectrum of Molybdenum is emphasized, as it contains significant peaks that are crucial for calculating lattice constants. The inquiry about the necessity of a Zr absorber foil suggests a misunderstanding of its role in the context of the experiment. Ultimately, recognizing the characteristics of the detected peaks is essential for accurate calculations of d_hkl.
Old_sm0key
Messages
17
Reaction score
0

Homework Statement


I am currently part way through a laboratory experiment that utilises basic crystallography to ultimately calculate lattice constants and structure factors for NaCl (we receive formal training in the next academic year via full treatment of von Laue, Bragg diffraction etc).
I have consulted a couple of recommended textbooks, but nothing addresses my concerns.
Our X ray spectrometer his an unfiltered Molybdenum anode lamp. The goniometer is geared to maintain the Bragg geometry (Geiger tube turns at twice angular speed of table).

The plot for scanning across angles for a NaCl crystal is shown below.

Now here is my major query:
Bremsstrahlung with Mo {k_alpha and k_beta} emission lines are incident on the NaCl.
  • What use it is having a continuous spectrum incident on the crystal? I thought standard practise is to attenuate with say a Zr absorber foil via the absorption principle?
  • Why is bremsstrahlung *detected* - I thought it is just produced by the Mo anode in etc X ray tube?
  • Not knowing precisely what each pair of peaks (of diminishing intensity) shows, I do not know how to calculate d_hkl from this plot
Kf8UF0N.png

Homework Equations


n\lambda =2d_{hkl}\sin \theta

The Attempt at a Solution

 
Old_sm0key said:
What use it is having a continuous spectrum incident on the crystal? I thought standard practise is to attenuate with say a Zr absorber foil via the absorption principle?
Depends on your application I think.
Old_sm0key said:
Why is bremsstrahlung *detected* - I thought it is just produced by the Mo anode in etc X ray tube?
It is produced in the x-ray tube and scattered in the NaCl crystal. Where is the problem?
Old_sm0key said:
Not knowing precisely what each pair of peaks (of diminishing intensity) shows, I do not know how to calculate d_hkl from this plot
You can look up the spectrum for Molybdenum anodes. There are two very prominent peaks.
 
The book claims the answer is that all the magnitudes are the same because "the gravitational force on the penguin is the same". I'm having trouble understanding this. I thought the buoyant force was equal to the weight of the fluid displaced. Weight depends on mass which depends on density. Therefore, due to the differing densities the buoyant force will be different in each case? Is this incorrect?

Similar threads

  • · Replies 1 ·
Replies
1
Views
2K
Replies
3
Views
4K