Entropy Definition and 1000 Threads

  1. slatts

    Scale of perturbations re entropy, in quantum bounce

    In Bojowald's 2010 popularization of Loop Quantum Cosmology Once Before Time, there's a sketchy diagram (on his p.125) showing quantum perturbations in a transitional phase between contracting and expanding universes as widest at earlier times of decreasing volume, narrowing at the...
  2. Jimster41

    Is the concept of entropy addressed in the Lagrangian formalism?

    just working my way through Susskind's "Theoretical Minimum". At the Langrangian formalism I'm in novel territory so this may be a dumb question. Kind of multiple choice or fill in a real answer. Why is there no term for the Entropy of a system in the Lagrangian? Is it because time is an...
  3. L

    Entropy Change for an Ideal Gas

    Homework Statement 10 moles of an ideal gas Cv = 20.8 J/mol at T0 = 300 K and P0 =0.3 MPa occupy the left half of an insulated vessel. At time t=0 a 1 kW electrical heating element is turned on. after 30 s, the partition dividing the vessel ruptures and the heating element is turned off...
  4. G

    How Do I Determine the Change in Entropy of the System?

    Homework Statement Determine ΔSsys when 3.0 mol of an ideal gas at 25°C and 1 atm is heatedd to 125°C and expanded to 5 atm. Rationalize the sign of ΔSsys. Homework Equations State Function: dS = (dU)/T + (PdV)/T State Function for Entropy of Ideal Gas: dS = (CV,mdT)/T + (nRdV)/V Ideal gas...
  5. Jimster41

    Is the Hubble Constant Linked to the Second Law of Thermodynamics?

    Do I understand correctly (in general terms) or wildly incorrectly if I imagine that the constant of expansion and the second law of thermodynamics are very closely connected, or even that the constant of expansion is potentially the source of the second law?
  6. Alexi-dono

    Python [python] How can I get my OS to pick this up as entropy?

    So I am going to be making some keys; and I want to make them more random... So I made this: #I know that the code is pretty crude, but it works. #P.S. it is an infinite loop, run at your own risk import random from random import randint import string import time x=1 n=randint(5,90)...
  7. G

    Determine all of the Physical Chemistry Variables of the System

    Homework Statement A weather balloon is filled with Helium gas and released from the ground. It goes up 18km and achieves a diameter of 15m. Determine if the following values are greater than zero, less than zero, or equal to zero: ΔV, ΔP, ΔT, ΔU, ΔH, Ssys, surr, Stot Homework Equations ΔU =...
  8. A

    Contradiction in thermodynamics problem?

    Consider a gas as your system, confined in the usual frictionless piston-cylinder. The piston is massless, external pressure is constant, Pext. Let the system be at initial state T1 and P1 = Pext. We want to compare the following two processes: in the first process, we reversibly heat the gas...
  9. predaylight

    De Broglie wavelength and ideal gas entropy derivation

    When the ideal gas entropy is derived, we consider N atoms in a box of volume=Lx*Ly*Lz. Then, we make the assumption that Lx,Ly,Lz >>de Broglie wavelength of atoms. I am not sure why we need to make this assumption? Thanks!
  10. It's me

    Callen Thermodynamics 2.8-2 matter flow equilibrium

    Homework Statement A two component gaseous system has a fundamental equation of the form $$S=AU^{1/3} V^{1/3} N^{1/3} + \frac{BN_1N_2}{N}$$ where $$N=N_1+N_2$$ and A and B are positive constants. A closed cylinder of total volume 2V_0 is separated into two equal subvolumes by a rigid diathermal...
  11. E

    Exploring the Mysteries of Black Hole Entropy and the Holographic Principle

    How exactly did Hawking compute that black hole entropy is 1/4 that of a Planck area and concluded about the holographic principle where information of a volume is located on the area of black hole? And if there was no holographic principle, how big should entropy of the black hole be with...
  12. S

    Confusion on entropy change calculations for irreversible process

    I was studying 2nd law thermodynamics. In that context found the clausius's inequality saying closed integral of dQ/T <0 for irreversible process. And from the reversible process entropy was defined. And from that view they said that for irreversible process dS>dQ/T. Now when I saw some...
  13. J

    Entropy increase in adiabatic irreversible compression

    Hi there, I was wondering if you could help me, I think I may have some concepts wrong or incomplete. Homework Statement We have an adiabatic cylinder of volume ##V_1## filled with a gas of pressure ##p_1## and temperature ##T_1## in thermal equilibrium, closed with a piston. All of a suden...
  14. Jewish_Vulcan

    Describe disorder in terms of entropy

    when they mean disorder do they mean the range of velocities of the particles increasing as entropy increases? so there are larger differences between the low KE particles and the high KE particles?
  15. Newb_Aero_Ninja

    Convergent Subsonic Ramjet Utilizing Shockwave Compression

    Hi, I am working on investigating an idea I proposed regarding a ramjet that operates in subsonic flow (of a fixed speed) with a convergent intake. That utilizes the pressure immediately behind a standing shock-wave for compression. I have posted a link to my initial report here and I now need...
  16. T

    Relationship between pressure & chem potential in ideal gas

    Homework Statement (Excerpted from a longer, multipart problem but essentially) Show that for an ideal gas, $$ \frac{\partial p}{\partial T}\bigg)_\mu = \frac{S}{V}. $$ Homework Equations • The ideal gas law, of course $$ pV = Nk_{\rm B}T $$ • Pressure, temperature, and chemical potential...
  17. diegzumillo

    Entropy as log of omega (phase space volume)

    Homework Statement I've seen this problem appear in more than one textbook almost without any changes. It goes like this: Assume the entropy ##S## depends on the volume ##\bar{\Omega}## inside the energy shell: ##S(\bar{\Omega})=f(\bar{\Omega})##. Show that from the additivity of ##S## and the...
  18. J

    Entropy (Information Theory Question)

    Homework Statement Let ##X## and ##Y## be two independent integer-valued random variables. Let ##X## be uniformly distributed over ##\left\{1,2,...,8\right\}##, and let ##\text{Pr}\left\{Y=k\right\} =2^{-k},~k=1,2,3,...## (a) Find ##H(X)##. (b) Find ##H(Y)##. (c) Find ##H(X+Y,X-Y)##. Homework...
  19. N

    Proof of "Entropy of preparation" in Von Neumann entropy

    How should I prove this? From John Preskill's quantum computation & quantum information lecture notes(chapter 5) If a pure state is drawn randomly from the ensemble{|φx〉,px}, so that the density matrix is ρ = ∑px|φx〉<φx| Then, H(X)≥S(ρ) where H stands for Shannon entropy of probability {px}...
  20. R

    Why Is Entropy Non-Zero in This Hamiltonian System?

    Homework Statement Bonjour, Given the hamiltonian Show that The Attempt at a Solution [/B]...
  21. V

    Papers on Entropy in Quantum Mechanics Framework

    Hey, I am going to write my bachelor's thesis on Entropy in a Quantum Mechanical Framework. My professor told me he would refer me to some literature. However it will take him some time. I would like to get started myself. Could you please refer me to papers, books, articles? I have already read...
  22. MexChemE

    Gibbs free energy and entropy inconsistency

    Homework Statement For a certain reaction, ΔG = 13580 + 16.1 T log10(T) - 72.59 T. Find ΔS and ΔH for the reaction at 298.15 K. Homework Equations ΔG = ΔH - TΔS \left[\frac{\partial (\Delta G)}{\partial T} \right]_P = - \Delta S The Attempt at a Solution For the sake of this thread's length I...
  23. L

    Change in Entropy for Isothermal Compression of Ideal Gas

    Problem statement: A sample of 8.02 × 10-1 moles of nitrogen gas ( γ = 1.40) occupies a volume of 2.00 × 10-2 m3at a pressure of 1.00 × 105 Pa and temperature of 300 K. It is isothermally compressed to half its original volume. It behaves like an ideal gas. Find the change in entropy of the gas...
  24. A

    How Is Entropy Change Calculated in a Heat Transfer Problem?

    Homework Statement A solid metallic cube of heat capacity S is at temperature 300K. It is brought in contact with a reservoir at 600K. If the heat transfer takes place only between the reservoir and the cube, the entropy change of the universe after reaching the thermal equillibrium is A...
  25. P

    What Is the Maximal Work from Two Equal Bodies with Different Temperatures?

    Homework Statement Two equal bodies with temperatures T1 and T2. T1 > T2. The specific heat c does not depend on temperature. What is the maximal work which can be done from this system? I have to get equation for max work which includes c and temperatures. Homework Equations This seems to...
  26. S

    Are "isentropic" and "adiabatic" same?

    Isentropic means a process where entropy remains constant. Now formula for entropy is ΔS = ΔQ/T now in an isentropic process, ΔS=0...so that means ΔQ = 0 ...right? but if ΔQ = 0, that is an adiabatic process. so are isentropic and adiabatic processes are...
  27. B

    Why is there a factor 2 in entropy development

    Hi, How do you explain the factor 2Nklog(2) in the last equation. Is there any mistake here?
  28. Chemer

    Understanding Thermodynamics Entropy: Common Questions Answered

    Hi, I've a few questions about entropy. Entropy is the measure of disorder in universe, and the entropy of universe always increase. So, is saying this correct that entropy is the unusable energy causing the disorder and due to this the amount of useable energy decrease every time when the...
  29. S

    Making sense of the units of entropy: J/K

    Hi everyone, I have a conceptual question about entropy. I understand perfectly why mathematically the units of entropy are energy per temperature (SI: J / K). However, I would like to better understand the significance of these units. For example, the SI units for speed/velocity are m / s...
  30. avito009

    Entropy as number of microstates

    As we know S=Q/T. And Entropy is defined as number of microstates of a system. So does that prove that, the lower the temperature the more the microstates available?
  31. J

    MHB Max Entropy of 16-Symbol Source

    Hi I am studying entropy and I am new to the concept I don't know where to start in this question: State the maximum entropy of a 16-symbol source. thank you
  32. avito009

    How Does Entropy Influence Hawking Radiation in Black Holes?

    I know that entropy is a measure of disorder. But Entropy is also a function of the state of a system, and has a value determined by the state variables of the system. Does that mean Entropy describes the equilibrium state of a system. Please explain in layman terms in this context what is...
  33. L

    Entropy of translation and rotation of a molecules

    Homework Statement Hi all, There is a question from the course book: Homework Equations S=k_B ln W The Attempt at a Solution My solution: So first of all, for each molecule, there are 2 motions: translational and rotational. For rotational I get: W_1 =\Omega \left ( \theta \right ) For...
  34. M

    What is the Entropy of a Half Reaction?

    Hi everybody, I have some troubles to define the enthalpy and entropy of a half reaction. If we consider the 2 following reactions : Anode : H2 = 2H+ + 2e- Cathode : 2H+ + 2e- + 1/2O2 = H2O So the global reaction is : H2 + 1/2O2 = H2O We know the global reaction's entropy can...
  35. Paul Howard A

    Progression of Time & Entropy: Is the Pass. Slowing?

    The directionality of time seems to be linked to the process of increasing disorder. Is the 'passage' of time similarly linked? If so, it would seem that the passage of time would generally slow down as the universe cools. And perhaps time should pass more slowly in cooler regions of the...
  36. Y

    Understanding the Relationship between Entropy and Temperature

    I am unable to grasp why is entropy inversely proportional to temperature. My book says that "Heat added to a system at a lower temperature causes higher entropy increase than heat added to the same system at a higher temperature." What is meant by this statement?
  37. T

    Understanding the Second Order Relation of Entropy: A Homework Guide

    Homework Statement Find: Homework Equations The Attempt at a Solution
  38. S

    Understanding Entropy: The Impact on Systems

    What is entropy ?, And how it effect the system?
  39. F

    Understanding entropy calculations

    Homework Statement A mass m of water cools down from 50degc to 10degc (the temperature of the surrounding environment). Calculate the entropy increase of the system (the water). The water has specific heat capacity c. Homework Equations dS=dQrev/T S is entropy, Q is heat added to the system, T...
  40. S

    How Does a Constant Temperature Affect Spring Entropy?

    Homework Statement Homework Equations The Attempt at a Solution I have already submitted these questions and have gotten them wrong. I'm just wanting to see how to properly do it. Thanks.
  41. S

    Change in entropy of system and universe

    Homework Statement 50.0g of water (the system) at 30C is frozen to ice at a final temp of -10C in a freezer. Assuming that the volume of water remains the same during the process, calculate the change in entropy of the system and the change of entropy of the thermal universe when the system...
  42. R

    Entropy of the initital state of the universe

    I saw an old interview with Roger Penrose where at one point he was talking about the degree of organization the universe exhibited at it's initial state. He said the second law of thermodynamics tells us as time passes the universe is becoming more disorderly, which means if we were to go back...
  43. ChristineMarie

    How to Calculate Entropy of an Ideal Gas During Expansion?

    How do you calculate the entropy of an ideal gas with n = 1, Cv,m = 1.5R, Ti = 300K, P=3bar and expands against Pext = 1bar until final volume is twice initial volume at Tf = 200K?
  44. V

    Shannon Information Theory: Transducer Entropy doesn't increase

    HI, I am reading Shannon's paper on Theory of Communication and I having trouble with a concept. Shannon writes: The output of a finite state transducer driven by a finite state statistical source is a finite state statistical source, with entropy (per unit time) less than or equal to that of...
  45. S

    Entropy: Joules per Kelvin Explained

    Whilst I understand that entropy is a measure of the number of specific ways in which a system may be arranged. The units for entropy don't make sense to me intuitively. Why joules per kelvin? What way at all does that show how "disordered" a system is. When I hear joules per kelvin, I think of...
  46. SalfordPhysics

    Derive Entropy Change for Ideal Monatomic Gas

    A Monatomic gas passes from state 1 (pressure p1, volume V1) to state 2 (p2, V2). Derive an expression for the change in entropy of a monatomic ideal gas. The required final equation is: ΔS = Cv ln(T2/T1) + nRln(V2/V1) In my attempt, I am retrieving ΔS = Cv ln(T2/T1) + Rln(V2/V1) i.e.; the...
  47. H

    Deriving Boltzmann's Distribution

    I am sure this has a simple answer, but I don't seem to get it at the moment. I am going through a derivation of the Boltzmann's distribution by maximising the entropy with the constraints that the sum of the probabilities add to 1 and the average energy is some constant value. My question is...
  48. ZetaOfThree

    What Is the Total Probability of Rolling a 6 with Maximum Shannon Entropy?

    Homework Statement A 6 sided dice is loaded such that 6 occurs twice as often as 1. What is the total probability of rolling a 6 if the Shannon entropy is a maximum? Homework Equations Shannon Entropy: $$S=-\sum_i p_i \ln{p_i}$$ where ##p_i## is the probability that we roll ##i##. The Attempt...
  49. C

    Entropy in isothermal expansion

    Air: V1= 0,1 m3 P1= 1 MPa T1= 20 C After isothermal expansion P2= 0,1 MPa I had to find T2, M, V2, L, Q and found all those (T2=20 C; M=1,1927 kg; V2=1 m3; L=Q=230258 J) but need s (enthropy) for creating illustration in T-s I can`t find how it`s possible to calculate s1 and s2, is it possible...
  50. Q

    Is it possible to create order from disorder in a thermodynamic system?

    Hi all I hope you can help me with the statistical origins of the Second Law. I cannot find anything that mathematically proves that order from disorder is impossible only improbable. Leading me to think that a system (Kelvin engine) that allows order to be created from disorder (work from...
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