Entropy is a scientific concept, as well as a measurable physical property that is most commonly associated with a state of disorder, randomness, or uncertainty. The term and the concept are used in diverse fields, from classical thermodynamics, where it was first recognized, to the microscopic description of nature in statistical physics, and to the principles of information theory. It has found far-ranging applications in chemistry and physics, in biological systems and their relation to life, in cosmology, economics, sociology, weather science, climate change, and information systems including the transmission of information in telecommunication.The thermodynamic concept was referred to by Scottish scientist and engineer Macquorn Rankine in 1850 with the names thermodynamic function and heat-potential. In 1865, German physicist Rudolph Clausius, one of the leading founders of the field of thermodynamics, defined it as the quotient of an infinitesimal amount of heat to the instantaneous temperature. He initially described it as transformation-content, in German Verwandlungsinhalt, and later coined the term entropy from a Greek word for transformation. Referring to microscopic constitution and structure, in 1862, Clausius interpreted the concept as meaning disgregation.A consequence of entropy is that certain processes are irreversible or impossible, aside from the requirement of not violating the conservation of energy, the latter being expressed in the first law of thermodynamics. Entropy is central to the second law of thermodynamics, which states that the entropy of isolated systems left to spontaneous evolution cannot decrease with time, as they always arrive at a state of thermodynamic equilibrium, where the entropy is highest.
Austrian physicist Ludwig Boltzmann explained entropy as the measure of the number of possible microscopic arrangements or states of individual atoms and molecules of a system that comply with the macroscopic condition of the system. He thereby introduced the concept of statistical disorder and probability distributions into a new field of thermodynamics, called statistical mechanics, and found the link between the microscopic interactions, which fluctuate about an average configuration, to the macroscopically observable behavior, in form of a simple logarithmic law, with a proportionality constant, the Boltzmann constant, that has become one of the defining universal constants for the modern International System of Units (SI).
In 1948, Bell Labs scientist Claude Shannon developed similar statistical concepts of measuring microscopic uncertainty and multiplicity to the problem of random losses of information in telecommunication signals. Upon John von Neumann's suggestion, Shannon named this entity of missing information in analogous manner to its use in statistical mechanics as entropy, and gave birth to the field of information theory. This description has been proposed as a universal definition of the concept of entropy.
1. Suppose that you have a sample of a gas in a cylinder equipped with a piston that has a volume of 1.50 L, a pressure of 1.20 atm, and a temperature of 250 K. Suppose that the gas is expanded reversibility under isothermal conditions until the pressure is 0.75 atm. What is the entropy change...
Homework Statement
An aluminum can, with negligible heat capacity, is filled with 150g of water at 0 ∘C and then is brought into thermal contact with a similar can filled with 150g of water at 53∘C.
Find the change in entropy of the system if no heat is allowed to exchange with the...
Homework Statement
1.00mole of nitrogen (N2) gas and 1.00mole of argon (Ar) gas are in separate, equal-sized, insulated containers at the same temperature. The containers are then connected and the gases (assumed ideal) allowed to mix.
A) What is the change in entropy of the system?
B) What is...
Homework Statement
I am to show that ΔS=Q/T for the isothermal expansion of a monoatomic ideal gas, when the expansion is so slow that the gas is always in equilibrium.
Homework Equations
1. law: ΔU=Q+W (We mustn't use dQ and dW - our teacher hates that :( ).
Ideal gas law: PV=NkT
We need the...
Homework Statement
A liter of air, initially at room temperature and atmospheric pressure, is heated at constant pressure until it doubles in volume. Calculate the increase in its entropy during this process.
so Ti= 300K, Volume which is 2Vi=Vf; Pressure is constant
Homework Equations
ΔS...
Homework Statement
http://puu.sh/c09sc/b1d02302bd.png
Homework Equations
Conceptual question.
The Attempt at a Solution
The answer is isothermal expansion(D).
but heat does not decrease due to isothermal process and expansion leads to lesser collision of particles on walls of container.
So...
I am teaching myself Stat Mech / thermo from Swendsen's "An Introduction to statistical mechanics and thermodynamics". To this point I find the book interesting and clear to follow.
But in section 4.6, Probability and Entropy, he confuses me by concluding that the entropy that he defines there...
Hi. Say you have a canonical ensemble, and its zustandssumme is ##Z = \sum_j e^{- \beta E_j}##.
Then $$d \: ln(Z) = \frac{-d\beta}{Z} \sum_j e^{- \beta E_j} E_j - \frac{-\beta}{Z} \sum_j e^{- \beta E_j} dE_j$$
Further, my book says the second term is given by the work ##dW## done on the...
Sean Carroll has stated several times that the reason we can remember the past and not the future is because entropy is increasing, i.e. because there is an arrow of time. Is this statement justifiable?
Remember that life and its processes, including memory, require negentropy. In other words...
A few months ago my door broke, so can I say the Entropy of the door is increased? This is because I read that Entropy is wear and tear. So the door broke due to wear and tear.
Homework Statement
A piston‐cylinder initially contains 0.5 m3 of an ideal gas at 150 kPa and 20 degrees. The gas is suddenly subjected to a constant external pressure of 400 kPa and it is compressed in a manner that the final temperature is also 20oC. Assume the surroundings are also at 20...
I have a conceptual question that I am trying to clear up.
A reversible process means that the net change in entropy is zero.
If we have two scenarios, where case 1 has a ΔS= 0.1 J/K and case 2 has a ΔS= 0.5 J/K.
Is it a correct statement to say that case 1 is "less irreversible (i.e...
Certainly fission is a prime example of entropy. But what about fusion? Doesn't fusion look like a process that goes from a disordered state to an ordered one? Out of chaos comes order!
If dark matter affects normal matter (by gravity), does that mean that normal matter also affects dark matter? I think it does...
In which case;
Black holes could attract BOTH dark and normal matter?
Does this give any opportunity to "information loss"?
What if some information in normal...
Do different observers, say, inertial and accelerated, moving thru the same point in space, agree on the entropy of the same isolated system they observe?
I am interested in it in the context of Unruh effect. If we switch between inertial and accelerated frames, we switch Unruh particles...
Assuming a big crunch theory were to be true (I know it's not too popular a theory these days) I figure a collapsing universe would need to have decreasing entropy. If entropy is decreasing, would the arrow of time flip? Also, because physics is just as valid with time moving backwards, would...
Homework Statement
I know that the equation ΔSsystem = Q/T is only valid for a reversible process but whenever i see problems involving a irreversible isothermal expansion of ideal gas, the ΔSsurroundings is taken as -Qirr/T. Why is that equation valid for surroundings, is it because the...
Homework Statement
Calculate the entropy change of an ice cube of mass 10g, at an initial temperature of -5°C, when it completely melts.
cice = 2.1 kJkg-1K-1
Lice-water = 3.34x105 Jkg-1
Homework Equations
dQ = mcdT
dS = \frac{dQ}{T}
ΔS = \frac{Q}{T}
Q = mL
The Attempt at a...
Homework Statement
A well-insulated rigid tank contains 7 kg of a saturated liquid-vapor mixture of water at 150 kPa. Initially, three-quarters of the mass is in the liquid phase. An electric resistance heater placed in the tank is now turned on and kept on until all the liquid in the tank is...
Homework Statement
Imagine that the temperature of 255 g of aluminum sitting in the sum increases from 278 K to 294 K. By how much has its entropy increased?
Homework Equations
Q=mcΔT
ΔS=Q/T
The Attempt at a Solution
Q=(255 g)(.90 J/gK)(294 K -278 K)
Q=3672 J
ΔS=Q/T...
Homework Statement
If 25.0 g of gallium melts in your hand, what is the change in entropy of the gallium?
What about the change of entropy in your hand? Is it positive or negative? Is its magnitude greater or less than that of the change in entropy of the gallium?
The melting...
Homework Statement
Premium gasoline produces 1.23×108 J of heat per gallon when it is burned at a temperature of approximately 400ºC (although the amount can vary with the fuel mixture). If the car's engine is 25.0% efficient, three-fourths of that heat is expelled into the air, typically at...
I have seen in a number of thermodynamics lectures that the entropy change of a system as it falls approximately isothermally from some height h to the ground is: ΔS = mgh/T
(The proof basically has you conceive of a reversible process between the same two states where some upwards force acts...
Homework Statement
S(E,V) = kln(\Gamma(E) )\\
S(E,V) = kln(\omega(E) )\\
S(E,V) = kln(\Sigma(E) )\\
S entropy, k Boltzmann's constant. Prove these 3 are equivalent up to an additive constant.
Homework Equations
\Gamma(E) = \int_{E<H<E+\Delta}^{'}dpdq\\...
Combining first and second law of thermodynamics we can get the following equation
TdS=dU-PextdV
First question: Is this equation available for irreversible process that dS≠dQ/T?
Second question:If the system temperature Tsys is smaller than the surrounding temperature Tsur, which...
The usual "proof" entropy is a state property is like that:
"Consider a system which undergoes a reversible process from state 1 to state 2 along path A, and let cycle be completed along path B, which is also reversible. Since the cycle is reversible we can write:
∫1-2 δQ / T + ∫2-1 δQ / T...
Hello guys,
I was watching video about physical basis for arrow of time..
..as well as several other videos and articles about physics of time. I am puzzled with this picture here (seen in 35:07 in video above)...
I'm having trouble getting my head around entropy. In an isolated system, entropy can only remain the same or increase. Is this the same for a thermodynamics cycle? What I mean is, if I drew a cycle on a PV diagram, would the entropy keep increasing? I can't see how that would work, that would...
When:
- Vacuum had an absolute mass, relatively limiting expension of all universal matter
- Newton's second law could be overridden or negated
- [Anything else I couldn't think of]
I am presented a review of data which gives:
vapour pressures of a liquid have been measured and fit to the following equation:
Log10 (mmHg) = -3571/T + 8.999
The melting point has been determined to be 392.7 K.
A Cp value given for the liquid is 250 J/mol K
and the ΔSvap is 117 J/mol K...
Homework Statement
Homework Equations
The Attempt at a Solution
I don't know what is the difference between the change in entropy of the gas vs the thermal reservoir??
1) What is the reason why dH!=0 for an adiabatic(q=0) reversible process?
The mathematical argument is irrefutable and it is clear that it has to do with the process not being isobaric:
ΔH=ΔU+PΔV+VΔP , ΔU=work=−PΔV
Therefore, ΔH=VΔP and this is not 0.
However, I do not understand it...
Hello. I was reading Hyperphysics website and could not get one particular part. I am providing a picture of the equation I am having trouble with: http://i.snag.gy/W3CC3.jpg
The particular part that puzzles me is the relation around the third equation sign. From the formula there one can think...
Homework Statement
Vapour pressures of a liquid have been measured and fit to the following equation:
Log10 P (mmHg) = -3571/T + 8.999
The melting point has been determined to be 392.7 K.
A Cp value given for the liquid is 250 J/mol K
and the ΔSvap is 117.20 J/mol K
Homework Equations...
We Now From Information Theory That Entropy Of Functions Of A Random Variable X Is Less Than Or Equal To The Entropy Of X.
Does It Break The Second Law Of Thermodynamic?
Homework Statement
vapour pressures of a liquid have been measured and fit to the following equation:
Log10 (mmHg) = -3571/T + 6.124
The melting point has been determined to be 392.7 K.
A Cp value given for the liquid is 250 J/mol K
and theΔSvap is 117 J/mol K
Homework Equations...
Homework Statement
The vapour pressures of a liquid have been measured and fit to the following equation:
Log10 (mmHg) = -3571/T + 6.124
The melting point has been determined to be 392.7 K.
Calculate the standard entropy of the liquid at the melting point.
Homework Equations...
No heat exchange is facilitated during an adiabatic process. Change is heat is zero.
How does this relates to the entropy being zero?
∫dQ/T?
But this could really just mean that the integral is of any constant.
okay so I suck at La-Tex so I'm not going to put the actual equation, but it's not important for my question.
In the equation the entropy is dependent on the natural log with mass in the numerator of the argument. Why is mass involved when talking about entropy at all?
I mean I think of...
I have a short question which I have been discussing with a fellow student and a professor. The question (which is not a homework question!), is as follows:
If you shift all the energies E_i \to E_i + E_0 (thus also shifting the mean energy U \to U + E_0), does the entropy of the system remain...
Calculate the change in entropy of the Universe as a result of the following
operations:
(a) A copper block of mass 0.4kg and thermal capacity 150JK-1 at 100◦C is
placed in a lake at 10◦C.
dS=dQ/T dQ=mCdT
Tried simply combining these equations and integrating to find change of entropy of...
Hello, I am looking for some clarity on the second law of thermodynamics. I am an amateur physics student and only just beginning and so my understanding is currently very basic!
I have watched Brian Cox's Wonders of the Universe, where he talks about the second law of thermodynamics being...
Homework Statement
Suppose we put N atoms of argon into a container of volume V at temperature T. Of these N atoms, Nad stick to the surface, while the remainder Ngas = N - Nad form an ideal gas inside the container.
Assume that the atoms on the surface are not able to move and have an...
There is one paragraph that says:
"
Our starting assumption is directly motivated by Bekenstein's original thought experiment
from which he obtained is famous entropy formula. He considered a particle with
mass m attached to a ctitious "string" that is lowered towards a black hole. Just...
Hello
Homework Statement
From the expression of the partition function of a fermi dirac ideal gas
ln(Z)=αN + ∑ ln(1+exp(-α-βEr))
show that
S= k ∑ [ <nr>ln(<nr>)+(1-<nr>)ln(1-<nr>)
Homework Equations
S=k( lnZ+β<E>)
<nr>=-1/β ∂ln(Z)/∂Er
<E>=-∂ln(Z)/∂β
The Attempt at a Solution
I...
1.0 mol of N2O4 placed in a constant pressure vessel at P = 1bar and T = 298 K. The system is allowed to slowly (reversibly) come to equilibrium. Given gibbs energy of formation, enthalpy of formation and entropy (the values are below) calculate the entropy change to the surroundings.
N2O4...
Homework Statement
Four moles of an ideal gas expands at constant temperature until its pressure is reduced to half of its initial value. What is the change in entropy of the gas?
Homework Equations
ΔS=Q/T (For constant T) pinitial=p pfinal=.5p
Q=W
W=pdv
nrTln(vf/vi)
The Attempt...