Molecular Definition and 583 Threads

A molecule is an electrically neutral group of two or more atoms held together by chemical bonds. Molecules are distinguished from ions by their lack of electrical charge.
In quantum physics, organic chemistry, and biochemistry, the distinction from ions is dropped and molecule is often used when referring to polyatomic ions.
In the kinetic theory of gases, the term molecule is often used for any gaseous particle regardless of its composition. This violates the definition that a molecule contain two or more atoms, since the noble gases are individual atoms.A molecule may be homonuclear, that is, it consists of atoms of one chemical element, as with two atoms in the oxygen molecule (O2); or it may be heteronuclear, a chemical compound composed of more than one element, as with water (two hydrogen atoms and one oxygen atom; H2O).
Atoms and complexes connected by non-covalent interactions, such as hydrogen bonds or ionic bonds, are typically not considered single molecules.Molecules as components of matter are common. They also make up most of the oceans and atmosphere. Most organic substances are molecules. The substances of life are molecules, e.g. proteins, the amino acids they are made of, the nucleic acids (DNA & RNA), sugars, carbohydrates, fats, and vitamins. The nutrient minerals ordinarily are not molecules, e.g. iron sulfate.
However, the majority of familiar solid substances on Earth are not made of molecules. These include all of the minerals that make up the substance of the Earth, soil, dirt, sand, clay, pebbles, rocks, boulders, bedrock, the molten interior, and the core of the Earth. All of these contain many chemical bonds, but are not made of identifiable molecules.
No typical molecule can be defined for salts nor for covalent crystals, although these are often composed of repeating unit cells that extend either in a plane, e.g. graphene; or three-dimensionally e.g. diamond, quartz, sodium chloride. The theme of repeated unit-cellular-structure also holds for most metals which are condensed phases with metallic bonding. Thus solid metals are not made of molecules.
In glasses, which are solids that exist in a vitreous disordered state, the atoms are held together by chemical bonds with no presence of any definable molecule, nor any of the regularity of repeating unit-cellular-structure that characterizes salts, covalent crystals, and metals.

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  1. K

    I Molecular Bond in H2+: Explained

    The ## {H_2^+}## molecule consists of two hydrogen nuclei and a single electron.What kind of molecular bond do you think holds this molecular together? Explain.
  2. Q

    Molecular Formula of different Octane rating gasolines?

    Trying to calculate the enthalpy of combustion for gasolines with different octane ratings, 95 and 91 gasoline in particular. The thing is, they are mixtures and not compounds. To calculate the enthalpy of combustion, I am trying to find the molecular formula for each of the gasolines, in order...
  3. cookiemnstr510510

    Frontier Molecular Orbital Theory Problem

    Summary: How do I draw the HOMO of HO-. The problem asks about the HOMO of HO- interacting in different ways with the LUMO of H-Cl. I cannot proceed with the question without figuring out how to draw the HOMO of HO-. I have attached pictures. Hello All, I have been struggling with this problem...
  4. sams

    Calculating the Molecular Orbitals of a Molecular State

    I am performing ab initio calculations on a heteronuclear diatomic compound using the MRCI method on the MOLPRO quantum chemistry package. I obtained the molecular states of the compound but I was wondering how to find the molecular orbital configuration of each electronic state in addition to...
  5. S

    Chemistry Calculation of average molecular speed

    We can calculate the average speed using this formula: uavg=root(8PV/ΠnM) I plugged in the following values: P= pi*10 atm (bar is approximately equal to atm) V=8lts n=2mol M=32*10^-3kg/mol But it is giving wrong answer. Can you tell me what went wrong?
  6. I

    I Molecular Vibrations: Rotational and Translational Movement

    Summary: Do solid particles rotate or transit or they just vibrate? Do solid particles move rotationaly and transitionally or all of these for liquid and gas?
  7. I

    A Find Reduced Mass for Polyatomic Molecules

    Summary: How could we find the reduced mass for polyatomic molecule ? I have problem with reduced mass of poly atomic moleculs because for diatomic molecules you can easily find out the reduced mass by M¹M²/M¹+M²,but I don't think with this way we can find reduces mass for example for fe²o³?
  8. M

    I What happens in the molecular structure of a liquid (imcompressible)?

    Suppose you have a liquid with high potential energy at a height [H] in a first moment. In a second moment, the liquid loses its potential energy (that is converted into kinetic energy) and fall in a cylinder at height [h] .IF the liquid is incompressible what happens with the molecules in the...
  9. C

    Molecular Orbits....what exactly is meant by orbitals having phase?

    Hello. I understand constructive/destructive interference for waves in general. But why do orbitals have phase? What is meant by phase for an orbital? What is the phase describing? Isn't the wave function describing where you are likely to locate the electron? Why is one positive and one...
  10. O

    B Photon exchange in molecular bonds

    So a photon is absorbed into and emitted from electrons, causing the electrons to jump energy levels around an atomic nucleus. And enough energy absorbed into the electron will cause the electron to break from the atom altogether. My question is, where does this energy that enters the...
  11. C

    A Is there a passive molecular flow 'diode'?

    During high vacuum pumping, one sucks viscous gas out of a chamber down to just above the molecular flow density where viscous flow becomes absent, and then may employ a different sort of pump to start pulling in the remaining molecules: Molecular flow. I have been wondering for a while if...
  12. N

    B Molecular Uncertainty: Exploring Position & Momentum

    Apologies in advance if my understandings are simply incorrect. As I understand it, there is a limit to what can be known about both a particle's position and momentum, and in some interpretations this is because there is no position or momentum until measurement only a probability. What I am...
  13. R

    How did 19th century scientists measure atomic and molecular weight?

    Found myself wondering about this recently, though I can't recall the context. When Mendeleev proposed the periodic table of elements, I believe that it was known that atomic weights of the known elements were multiples of hydrogen's atomic weight. Presumably also with substances like oxygen...
  14. T

    Bernoulli Principle from a molecular scale

    Good evening everyone. Can you tell me if it is possible to mathematically derive the Bernoulli principle from a microscopic analysis? In particular, in the hypothesis of an incompressible stationary flow, at a constant altitude, it states that: P + 0.5ρV^2 = cost Well, in textbooks this...
  15. ChrisXenon

    Temperature and molecular Kinetic Energy

    We are told that temperature measures the average kinetic energy of the molecules or atoms in a substance, but this cannot be true. If I take a jar of water and put the jar in my car and drive it aorund, it won't get hotter, though it's kinetic energy must surely be higher. Clearly, I've got...
  16. C

    Can Covalent Bonds form between atoms with no electrons?

    Homework Statement I learned that Covalent Bonds form between different specific atoms ( with similar electro-negativity ) with electrons. However, I wondered what type of bond would form between the different atoms if they had no electrons? Also , if I have 2 atoms with similar...
  17. Y

    Molecular Seive for making vacuum tubes

    im trying to jog my memory back 30years when I worked with vacuum tubes. I worked with manufacturing of image tubes. I remember the vacuum systems used vac-ion pumps to achieve -12 power torr. I alsoo remember first using a molecular seive for roughing,pumping to 10 microns. The seive was a...
  18. nineteen

    Chemistry How can I find the molecular formula in this problem?

    Homework Statement In an organic compound "A" only C,H and O is present. 1.22g of A is completely burned and it gives 0.84g of CO2 and 0.54g of H2O. If the relative molecular mass of "A" is 123. Find the molecular formula of A. [/B] I have showed my attempt at solving this problem, but I think...
  19. H

    I Nuclear spin coupling in molecular (protium) hydrogen

    I'm not sure where this post belongs--here, or nuclear chemistry, quantum mechanics, NMR spectroscopy, etc. Moderator--please feel free to move it to a better location. I'm wondering if a container of liquid hydrogen subjected to a strong magnetic field would have both nuclei of each atom...
  20. nineteen

    Chemistry Finding the Chemical Formula and Relative Molecular Mass

    My chemistry teacher gave me this problem. I tried and tried, but I couldn't figure it out and the deadline is tomorrow. Please help me out here friends. 1. This is the problem : In a compound which is made of element Y, weight percentage of Y is 72% and N( Nitrogen) is 28%. Also, 3 Y atoms...
  21. A

    Molecular Diffusion of A through Non-diffusing B

    Diffusion of A through Non-diffusing B Dry air is required for burning of sulphur in a sulphuric acid plant. Moisture (A) diffuses through a film or layer of air (B), reaches the acid and gets absorbed in it. But air being virtually insoluble in sulphuric acid will not diffuse. So air is...
  22. S

    Chemistry How to get molality without using a molecular formula?

    Homework Statement Freezing point depression question[/B] student determines molar mass of acetone using the method used in this experiment. She found that the eq temp of water and ice was 1 deg C. She then adds 11.1g of the sample to mixture and temp falls to -3 deg C. Mass of solution was...
  23. Ashley1999

    Programs Should I switch my major to Molecular Genetics?

    Hi, currently I am a freshman who is majoring in Biosystems Engineering. I selected this major because I did a lot of research into biology undergrads and I didn't like what I saw. I got the notion that these majors did not emphasize the technical skills necessary to do well in a science...
  24. BillTre

    Monocots Evolved from Aquatic Plants says Molecular Study

    I'm not a plant expert, but I can tell monocots from dicots. Apparently the monocot lineage was founded by aquatic plants (Science mag news story, original paper) and some obscure monocot leaf structure features can be explained by that aquatic origin. I'm actually kind of surprised...
  25. Sophrosyne

    B How to think of molecular orbitals quantum mechanically

    The electrons in a molecule are said to be in a quantum superposition state in terms of their position/spin/momentum. But when you look at a molecule like water at a chemical level, it has a very specific shape corresponding to the P orbitals of the outer shell of the Oxygen atom. The two...
  26. Dustyneo

    Chemistry Combustion Analysis- Empirical and molecular formula

    Homework Statement Menthol, the substance we can smell in mentholated cough drops, is composed of C, H, and O. A 0.1005-g sample of menthol is combusted, producing 0.2829 g of CO2 and 0.1159 g of H2O. What is the empirical formula for menthol? If menthol has a molar mass of 156 g/mol, what is...
  27. C

    Molecular dynamics Lennard Jones

    Following Frekel-Smit book: https://www.amazon.it/dp/0122673514/ I am trying to write a program based on the algorithms 3,4,5 and 6 in the book. I use a cutted-shifted Lennard Jones potential, with cutoff radius at 2σ. #include <iostream> #include <cstdlib> #include <cmath> #include<fstream>...
  28. S

    Infinitely long molecular zipper

    Homework Statement [/B] A "molecular zipper" has two rows of molecules, and each row has a large number of monomers. A monomer from one row is weakly linked to a monomer in the other row. The zipper can unzip from one end by breaking the bond between pairs of monomers. A bond can be broken...
  29. prakhargupta3301

    Is Molecular Orbital Theory really helpful?

    Who am I kidding? Of course it is. But, everywhere I look, the series of increasing levels of orbitals is till σ*2pz only That's all. So if I need to find bond order of , say, some molecule with greater number of e- like BF3 with 24 electrons, how do I proceed?
  30. D

    Velocity correlations and molecular chaos

    I’ve been reading up about Boltzmann transport equations, and the concept of molecular chaos has come up, in which one assumes the velocities of particles are assumed to be uncorrelated. I’m a bit confused about the concept though. In what sense do the velocities become correlated in the first...
  31. D

    Calculate the molecular weight of Al2(SO4)3.14.3H2O

    Homework Statement Calculate the molecular weight of Al2(SO4)3.14.3H2O Homework EquationsThe Attempt at a Solution May i know how to do this ? Does it mean 14*3 = 42(H20) , where there re 84H , 42O atoms ?
  32. mark!

    Pathogenic molecular handedness

    Why is the enantiomer of a chiral molecule often considered to be a foreign, not-body-own pathogen? Peptidoglycan, which makes up a great part of the bacterial cell wall, contains several of these molecules, such as D-alanin, whereas humans use the L-form, or other components like L-glutamic...
  33. P

    I EM Radiation of "Permanent" Molecular Electric Dipoles

    Suppose I were to subject a polar molecule to a high-frequency electric field. The polar molecule responds to the high-frequency electric field and thus it has a time-varying electric dipole moment vector. If we treated this as a classical electric dipole, it would be expected to radiate some of...
  34. I

    Formal name for molecular aggregations?

    Is there a word that describes physical bodies of molecules? By this, I mean any "body" that is composed of similar or different molecules, whether it is an ocean, a drop of water, a mountain, a glass cup, or a cloud, or even living bodies and their parts for that matter. This is in lines of...
  35. Superhet

    Courses Molecular nanotechnology and programmable matter

    My plan right now is to study a program called 'engineering physics with materials science' when I enter university in the fall. What I want to work with is molecular nanotechnology and programmable matter. I want to contribute to creating stuff like "computronium", utility fog, self-healing...
  36. L

    B Why aren't molecular vibrations synchronized in a way that can be observed?

    why are molecular vibrations never synchronized in a way that would make them macroscopically observable?
  37. E

    Molecular Dynamics Simulation - How Do You Find Parameters?

    Hi all, I'm doing a bit of material science research at my university. I'm running molecular dynamics simulation programs like Lammps and Amber as part of it, and I'm pretty new to the whole thing (just like I'm pretty new to this forum). I'd like to ask, has anyone here used Amber to find their...
  38. T

    Pressure caused by beam of molecular oxygen

    Homework Statement A beam of molecular oxygen containing 1010 molecules/cm3 and average speed of 500 m/s strikes (elastic collision) a plate at an angle of 30º with the normal direction. Calculate the exerted pressure on the plate. Homework Equations P = Impluse x Flux The Attempt at a...
  39. Wrichik Basu

    Atomic Books on Molecular Orbital Theory

    I need good books on Molecular Orbital Theory. The book(s) should have the basics, and the level should not be less than graduation. I have Quantum mechanics books, but they don't throw any light on this. My course books are rubbish, only mentioning the name of the theory and some illogical...
  40. MathematicalPhysicist

    I How Does Weiss Molecular Field Theory Model Magnetization Symmetry?

    This question is more about the maths than the physics. So I am reading the textbook by Bergersen and Plischke, and they get the following: $$m= \tanh [ \beta (qJm+h)]$$ where ##m## is the magnetization, ##q## is the number of nearest neighbours of site ##0##, ##J## and ##h##are the...
  41. H

    Nozzle/Turbine at the Molecular Level

    Hey all. I feel like I understand the topic mathematically, but I have little intuition behind this. I like to try to think about what is going on at the molecular level. I've recently learned that the basis of lift that I was taught in class is not simply a pressure difference on the top and...
  42. A

    Chemistry Polystyrene repeat unit molecular weight.

    Edit: thread moved from non HW forum. I'm trying to calculate the unit molecular weight of polystyrene. I'm given the structure, and I have to count all the elements in the structure. To calculate the weight, I keep counting 8C & 7H. The correct answer is 8C +8H. I'm having a hard time...
  43. L

    Chemistry How many grams of NaCl are needed to make a 2M stock solution?

    Homework Statement - How many grams of NaCl (molecular weight = 58 Da) would you have to dissolve in 50ml to make a 2M stock solution? The Attempt at a Solution I have thought about simply multiplying 58 by 0.1 = 5.8 g, but am not sure if this is correct. It's just the daltons that are...
  44. R

    B Molecular Entanglement: Exploring Interconnectedness in Biochemistry

    Nucleus are entangled to electrons... Atoms are entangled to other atoms in molecules.. Are molecules at distance also entangled to one another? Is there a way to test if this is true? I want to know if our biochemistry is entangled to the biochemistry of other people.
  45. Const@ntine

    Molecular Specific Heat of an Ideal Gas: Computations

    Homework Statement A cylinder with a heavy ram/piston contains air at T = 300 K. Pi = 2.00 * 105 Pa, Vi = 0.350 m3, Mr = 28.9 g/mol & Cv = 5R/2 (a) What's the Molecular Specific Heat of an Ideal Gas, with a constant volume, computed at J/KgC ? (Cv) (b) What's the mass of the air inside the...
  46. R

    B Pocket size molecular spectrometer

    Has anyone owned the Scio pocket size molecular spectrometer that can make you identify substances? see https://www.consumerphysics.com/ how accurate is it? Is there a size limit for any spectrometer where accuracy could be affected? the Scio is an IR spectrometer.. is pocket size Raman...
  47. T

    How does a C4 explosion work on a molecular level

    I understand the fact that the detonator begins the reaction. The reaction happens many times release a ton of energy which causes the gases around it to rapidly expand and accelerate away (not the best summary). However, what causes the combustion which tends to happen as a consequence of the...
  48. N

    Chemistry Estimating number of amino acids with protein molecular mass

    Homework Statement Suppose you were told you had a protein with molecular mass of 65,000 g/mol. Show how you would estimate the number of amino acids present in this protein. Keep in mind that you cannot calculate the exact number, the point of this is to approximate how many amino acids are...
  49. Konte

    Computing molecular symmetry group for non rigid molecules

    Hi everybody, My post today is about Molecular Symmetry group (MS) for non-rigid molecules. I read from this excellent work (Longuet-Higgins), that MS is obtained by selecting only feasible operation from Complete Nuclear Permutation Inversion Group (CNPI). My question is, As I have a quite...
  50. Konte

    Molecular symmetry group of non-rigid molecules

    Hello everybody, I have read some very interesting book (Molecular symmetry and Spectroscopy - Bunker and Jensen) that talk about how to find the Molecular Symmetry group (MS) of a molecule by using the concept of "feasible" operation from the Complete Nuclear Permutation Inversion (CNPI)...
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